Study of the structure and curing of thiourethane elastomers based on oligomer compositions
Data on the structure formation of thiourethane elastomers based on oligo(diene diols) and polysulfide oligomers are generalized. The curing of oligo(diene diols) by polyfunctional isocyanates in the presence of liquid thiokols and glycerol is characterized by the formation of highly branched molecu...
Gespeichert in:
| Veröffentlicht in: | Polymer science. Series B 2012-04, Vol.54 (3-4), p.240-246 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 246 |
|---|---|
| container_issue | 3-4 |
| container_start_page | 240 |
| container_title | Polymer science. Series B |
| container_volume | 54 |
| creator | Novakov, I. A. Chalykh, A. E. Nistratov, A. V. Reznikova, O. A. Matveev, V. V. Budylin, N. Yu Pyl’nov, D. V. |
| description | Data on the structure formation of thiourethane elastomers based on oligo(diene diols) and polysulfide oligomers are generalized. The curing of oligo(diene diols) by polyfunctional isocyanates in the presence of liquid thiokols and glycerol is characterized by the formation of highly branched molecules already at the early stages of structure formation. This feature predetermines the microheterogeneous character of the process and the appearance of the gel fraction at low conversions of functional groups. The maximum values of the curing rate and crosslink density are achieved at NCO: (OH + SH) = 1. |
| doi_str_mv | 10.1134/S1560090412040045 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1031319143</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1031319143</sourcerecordid><originalsourceid>FETCH-LOGICAL-c321t-c86d36cce7934118f547a7a2dd8e22dbeeeac87a3ab0109fa824405ccbb8ef253</originalsourceid><addsrcrecordid>eNp9UDtPwzAQthBIVKU_gM0jS8DnRx4jqnhJlRgKE0PkOJc2VRIH2xn673EUNiRuudP3ON19hNwCuwcQ8mEPKmWsYBI4k4xJdUFWoJRKUuDicp5Tlsz8Ndl4f2KxRCEAihX52oepPlPb0HBE6oObTJgcUj3U1EyuHQ4L19qIhqMekGKnfbA9Ok8r7bGmdqC2aw8zRI3tR-vb0NrB35CrRnceN799TT6fnz62r8nu_eVt-7hLjOAQEpOntUiNwawQEiBvlMx0pnld58h5XSGiNnmmha4YsKLROZeSKWOqKseGK7Emd8ve0dnvCX0o-9Yb7Lp4rZ18CUyAgAKkiFJYpMZZ7x025ejaXrtzFJVzluWfLKOHLx4_znmgK08xjCF-9I_pB1lidzs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1031319143</pqid></control><display><type>article</type><title>Study of the structure and curing of thiourethane elastomers based on oligomer compositions</title><source>SpringerNature Journals</source><creator>Novakov, I. A. ; Chalykh, A. E. ; Nistratov, A. V. ; Reznikova, O. A. ; Matveev, V. V. ; Budylin, N. Yu ; Pyl’nov, D. V.</creator><creatorcontrib>Novakov, I. A. ; Chalykh, A. E. ; Nistratov, A. V. ; Reznikova, O. A. ; Matveev, V. V. ; Budylin, N. Yu ; Pyl’nov, D. V.</creatorcontrib><description>Data on the structure formation of thiourethane elastomers based on oligo(diene diols) and polysulfide oligomers are generalized. The curing of oligo(diene diols) by polyfunctional isocyanates in the presence of liquid thiokols and glycerol is characterized by the formation of highly branched molecules already at the early stages of structure formation. This feature predetermines the microheterogeneous character of the process and the appearance of the gel fraction at low conversions of functional groups. The maximum values of the curing rate and crosslink density are achieved at NCO: (OH + SH) = 1.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090412040045</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Chemistry ; Chemistry and Materials Science ; Conversion ; Curing ; Density ; Diols ; Elastomers ; Glycerols ; Liquids ; Modification of Polymers ; Oligomers ; Polymer Sciences</subject><ispartof>Polymer science. Series B, 2012-04, Vol.54 (3-4), p.240-246</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-c86d36cce7934118f547a7a2dd8e22dbeeeac87a3ab0109fa824405ccbb8ef253</citedby><cites>FETCH-LOGICAL-c321t-c86d36cce7934118f547a7a2dd8e22dbeeeac87a3ab0109fa824405ccbb8ef253</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1560090412040045$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1560090412040045$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Novakov, I. A.</creatorcontrib><creatorcontrib>Chalykh, A. E.</creatorcontrib><creatorcontrib>Nistratov, A. V.</creatorcontrib><creatorcontrib>Reznikova, O. A.</creatorcontrib><creatorcontrib>Matveev, V. V.</creatorcontrib><creatorcontrib>Budylin, N. Yu</creatorcontrib><creatorcontrib>Pyl’nov, D. V.</creatorcontrib><title>Study of the structure and curing of thiourethane elastomers based on oligomer compositions</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>Data on the structure formation of thiourethane elastomers based on oligo(diene diols) and polysulfide oligomers are generalized. The curing of oligo(diene diols) by polyfunctional isocyanates in the presence of liquid thiokols and glycerol is characterized by the formation of highly branched molecules already at the early stages of structure formation. This feature predetermines the microheterogeneous character of the process and the appearance of the gel fraction at low conversions of functional groups. The maximum values of the curing rate and crosslink density are achieved at NCO: (OH + SH) = 1.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conversion</subject><subject>Curing</subject><subject>Density</subject><subject>Diols</subject><subject>Elastomers</subject><subject>Glycerols</subject><subject>Liquids</subject><subject>Modification of Polymers</subject><subject>Oligomers</subject><subject>Polymer Sciences</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9UDtPwzAQthBIVKU_gM0jS8DnRx4jqnhJlRgKE0PkOJc2VRIH2xn673EUNiRuudP3ON19hNwCuwcQ8mEPKmWsYBI4k4xJdUFWoJRKUuDicp5Tlsz8Ndl4f2KxRCEAihX52oepPlPb0HBE6oObTJgcUj3U1EyuHQ4L19qIhqMekGKnfbA9Ok8r7bGmdqC2aw8zRI3tR-vb0NrB35CrRnceN799TT6fnz62r8nu_eVt-7hLjOAQEpOntUiNwawQEiBvlMx0pnld58h5XSGiNnmmha4YsKLROZeSKWOqKseGK7Emd8ve0dnvCX0o-9Yb7Lp4rZ18CUyAgAKkiFJYpMZZ7x025ejaXrtzFJVzluWfLKOHLx4_znmgK08xjCF-9I_pB1lidzs</recordid><startdate>20120401</startdate><enddate>20120401</enddate><creator>Novakov, I. A.</creator><creator>Chalykh, A. E.</creator><creator>Nistratov, A. V.</creator><creator>Reznikova, O. A.</creator><creator>Matveev, V. V.</creator><creator>Budylin, N. Yu</creator><creator>Pyl’nov, D. V.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120401</creationdate><title>Study of the structure and curing of thiourethane elastomers based on oligomer compositions</title><author>Novakov, I. A. ; Chalykh, A. E. ; Nistratov, A. V. ; Reznikova, O. A. ; Matveev, V. V. ; Budylin, N. Yu ; Pyl’nov, D. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-c86d36cce7934118f547a7a2dd8e22dbeeeac87a3ab0109fa824405ccbb8ef253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Conversion</topic><topic>Curing</topic><topic>Density</topic><topic>Diols</topic><topic>Elastomers</topic><topic>Glycerols</topic><topic>Liquids</topic><topic>Modification of Polymers</topic><topic>Oligomers</topic><topic>Polymer Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Novakov, I. A.</creatorcontrib><creatorcontrib>Chalykh, A. E.</creatorcontrib><creatorcontrib>Nistratov, A. V.</creatorcontrib><creatorcontrib>Reznikova, O. A.</creatorcontrib><creatorcontrib>Matveev, V. V.</creatorcontrib><creatorcontrib>Budylin, N. Yu</creatorcontrib><creatorcontrib>Pyl’nov, D. V.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Novakov, I. A.</au><au>Chalykh, A. E.</au><au>Nistratov, A. V.</au><au>Reznikova, O. A.</au><au>Matveev, V. V.</au><au>Budylin, N. Yu</au><au>Pyl’nov, D. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of the structure and curing of thiourethane elastomers based on oligomer compositions</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2012-04-01</date><risdate>2012</risdate><volume>54</volume><issue>3-4</issue><spage>240</spage><epage>246</epage><pages>240-246</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>Data on the structure formation of thiourethane elastomers based on oligo(diene diols) and polysulfide oligomers are generalized. The curing of oligo(diene diols) by polyfunctional isocyanates in the presence of liquid thiokols and glycerol is characterized by the formation of highly branched molecules already at the early stages of structure formation. This feature predetermines the microheterogeneous character of the process and the appearance of the gel fraction at low conversions of functional groups. The maximum values of the curing rate and crosslink density are achieved at NCO: (OH + SH) = 1.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1560090412040045</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1560-0904 |
| ispartof | Polymer science. Series B, 2012-04, Vol.54 (3-4), p.240-246 |
| issn | 1560-0904 1555-6123 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1031319143 |
| source | SpringerNature Journals |
| subjects | Chemistry Chemistry and Materials Science Conversion Curing Density Diols Elastomers Glycerols Liquids Modification of Polymers Oligomers Polymer Sciences |
| title | Study of the structure and curing of thiourethane elastomers based on oligomer compositions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T12%3A21%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Study%20of%20the%20structure%20and%20curing%20of%20thiourethane%20elastomers%20based%20on%20oligomer%20compositions&rft.jtitle=Polymer%20science.%20Series%20B&rft.au=Novakov,%20I.%20A.&rft.date=2012-04-01&rft.volume=54&rft.issue=3-4&rft.spage=240&rft.epage=246&rft.pages=240-246&rft.issn=1560-0904&rft.eissn=1555-6123&rft_id=info:doi/10.1134/S1560090412040045&rft_dat=%3Cproquest_cross%3E1031319143%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1031319143&rft_id=info:pmid/&rfr_iscdi=true |