Improvement of anti-corrosive properties of epoxy-coated AA 2024-T3 with TiO2 nanocontainers loaded with 8-hydroxyquinoline

► Titanium oxide nanocontainers loaded with corrosion inhibitor. ► Epoxy coatings including loaded nanocontainers applied to AA2024-T3. ► The loaded nanocontainers improve epoxy coatings corrosion protection properties. Epoxy coatings containing TiO2 nanocontainers were applied on aluminium alloy (A...

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Veröffentlicht in:Progress in organic coatings 2012-07, Vol.74 (3), p.418-426
Hauptverfasser: Balaskas, A.C., Kartsonakis, I.A., Tziveleka, L.-A., Kordas, G.C.
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container_end_page 426
container_issue 3
container_start_page 418
container_title Progress in organic coatings
container_volume 74
creator Balaskas, A.C.
Kartsonakis, I.A.
Tziveleka, L.-A.
Kordas, G.C.
description ► Titanium oxide nanocontainers loaded with corrosion inhibitor. ► Epoxy coatings including loaded nanocontainers applied to AA2024-T3. ► The loaded nanocontainers improve epoxy coatings corrosion protection properties. Epoxy coatings containing TiO2 nanocontainers were applied on aluminium alloy (AA) 2024-T3 for corrosion protection. The nanocontainers were loaded with the corrosion inhibitor 8-hydroxyquinoline (8-HQ). Epoxy coatings were deposited via the dip-coating process. The morphology of the coatings was examined by scanning electron microscopy (SEM). The composition of the films was determined by energy dispersive X-ray analysis (EDX). Electrochemical impedance spectroscopy (EIS) was employed for the characterization of the corrosion resistance of these coatings. The total impedance values were measured as a function of time exposure in corrosive environment. We observed a continuous increase of the total impedance value with the time of exposure suggesting a possible self-healing effect due to the release of the inhibitors from the nanocontainers. Furthermore, addition of loaded nanocontainers into the coatings leads to the enhancement of the barrier properties of the coatings. Conclusively, we observed an improvement of the performance of the coatings due to the loaded nanocontainers.
doi_str_mv 10.1016/j.porgcoat.2012.01.005
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Epoxy coatings containing TiO2 nanocontainers were applied on aluminium alloy (AA) 2024-T3 for corrosion protection. The nanocontainers were loaded with the corrosion inhibitor 8-hydroxyquinoline (8-HQ). Epoxy coatings were deposited via the dip-coating process. The morphology of the coatings was examined by scanning electron microscopy (SEM). The composition of the films was determined by energy dispersive X-ray analysis (EDX). Electrochemical impedance spectroscopy (EIS) was employed for the characterization of the corrosion resistance of these coatings. The total impedance values were measured as a function of time exposure in corrosive environment. We observed a continuous increase of the total impedance value with the time of exposure suggesting a possible self-healing effect due to the release of the inhibitors from the nanocontainers. Furthermore, addition of loaded nanocontainers into the coatings leads to the enhancement of the barrier properties of the coatings. 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source ScienceDirect Journals (5 years ago - present)
subjects AA2024-T3
Aluminum base alloys
Coatings
Corrosion
Corrosion inhibitors
EIS
Inhibition
Nanocomposites
Nanocontainers
Nanomaterials
Nanostructure
Self-healing
Titanium dioxide
title Improvement of anti-corrosive properties of epoxy-coated AA 2024-T3 with TiO2 nanocontainers loaded with 8-hydroxyquinoline
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