Regiodiverse Three-Component Synthesis of Arenes

A ruthenium‐catalyzed enyne metathesis reaction followed by a cobalt‐catalyzed Diels–Alder reaction and oxidation of the dihydroaromatic intermediate generates the two regioisomeric aromatic products in good overall yields in a one‐pot procedure. The regiochemistry of the cycloaddition can be contro...

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Veröffentlicht in:	Advanced synthesis & catalysis 2011-02, Vol.353 (2-3), p.303-308
Hauptverfasser:	Danz, Michael, Hilt, Gerhard
Format:	Artikel
Sprache:	eng
Schlagworte:	alkynes arenes Catalysis Catalysts: preparations and properties Chemistry Cobalt Diels-Alder reactions Exact sciences and technology Functional groups General and physical chemistry Kinetics and mechanisms Ligands Metathesis Organic chemistry Reactivity and mechanisms regioselectivity Synthesis Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tolerances
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