Total Synthesis and Structure Confirmation of Elatenyne: Success of Computational Methods for NMR Prediction with Highly Flexible Diastereomers

Elatenyne is a small dibrominated natural product first isolated from Laurencia elata. The structure of elatenyne was originally assigned as a pyrano[3,2-b]pyran on the basis of NMR methods. Total synthesis of the originally proposed pyrano[3,2-b]pyran structure of elatenyne led to the gross structu...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-07, Vol.134 (28), p.11781-11790
Hauptverfasser:	Dyson, Bryony S, Burton, Jonathan W, Sohn, Te-ik, Kim, Byungsook, Bae, Hoon, Kim, Deukjoon
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemical synthesis Alkynes - chemistry Carbon Isotopes Furans - chemical synthesis Furans - chemistry Magnetic Resonance Spectroscopy - methods Stereoisomerism
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