Gas phase reaction kinetics in boron fibre production
In the production of boron fibres using the chemical vapor deposition (CVD) technique, boron deposition and dichloroborane formation reactions occurs simultaneously. Boron deposition reaction occurs at the surface, whereas the formation of dichloroborane is the result of both gas phase and surface r...
Gespeichert in:
Veröffentlicht in: | AIChE journal 2012-05, Vol.58 (5), p.1562-1569 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 1569 |
---|---|
container_issue | 5 |
container_start_page | 1562 |
container_title | AIChE journal |
container_volume | 58 |
creator | Fırat, Fatih Sezgi, Naime A. Özbelge, Hilmi Ö. Doğu, Timur |
description | In the production of boron fibres using the chemical vapor deposition (CVD) technique, boron deposition and dichloroborane formation reactions occurs simultaneously. Boron deposition reaction occurs at the surface, whereas the formation of dichloroborane is the result of both gas phase and surface reactions. A continuous stirred tank reactor (CSTR) type of reactor was designed to investigate the reaction kinetics and kinetic parameters in the gas phase reactions of boron trichloride and hydrogen. It was concluded that reaction rate of the product increased with an increase in the inlet concentration of both reactants (BCl3 and H2) and with an increase in the reactor temperature. While reaction order with respect to BCl3 was almost constant at about 0.5 at each temperature, reaction order with respect to hydrogen increased significantly at temperatures lower than 350°C. A general rate expression was derived for BHCl2 formation from BCl3 and hydrogen. © 2011 American Institute of Chemical Engineers AIChE J, 2012 |
doi_str_mv | 10.1002/aic.12671 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1022859437</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1022859437</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3951-3346ea7b49aeb508ea7a0c24eff767b5e35f37138d24aa131bdd87fe37712b6a3</originalsourceid><addsrcrecordid>eNp10M9LwzAUB_AgCs7pwf-gIIIeuuVH07THMXVOil6UwS7hNUsxW9fOpEX33xvXuYPgKcnj874vPIQuCR4QjOkQjBoQGgtyhHqERyLkKebHqIcxJqEvkFN05tzSv6hIaA_xCbhg8w5OB1aDakxdBStT6cYoF5gqyGvrK4XJrQ42tl60O3KOTgoonb7Yn3309nD_On4Ms5fJdDzKQsVSTkLGoliDyKMUdM5x4u-AFY10UYhY5FwzXjBBWLKgEQBhJF8sElFoJgSheQysj266XD_6o9WukWvjlC5LqHTdOkkwpQlPIyY8vfpDl3VrK_87r3DKqOAx9uq2U8rWzlldyI01a7Bbj34clX6BcrdAb6_3ieAUlIWFShl3aKA8iXiccu-Gnfs0pd7-HyhH0_Fvcth1GNfor0MH2JWMBRNczp4nMnu6m2fRjMg5-wbHj4vi</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1009327560</pqid></control><display><type>article</type><title>Gas phase reaction kinetics in boron fibre production</title><source>Wiley Journals</source><creator>Fırat, Fatih ; Sezgi, Naime A. ; Özbelge, Hilmi Ö. ; Doğu, Timur</creator><creatorcontrib>Fırat, Fatih ; Sezgi, Naime A. ; Özbelge, Hilmi Ö. ; Doğu, Timur</creatorcontrib><description>In the production of boron fibres using the chemical vapor deposition (CVD) technique, boron deposition and dichloroborane formation reactions occurs simultaneously. Boron deposition reaction occurs at the surface, whereas the formation of dichloroborane is the result of both gas phase and surface reactions. A continuous stirred tank reactor (CSTR) type of reactor was designed to investigate the reaction kinetics and kinetic parameters in the gas phase reactions of boron trichloride and hydrogen. It was concluded that reaction rate of the product increased with an increase in the inlet concentration of both reactants (BCl3 and H2) and with an increase in the reactor temperature. While reaction order with respect to BCl3 was almost constant at about 0.5 at each temperature, reaction order with respect to hydrogen increased significantly at temperatures lower than 350°C. A general rate expression was derived for BHCl2 formation from BCl3 and hydrogen. © 2011 American Institute of Chemical Engineers AIChE J, 2012</description><identifier>ISSN: 0001-1541</identifier><identifier>EISSN: 1547-5905</identifier><identifier>DOI: 10.1002/aic.12671</identifier><identifier>CODEN: AICEAC</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Boron ; boron fibres ; Chemical engineering ; Chemical reactions ; Chemical vapor deposition ; CVD ; dichloroborane ; Exact sciences and technology ; gas phase reaction ; kinetics ; Reaction kinetics ; Reactors</subject><ispartof>AIChE journal, 2012-05, Vol.58 (5), p.1562-1569</ispartof><rights>Copyright © 2011 American Institute of Chemical Engineers (AIChE)</rights><rights>2015 INIST-CNRS</rights><rights>Copyright American Institute of Chemical Engineers May 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c3951-3346ea7b49aeb508ea7a0c24eff767b5e35f37138d24aa131bdd87fe37712b6a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faic.12671$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faic.12671$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25845695$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Fırat, Fatih</creatorcontrib><creatorcontrib>Sezgi, Naime A.</creatorcontrib><creatorcontrib>Özbelge, Hilmi Ö.</creatorcontrib><creatorcontrib>Doğu, Timur</creatorcontrib><title>Gas phase reaction kinetics in boron fibre production</title><title>AIChE journal</title><addtitle>AIChE J</addtitle><description>In the production of boron fibres using the chemical vapor deposition (CVD) technique, boron deposition and dichloroborane formation reactions occurs simultaneously. Boron deposition reaction occurs at the surface, whereas the formation of dichloroborane is the result of both gas phase and surface reactions. A continuous stirred tank reactor (CSTR) type of reactor was designed to investigate the reaction kinetics and kinetic parameters in the gas phase reactions of boron trichloride and hydrogen. It was concluded that reaction rate of the product increased with an increase in the inlet concentration of both reactants (BCl3 and H2) and with an increase in the reactor temperature. While reaction order with respect to BCl3 was almost constant at about 0.5 at each temperature, reaction order with respect to hydrogen increased significantly at temperatures lower than 350°C. A general rate expression was derived for BHCl2 formation from BCl3 and hydrogen. © 2011 American Institute of Chemical Engineers AIChE J, 2012</description><subject>Applied sciences</subject><subject>Boron</subject><subject>boron fibres</subject><subject>Chemical engineering</subject><subject>Chemical reactions</subject><subject>Chemical vapor deposition</subject><subject>CVD</subject><subject>dichloroborane</subject><subject>Exact sciences and technology</subject><subject>gas phase reaction</subject><subject>kinetics</subject><subject>Reaction kinetics</subject><subject>Reactors</subject><issn>0001-1541</issn><issn>1547-5905</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp10M9LwzAUB_AgCs7pwf-gIIIeuuVH07THMXVOil6UwS7hNUsxW9fOpEX33xvXuYPgKcnj874vPIQuCR4QjOkQjBoQGgtyhHqERyLkKebHqIcxJqEvkFN05tzSv6hIaA_xCbhg8w5OB1aDakxdBStT6cYoF5gqyGvrK4XJrQ42tl60O3KOTgoonb7Yn3309nD_On4Ms5fJdDzKQsVSTkLGoliDyKMUdM5x4u-AFY10UYhY5FwzXjBBWLKgEQBhJF8sElFoJgSheQysj266XD_6o9WukWvjlC5LqHTdOkkwpQlPIyY8vfpDl3VrK_87r3DKqOAx9uq2U8rWzlldyI01a7Bbj34clX6BcrdAb6_3ieAUlIWFShl3aKA8iXiccu-Gnfs0pd7-HyhH0_Fvcth1GNfor0MH2JWMBRNczp4nMnu6m2fRjMg5-wbHj4vi</recordid><startdate>201205</startdate><enddate>201205</enddate><creator>Fırat, Fatih</creator><creator>Sezgi, Naime A.</creator><creator>Özbelge, Hilmi Ö.</creator><creator>Doğu, Timur</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>American Institute of Chemical Engineers</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7U5</scope><scope>8FD</scope><scope>C1K</scope><scope>L7M</scope><scope>SOI</scope></search><sort><creationdate>201205</creationdate><title>Gas phase reaction kinetics in boron fibre production</title><author>Fırat, Fatih ; Sezgi, Naime A. ; Özbelge, Hilmi Ö. ; Doğu, Timur</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3951-3346ea7b49aeb508ea7a0c24eff767b5e35f37138d24aa131bdd87fe37712b6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Boron</topic><topic>boron fibres</topic><topic>Chemical engineering</topic><topic>Chemical reactions</topic><topic>Chemical vapor deposition</topic><topic>CVD</topic><topic>dichloroborane</topic><topic>Exact sciences and technology</topic><topic>gas phase reaction</topic><topic>kinetics</topic><topic>Reaction kinetics</topic><topic>Reactors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fırat, Fatih</creatorcontrib><creatorcontrib>Sezgi, Naime A.</creatorcontrib><creatorcontrib>Özbelge, Hilmi Ö.</creatorcontrib><creatorcontrib>Doğu, Timur</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>AIChE journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fırat, Fatih</au><au>Sezgi, Naime A.</au><au>Özbelge, Hilmi Ö.</au><au>Doğu, Timur</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gas phase reaction kinetics in boron fibre production</atitle><jtitle>AIChE journal</jtitle><addtitle>AIChE J</addtitle><date>2012-05</date><risdate>2012</risdate><volume>58</volume><issue>5</issue><spage>1562</spage><epage>1569</epage><pages>1562-1569</pages><issn>0001-1541</issn><eissn>1547-5905</eissn><coden>AICEAC</coden><abstract>In the production of boron fibres using the chemical vapor deposition (CVD) technique, boron deposition and dichloroborane formation reactions occurs simultaneously. Boron deposition reaction occurs at the surface, whereas the formation of dichloroborane is the result of both gas phase and surface reactions. A continuous stirred tank reactor (CSTR) type of reactor was designed to investigate the reaction kinetics and kinetic parameters in the gas phase reactions of boron trichloride and hydrogen. It was concluded that reaction rate of the product increased with an increase in the inlet concentration of both reactants (BCl3 and H2) and with an increase in the reactor temperature. While reaction order with respect to BCl3 was almost constant at about 0.5 at each temperature, reaction order with respect to hydrogen increased significantly at temperatures lower than 350°C. A general rate expression was derived for BHCl2 formation from BCl3 and hydrogen. © 2011 American Institute of Chemical Engineers AIChE J, 2012</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/aic.12671</doi><tpages>8</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0001-1541 |
ispartof | AIChE journal, 2012-05, Vol.58 (5), p.1562-1569 |
issn | 0001-1541 1547-5905 |
language | eng |
recordid | cdi_proquest_miscellaneous_1022859437 |
source | Wiley Journals |
subjects | Applied sciences Boron boron fibres Chemical engineering Chemical reactions Chemical vapor deposition CVD dichloroborane Exact sciences and technology gas phase reaction kinetics Reaction kinetics Reactors |
title | Gas phase reaction kinetics in boron fibre production |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T14%3A14%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Gas%20phase%20reaction%20kinetics%20in%20boron%20fibre%20production&rft.jtitle=AIChE%20journal&rft.au=F%C4%B1rat,%20Fatih&rft.date=2012-05&rft.volume=58&rft.issue=5&rft.spage=1562&rft.epage=1569&rft.pages=1562-1569&rft.issn=0001-1541&rft.eissn=1547-5905&rft.coden=AICEAC&rft_id=info:doi/10.1002/aic.12671&rft_dat=%3Cproquest_cross%3E1022859437%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1009327560&rft_id=info:pmid/&rfr_iscdi=true |