Catalytic decomposition of methane on impregnated nickel based anodes with molecular-beam mass spectrometry and tunable synchrotron vacuum ultraviolet photoionization
The molecular-beam spectrometric technique coupled with tunable synchrotron vacuum ultraviolet photoionization is applied to reveal the catalytic decomposition of methane over Ni-based composites with and without impregnated nano-sized samaria-doped ceria (SDC) particles. It is shown that the coatin...
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| Veröffentlicht in: | International journal of hydrogen energy 2012-05, Vol.37 (10), p.8354-8359 |
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| container_end_page | 8359 |
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| container_issue | 10 |
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| container_title | International journal of hydrogen energy |
| container_volume | 37 |
| creator | Liu, Beibei Liu, Zhangbo Wang, Shuang Xia, Changrong Xie, Mingfeng Cheng, Zhanjun Li, Yuyang |
| description | The molecular-beam spectrometric technique coupled with tunable synchrotron vacuum ultraviolet photoionization is applied to reveal the catalytic decomposition of methane over Ni-based composites with and without impregnated nano-sized samaria-doped ceria (SDC) particles. It is shown that the coating of SDC nanoparticles not only decreases the decomposition temperature, but also increases the conversion ratio, thus indicating that those impregnated SDC nanoparticles are highly catalytically active for methane decomposition. In addition, C2H4 is observed when the impregnated Ni-SDC composites are used as the catalyst, suggesting that SDC coating also suppresses carbon deposition at the anodes of solid oxide fuel cells. |
| doi_str_mv | 10.1016/j.ijhydene.2012.02.120 |
| format | Article |
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It is shown that the coating of SDC nanoparticles not only decreases the decomposition temperature, but also increases the conversion ratio, thus indicating that those impregnated SDC nanoparticles are highly catalytically active for methane decomposition. In addition, C2H4 is observed when the impregnated Ni-SDC composites are used as the catalyst, suggesting that SDC coating also suppresses carbon deposition at the anodes of solid oxide fuel cells.</description><identifier>ISSN: 0360-3199</identifier><identifier>EISSN: 1879-3487</identifier><identifier>DOI: 10.1016/j.ijhydene.2012.02.120</identifier><identifier>CODEN: IJHEDX</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alternative fuels. Production and utilization ; Applied sciences ; Catalysis ; Catalytic decomposition ; Energy ; Exact sciences and technology ; Fuels ; Hydrogen ; Methane ; Solid oxide fuel cell ; Synchrotron vacuum ultraviolet photoionization mass spectrometry</subject><ispartof>International journal of hydrogen energy, 2012-05, Vol.37 (10), p.8354-8359</ispartof><rights>2012 Hydrogen Energy Publications, LLC.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-ba00a4b8de6861fdb2ca7c3619fc025105e96000e9c3bc2a16a130bc092223ec3</citedby><cites>FETCH-LOGICAL-c375t-ba00a4b8de6861fdb2ca7c3619fc025105e96000e9c3bc2a16a130bc092223ec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0360319912004843$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25846435$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Beibei</creatorcontrib><creatorcontrib>Liu, Zhangbo</creatorcontrib><creatorcontrib>Wang, Shuang</creatorcontrib><creatorcontrib>Xia, Changrong</creatorcontrib><creatorcontrib>Xie, Mingfeng</creatorcontrib><creatorcontrib>Cheng, Zhanjun</creatorcontrib><creatorcontrib>Li, Yuyang</creatorcontrib><title>Catalytic decomposition of methane on impregnated nickel based anodes with molecular-beam mass spectrometry and tunable synchrotron vacuum ultraviolet photoionization</title><title>International journal of hydrogen energy</title><description>The molecular-beam spectrometric technique coupled with tunable synchrotron vacuum ultraviolet photoionization is applied to reveal the catalytic decomposition of methane over Ni-based composites with and without impregnated nano-sized samaria-doped ceria (SDC) particles. It is shown that the coating of SDC nanoparticles not only decreases the decomposition temperature, but also increases the conversion ratio, thus indicating that those impregnated SDC nanoparticles are highly catalytically active for methane decomposition. In addition, C2H4 is observed when the impregnated Ni-SDC composites are used as the catalyst, suggesting that SDC coating also suppresses carbon deposition at the anodes of solid oxide fuel cells.</description><subject>Alternative fuels. Production and utilization</subject><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalytic decomposition</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fuels</subject><subject>Hydrogen</subject><subject>Methane</subject><subject>Solid oxide fuel cell</subject><subject>Synchrotron vacuum ultraviolet photoionization mass spectrometry</subject><issn>0360-3199</issn><issn>1879-3487</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkc-O0zAQxiMEEmXhFZAvSFzSHdtNmtxAFQtIK3GBszWZTKhLYgfbKQoPxHPiqsteOY1G85tv_nxF8VrCVoKsb09bezquPTveKpBqC2orFTwpNrLZt6XeNfunxQZ0DaWWbfu8eBHjCUDuYdduij8HTDiuyZLomfw0-2iT9U74QUycjuhY5MxOc-DvDhP3wln6waPoMOYEne85il82HcXkR6ZlxFB2jJOYMEYRZ6YUfJYKa4Z7kRaH3cgiro6OweeaE2ekZZnEMqaAZ5tVkpiPPvm8h_2Nl3VeFs8GHCO_eog3xbe7D18Pn8r7Lx8_H97fl6T3VSo7BMBd1_RcN7Uc-k4R7knXsh0IVCWh4rYGAG5Jd6RQ1ig1dAStUkoz6Zvi7VV3Dv7nwjGZyUbiccx_8Es0EpRqKiUbndH6ilLwMQYezBzshGHNkLkYY07mnzHmYowBZbIxufHNwwyMhOMQ0JGNj92qanb1TleZe3flOB98thxMJMuOuLchP9X03v5v1F_Vza1c</recordid><startdate>20120501</startdate><enddate>20120501</enddate><creator>Liu, Beibei</creator><creator>Liu, Zhangbo</creator><creator>Wang, Shuang</creator><creator>Xia, Changrong</creator><creator>Xie, Mingfeng</creator><creator>Cheng, Zhanjun</creator><creator>Li, Yuyang</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SU</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>L7M</scope></search><sort><creationdate>20120501</creationdate><title>Catalytic decomposition of methane on impregnated nickel based anodes with molecular-beam mass spectrometry and tunable synchrotron vacuum ultraviolet photoionization</title><author>Liu, Beibei ; Liu, Zhangbo ; Wang, Shuang ; Xia, Changrong ; Xie, Mingfeng ; Cheng, Zhanjun ; Li, Yuyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-ba00a4b8de6861fdb2ca7c3619fc025105e96000e9c3bc2a16a130bc092223ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Alternative fuels. Production and utilization</topic><topic>Applied sciences</topic><topic>Catalysis</topic><topic>Catalytic decomposition</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fuels</topic><topic>Hydrogen</topic><topic>Methane</topic><topic>Solid oxide fuel cell</topic><topic>Synchrotron vacuum ultraviolet photoionization mass spectrometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Beibei</creatorcontrib><creatorcontrib>Liu, Zhangbo</creatorcontrib><creatorcontrib>Wang, Shuang</creatorcontrib><creatorcontrib>Xia, Changrong</creatorcontrib><creatorcontrib>Xie, Mingfeng</creatorcontrib><creatorcontrib>Cheng, Zhanjun</creatorcontrib><creatorcontrib>Li, Yuyang</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>International journal of hydrogen energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Beibei</au><au>Liu, Zhangbo</au><au>Wang, Shuang</au><au>Xia, Changrong</au><au>Xie, Mingfeng</au><au>Cheng, Zhanjun</au><au>Li, Yuyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic decomposition of methane on impregnated nickel based anodes with molecular-beam mass spectrometry and tunable synchrotron vacuum ultraviolet photoionization</atitle><jtitle>International journal of hydrogen energy</jtitle><date>2012-05-01</date><risdate>2012</risdate><volume>37</volume><issue>10</issue><spage>8354</spage><epage>8359</epage><pages>8354-8359</pages><issn>0360-3199</issn><eissn>1879-3487</eissn><coden>IJHEDX</coden><abstract>The molecular-beam spectrometric technique coupled with tunable synchrotron vacuum ultraviolet photoionization is applied to reveal the catalytic decomposition of methane over Ni-based composites with and without impregnated nano-sized samaria-doped ceria (SDC) particles. It is shown that the coating of SDC nanoparticles not only decreases the decomposition temperature, but also increases the conversion ratio, thus indicating that those impregnated SDC nanoparticles are highly catalytically active for methane decomposition. In addition, C2H4 is observed when the impregnated Ni-SDC composites are used as the catalyst, suggesting that SDC coating also suppresses carbon deposition at the anodes of solid oxide fuel cells.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ijhydene.2012.02.120</doi><tpages>6</tpages></addata></record> |
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| ispartof | International journal of hydrogen energy, 2012-05, Vol.37 (10), p.8354-8359 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Alternative fuels. Production and utilization Applied sciences Catalysis Catalytic decomposition Energy Exact sciences and technology Fuels Hydrogen Methane Solid oxide fuel cell Synchrotron vacuum ultraviolet photoionization mass spectrometry |
| title | Catalytic decomposition of methane on impregnated nickel based anodes with molecular-beam mass spectrometry and tunable synchrotron vacuum ultraviolet photoionization |
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