Synthesis of atropisomeric 1-phenylpyrrole-derived amino alcohols: New chiral ligands

An efficient synthetic method has been developed for the preparation of a new family of atropisomeric amino alcohols with 1‐phenylpyrrole backbone. The synthesis is based on the different reactivities of the two carboxylic groups in optically active 1‐[2‐carboxy‐6‐(trifluoromethyl)phenyl]‐1H‐pyrrole...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2012-07, Vol.24 (7), p.532-542
Hauptverfasser:	Faigl, Ferenc, Mátravölgyi, Béla, Szöllősy, Áron, Czugler, Mátyás, Tárkányi, Gábor, Vékey, Károly, Kubinyi, Miklós
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino Alcohols - chemical synthesis Amino Alcohols - chemistry Chemistry Techniques, Synthetic chiral amino alcohol enantioselective reaction Ligands metalation Models, Molecular Molecular Conformation Optical Phenomena organocatalyst Pyrroles - chemistry Rotation site selective reaction Stereoisomerism Substrate Specificity Thermodynamics X-Ray Diffraction
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