{4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2: An Intramolecularly Coordinated Organotin(I) Compound with a Sn–Sn Single Bond, Its Disproportionation toward a Diorganostannylene and Elemental Tin, and Its Oxidation with PhI(OAc)2
Syntheses of the intramolecularly coordinated organotin(I) compound {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2 (2), which crystallized in two different pseudopolymorphs 2 and 2·C7H8, of the diorganostannylene {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2}2Sn (3) and of the organotin(II) acetate 4-t-Bu-2,6-[P(O)(O-i-Pr...
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| Veröffentlicht in: | Inorganic chemistry 2012-06, Vol.51 (12), p.6851-6859 |
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| container_title | Inorganic chemistry |
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| creator | Wagner, Michael Dietz, Christina Krabbe, Stefan Koller, Stephan G Strohmann, Carsten Jurkschat, Klaus |
| description | Syntheses of the intramolecularly coordinated organotin(I) compound {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2 (2), which crystallized in two different pseudopolymorphs 2 and 2·C7H8, of the diorganostannylene {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2}2Sn (3) and of the organotin(II) acetate 4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2SnOAc (4) are reported. The compounds were characterized by multinuclear NMR, IR (3 and 4), UV–vis spectroscopy (2), electrospray ionization mass spectrometry (3 and 4), and single-crystal X-ray diffraction analyses. Density functional theory calculations on compound 2 revealed the stabilizing effect of the intramolecular PO → Sn coordination. |
| doi_str_mv | 10.1021/ic3005954 |
| format | Article |
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The compounds were characterized by multinuclear NMR, IR (3 and 4), UV–vis spectroscopy (2), electrospray ionization mass spectrometry (3 and 4), and single-crystal X-ray diffraction analyses. 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Chem</addtitle><description>Syntheses of the intramolecularly coordinated organotin(I) compound {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2 (2), which crystallized in two different pseudopolymorphs 2 and 2·C7H8, of the diorganostannylene {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2}2Sn (3) and of the organotin(II) acetate 4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2SnOAc (4) are reported. The compounds were characterized by multinuclear NMR, IR (3 and 4), UV–vis spectroscopy (2), electrospray ionization mass spectrometry (3 and 4), and single-crystal X-ray diffraction analyses. 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Chem</addtitle><date>2012-06-18</date><risdate>2012</risdate><volume>51</volume><issue>12</issue><spage>6851</spage><epage>6859</epage><pages>6851-6859</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Syntheses of the intramolecularly coordinated organotin(I) compound {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2 (2), which crystallized in two different pseudopolymorphs 2 and 2·C7H8, of the diorganostannylene {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2}2Sn (3) and of the organotin(II) acetate 4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2SnOAc (4) are reported. The compounds were characterized by multinuclear NMR, IR (3 and 4), UV–vis spectroscopy (2), electrospray ionization mass spectrometry (3 and 4), and single-crystal X-ray diffraction analyses. Density functional theory calculations on compound 2 revealed the stabilizing effect of the intramolecular PO → Sn coordination.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>22624593</pmid><doi>10.1021/ic3005954</doi><tpages>9</tpages></addata></record> |
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| title | {4-t-Bu-2,6-[P(O)(O-i-Pr)2]2C6H2Sn}2: An Intramolecularly Coordinated Organotin(I) Compound with a Sn–Sn Single Bond, Its Disproportionation toward a Diorganostannylene and Elemental Tin, and Its Oxidation with PhI(OAc)2 |
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