Oxidation of Phosphorus Centers by Ferrate(VI): Spectral Observation of an Intermediate

The kinetics and mechanism for the oxidation of phosphite, hypophosphite, phenylphosphite, and trimethylphosphite by ferrate(VI) are reported. Hypophosphite is rapidly oxidized to phosphite which is slowly oxidized to phosphate, trimethylphosphite is oxidized to trimethylphosphate, and phenylphosphi...

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Veröffentlicht in:	Inorganic chemistry 2012-06, Vol.51 (12), p.6626-6632
Hauptverfasser:	Hightower, Shaun M, Lorenz, Bret B, Bernard, Jonathan G, Johnson, Michael D
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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