Ionic liquid-tethered nanoparticle/poly(ionic liquid) electrolytes for quasi-solid-state dye-sensitized solar cells
The quasi-solid-state dye-sensitized solar cells based on ionic liquid tethered TiO2/poly(ionic liquid) were fabricated and characterized. [Display omitted] ► We synthesize ionic liquid (IL) tethered TiO2 nanoparticles. ► We fabricate IL-TiO2/poly(ionic liquid) quasi-solid-state electrolytes. ► The...
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| Veröffentlicht in: | Journal of power sources 2012-06, Vol.207, p.216-221 |
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| creator | Chen, Xiaojian Li, Qing Zhao, Jie Qiu, Lihua Zhang, Yueguang Sun, Baoquan Yan, Feng |
| description | The quasi-solid-state dye-sensitized solar cells based on ionic liquid tethered TiO2/poly(ionic liquid) were fabricated and characterized. [Display omitted]
► We synthesize ionic liquid (IL) tethered TiO2 nanoparticles. ► We fabricate IL-TiO2/poly(ionic liquid) quasi-solid-state electrolytes. ► The quasi-solid-state dye-sensitized solar cells show a power conversion efficiency of 5.26%. ► The quasi-solid-state dye-sensitized solar cells show excellent long-term stability.
Ionic liquid-tethered TiO2 nanoparticles are prepared by tethering 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride (TMICl) to TiO2 nanoparticles. The quasi-solid-state dye-sensitized solar cells containing 15wt% of ionic liquid-tethered nanoparticle/poly(ionic liquid) hybrid electrolytes show an overall power conversion efficiency of ∼5.67% under simulated AM 1.5 solar spectrum irradiation at 50mWcm−2. Compared with unmodified TiO2 nanoparticles, ionic liquid-tethered nanoparticle based hybrid gel electrolytes show enhanced short circuit current density (Jsc), open circuit voltage (Voc), photoelectric conversion efficiency (η), and better long-term stability of the devices. These results indicate that the cells based on ionic liquid-tethered nanoparticle hybrid electrolytes could overcome the drawbacks of volatile liquid electrolytes, and offer a feasible method to fabricate quasi-solid-state DSSCs in future practical applications. |
| doi_str_mv | 10.1016/j.jpowsour.2012.01.143 |
| format | Article |
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► We synthesize ionic liquid (IL) tethered TiO2 nanoparticles. ► We fabricate IL-TiO2/poly(ionic liquid) quasi-solid-state electrolytes. ► The quasi-solid-state dye-sensitized solar cells show a power conversion efficiency of 5.26%. ► The quasi-solid-state dye-sensitized solar cells show excellent long-term stability.
Ionic liquid-tethered TiO2 nanoparticles are prepared by tethering 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride (TMICl) to TiO2 nanoparticles. The quasi-solid-state dye-sensitized solar cells containing 15wt% of ionic liquid-tethered nanoparticle/poly(ionic liquid) hybrid electrolytes show an overall power conversion efficiency of ∼5.67% under simulated AM 1.5 solar spectrum irradiation at 50mWcm−2. Compared with unmodified TiO2 nanoparticles, ionic liquid-tethered nanoparticle based hybrid gel electrolytes show enhanced short circuit current density (Jsc), open circuit voltage (Voc), photoelectric conversion efficiency (η), and better long-term stability of the devices. These results indicate that the cells based on ionic liquid-tethered nanoparticle hybrid electrolytes could overcome the drawbacks of volatile liquid electrolytes, and offer a feasible method to fabricate quasi-solid-state DSSCs in future practical applications.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2012.01.143</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Dye-sensitized solar cells ; Energy ; Exact sciences and technology ; Ionic liquid-tethered nanoparticle ; Nanocomposite ; Natural energy ; Photovoltaic conversion ; Poly(ionic liquids) ; Quasi-solid-state ; Solar cells. Photoelectrochemical cells ; Solar energy</subject><ispartof>Journal of power sources, 2012-06, Vol.207, p.216-221</ispartof><rights>2012 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-770fde291ed7fe89ec0e5c473793c2cae5482d9d3592ad04d294c8c052bdb9933</citedby><cites>FETCH-LOGICAL-c375t-770fde291ed7fe89ec0e5c473793c2cae5482d9d3592ad04d294c8c052bdb9933</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2012.01.143$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25789588$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Xiaojian</creatorcontrib><creatorcontrib>Li, Qing</creatorcontrib><creatorcontrib>Zhao, Jie</creatorcontrib><creatorcontrib>Qiu, Lihua</creatorcontrib><creatorcontrib>Zhang, Yueguang</creatorcontrib><creatorcontrib>Sun, Baoquan</creatorcontrib><creatorcontrib>Yan, Feng</creatorcontrib><title>Ionic liquid-tethered nanoparticle/poly(ionic liquid) electrolytes for quasi-solid-state dye-sensitized solar cells</title><title>Journal of power sources</title><description>The quasi-solid-state dye-sensitized solar cells based on ionic liquid tethered TiO2/poly(ionic liquid) were fabricated and characterized. [Display omitted]
► We synthesize ionic liquid (IL) tethered TiO2 nanoparticles. ► We fabricate IL-TiO2/poly(ionic liquid) quasi-solid-state electrolytes. ► The quasi-solid-state dye-sensitized solar cells show a power conversion efficiency of 5.26%. ► The quasi-solid-state dye-sensitized solar cells show excellent long-term stability.
Ionic liquid-tethered TiO2 nanoparticles are prepared by tethering 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride (TMICl) to TiO2 nanoparticles. The quasi-solid-state dye-sensitized solar cells containing 15wt% of ionic liquid-tethered nanoparticle/poly(ionic liquid) hybrid electrolytes show an overall power conversion efficiency of ∼5.67% under simulated AM 1.5 solar spectrum irradiation at 50mWcm−2. Compared with unmodified TiO2 nanoparticles, ionic liquid-tethered nanoparticle based hybrid gel electrolytes show enhanced short circuit current density (Jsc), open circuit voltage (Voc), photoelectric conversion efficiency (η), and better long-term stability of the devices. These results indicate that the cells based on ionic liquid-tethered nanoparticle hybrid electrolytes could overcome the drawbacks of volatile liquid electrolytes, and offer a feasible method to fabricate quasi-solid-state DSSCs in future practical applications.</description><subject>Applied sciences</subject><subject>Dye-sensitized solar cells</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Ionic liquid-tethered nanoparticle</subject><subject>Nanocomposite</subject><subject>Natural energy</subject><subject>Photovoltaic conversion</subject><subject>Poly(ionic liquids)</subject><subject>Quasi-solid-state</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkE1r3DAQhkVpodu0f6H4EkgOdvRhRdItISRtINBLexaKNKZaFMurkRO2v75aNi299TSgeead0UPIZ0YHRtnlxXbYLvkF81oGThkfKBvYKN6QDdNK9FxJ-ZZsqFC6V0qK9-QD4pZSypiiG4L3eY6-S3G3xtBXqD-hQOhmN-fFlRp9goslp_1Z_Ic77yCBr6W9V8BuyqXbrQ5jjzm1FKyuQhf20CPMGGv81RJby5XOQ0r4kbybXEL49FpPyI-72-83X_uHb1_ub64fei-UrO1aOgXghkFQE2gDnoL0oxLKCM-9AzlqHkwQ0nAX6Bi4Gb32VPLH8GiMECfk7Ji7lLxbAat9ini4wM2QV7SMcqqFomZs6OUR9SUjFpjsUuKTK_sG2YNlu7V_LNuDZUuZbZbb4OnrDofepam42Uf8O82l0kZq3birIwftw88RikUfYfYQYmkqbcjxf6t-Awsbmfs</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Chen, Xiaojian</creator><creator>Li, Qing</creator><creator>Zhao, Jie</creator><creator>Qiu, Lihua</creator><creator>Zhang, Yueguang</creator><creator>Sun, Baoquan</creator><creator>Yan, Feng</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope></search><sort><creationdate>20120601</creationdate><title>Ionic liquid-tethered nanoparticle/poly(ionic liquid) electrolytes for quasi-solid-state dye-sensitized solar cells</title><author>Chen, Xiaojian ; Li, Qing ; Zhao, Jie ; Qiu, Lihua ; Zhang, Yueguang ; Sun, Baoquan ; Yan, Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-770fde291ed7fe89ec0e5c473793c2cae5482d9d3592ad04d294c8c052bdb9933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Dye-sensitized solar cells</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Ionic liquid-tethered nanoparticle</topic><topic>Nanocomposite</topic><topic>Natural energy</topic><topic>Photovoltaic conversion</topic><topic>Poly(ionic liquids)</topic><topic>Quasi-solid-state</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Xiaojian</creatorcontrib><creatorcontrib>Li, Qing</creatorcontrib><creatorcontrib>Zhao, Jie</creatorcontrib><creatorcontrib>Qiu, Lihua</creatorcontrib><creatorcontrib>Zhang, Yueguang</creatorcontrib><creatorcontrib>Sun, Baoquan</creatorcontrib><creatorcontrib>Yan, Feng</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Xiaojian</au><au>Li, Qing</au><au>Zhao, Jie</au><au>Qiu, Lihua</au><au>Zhang, Yueguang</au><au>Sun, Baoquan</au><au>Yan, Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic liquid-tethered nanoparticle/poly(ionic liquid) electrolytes for quasi-solid-state dye-sensitized solar cells</atitle><jtitle>Journal of power sources</jtitle><date>2012-06-01</date><risdate>2012</risdate><volume>207</volume><spage>216</spage><epage>221</epage><pages>216-221</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>The quasi-solid-state dye-sensitized solar cells based on ionic liquid tethered TiO2/poly(ionic liquid) were fabricated and characterized. [Display omitted]
► We synthesize ionic liquid (IL) tethered TiO2 nanoparticles. ► We fabricate IL-TiO2/poly(ionic liquid) quasi-solid-state electrolytes. ► The quasi-solid-state dye-sensitized solar cells show a power conversion efficiency of 5.26%. ► The quasi-solid-state dye-sensitized solar cells show excellent long-term stability.
Ionic liquid-tethered TiO2 nanoparticles are prepared by tethering 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride (TMICl) to TiO2 nanoparticles. The quasi-solid-state dye-sensitized solar cells containing 15wt% of ionic liquid-tethered nanoparticle/poly(ionic liquid) hybrid electrolytes show an overall power conversion efficiency of ∼5.67% under simulated AM 1.5 solar spectrum irradiation at 50mWcm−2. Compared with unmodified TiO2 nanoparticles, ionic liquid-tethered nanoparticle based hybrid gel electrolytes show enhanced short circuit current density (Jsc), open circuit voltage (Voc), photoelectric conversion efficiency (η), and better long-term stability of the devices. These results indicate that the cells based on ionic liquid-tethered nanoparticle hybrid electrolytes could overcome the drawbacks of volatile liquid electrolytes, and offer a feasible method to fabricate quasi-solid-state DSSCs in future practical applications.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2012.01.143</doi><tpages>6</tpages></addata></record> |
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| subjects | Applied sciences Dye-sensitized solar cells Energy Exact sciences and technology Ionic liquid-tethered nanoparticle Nanocomposite Natural energy Photovoltaic conversion Poly(ionic liquids) Quasi-solid-state Solar cells. Photoelectrochemical cells Solar energy |
| title | Ionic liquid-tethered nanoparticle/poly(ionic liquid) electrolytes for quasi-solid-state dye-sensitized solar cells |
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