Optical and electrophysical properties of sulfur containing metal free phthalocyanine
Chemical and energy level structure, thin film formation as well as optical and electrophysical properties for metal free phthalocyanine containing rings with sulfur (2,3,9,10,16,17,23,24-tetra(5,6-dihydro-1,4-dithiin-2,3-dithiole)phthalocyanine) have been studied. Thermal heating of the substance p...
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| Veröffentlicht in: | Synthetic metals 2010-11, Vol.160 (21), p.2361-2365 |
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| creator | Kukhta, A.V. Kolesnik, E.E. Kukhta, I.N. Pochtenny, A.E. Dolgiy, V.K. Mousdis, G.A. Psaroudakis, N. |
| description | Chemical and energy level structure, thin film formation as well as optical and electrophysical properties for metal free phthalocyanine containing rings with sulfur (2,3,9,10,16,17,23,24-tetra(5,6-dihydro-1,4-dithiin-2,3-dithiole)phthalocyanine) have been studied. Thermal heating of the substance powder results in rather good evaporation. Smooth and glasslike homogeneous thin film with a metallic lustre has been obtained. The absorption spectrum of the film with a maximum at 680
nm is strongly broadened. The additional sulfur containing groups are bended forming a stool like structure. Phthalocyanine skeleton and the nearest not bended sulfur containing ring is involved into longwave transition. HOMO and LUMO are at −5.14 and −3.10
eV correspondingly. Vertical ionization potential of free molecule is 5.99
eV and adiabatic one is 5.90
eV. The dipole moment of this molecule is 4.85
D. The predominance of doped conductivity confirms the amorphism of the vacuum deposited film. The mechanism of conductivity was found to be hopping. |
| doi_str_mv | 10.1016/j.synthmet.2010.09.012 |
| format | Article |
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nm is strongly broadened. The additional sulfur containing groups are bended forming a stool like structure. Phthalocyanine skeleton and the nearest not bended sulfur containing ring is involved into longwave transition. HOMO and LUMO are at −5.14 and −3.10
eV correspondingly. Vertical ionization potential of free molecule is 5.99
eV and adiabatic one is 5.90
eV. The dipole moment of this molecule is 4.85
D. The predominance of doped conductivity confirms the amorphism of the vacuum deposited film. The mechanism of conductivity was found to be hopping.</description><identifier>ISSN: 0379-6779</identifier><identifier>EISSN: 1879-3290</identifier><identifier>DOI: 10.1016/j.synthmet.2010.09.012</identifier><identifier>CODEN: SYMEDZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Conductivity ; DFT ; Dipole moment ; Energy levels ; Evaporation ; Exact sciences and technology ; Lustre ; Optical properties ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of specific thin films ; Phthalocyanine ; Physics ; Polymers; organic compounds ; Stools ; Sulfur ; Thin film ; Thin films</subject><ispartof>Synthetic metals, 2010-11, Vol.160 (21), p.2361-2365</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c441t-a01bf76277d25266537cb3fe93e83564bf6629df8f347dba729513e5880d9ccf3</citedby><cites>FETCH-LOGICAL-c441t-a01bf76277d25266537cb3fe93e83564bf6629df8f347dba729513e5880d9ccf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.synthmet.2010.09.012$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23447774$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kukhta, A.V.</creatorcontrib><creatorcontrib>Kolesnik, E.E.</creatorcontrib><creatorcontrib>Kukhta, I.N.</creatorcontrib><creatorcontrib>Pochtenny, A.E.</creatorcontrib><creatorcontrib>Dolgiy, V.K.</creatorcontrib><creatorcontrib>Mousdis, G.A.</creatorcontrib><creatorcontrib>Psaroudakis, N.</creatorcontrib><title>Optical and electrophysical properties of sulfur containing metal free phthalocyanine</title><title>Synthetic metals</title><description>Chemical and energy level structure, thin film formation as well as optical and electrophysical properties for metal free phthalocyanine containing rings with sulfur (2,3,9,10,16,17,23,24-tetra(5,6-dihydro-1,4-dithiin-2,3-dithiole)phthalocyanine) have been studied. Thermal heating of the substance powder results in rather good evaporation. Smooth and glasslike homogeneous thin film with a metallic lustre has been obtained. The absorption spectrum of the film with a maximum at 680
nm is strongly broadened. The additional sulfur containing groups are bended forming a stool like structure. Phthalocyanine skeleton and the nearest not bended sulfur containing ring is involved into longwave transition. HOMO and LUMO are at −5.14 and −3.10
eV correspondingly. Vertical ionization potential of free molecule is 5.99
eV and adiabatic one is 5.90
eV. The dipole moment of this molecule is 4.85
D. The predominance of doped conductivity confirms the amorphism of the vacuum deposited film. The mechanism of conductivity was found to be hopping.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Conductivity</subject><subject>DFT</subject><subject>Dipole moment</subject><subject>Energy levels</subject><subject>Evaporation</subject><subject>Exact sciences and technology</subject><subject>Lustre</subject><subject>Optical properties</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of specific thin films</subject><subject>Phthalocyanine</subject><subject>Physics</subject><subject>Polymers; organic compounds</subject><subject>Stools</subject><subject>Sulfur</subject><subject>Thin film</subject><subject>Thin films</subject><issn>0379-6779</issn><issn>1879-3290</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWD_-guxF8NKaj91kc1OKX1DoxZ5Dmp3YlO3umqRC_71TW716yjB5Ju_kIeSG0QmjTN6vJ2nX5dUG8oRTbFI9oYyfkBGrlR4LrukpGVGBtVRKn5OLlNaUUqZ5NSKL-ZCDs21hu6aAFlyO_bDapZ_egDXEHCAVvS_StvXbWLi-yzZ0ofsoMBIpHwGKYZVXtu3dzuINXJEzb9sE18fzkiyen96nr-PZ_OVt-jgbu7JkeWwpW3oluVINr7iUlVBuKTxoAbWoZLn0UnLd-NqLUjVLq7iumICqrmmjnfPiktwd3sVNP7eQstmE5KBtbQf9Nhn0o6VGGxJReUBd7FOK4M0Qw8bGHUJ7Tpq1-fVo9h4N1QYncfD2mGETSvHRdi6kv2kuylIpVSL3cOAAP_wVIJrkAnQOmhBRq2n68F_UN4gtjhU</recordid><startdate>20101101</startdate><enddate>20101101</enddate><creator>Kukhta, A.V.</creator><creator>Kolesnik, E.E.</creator><creator>Kukhta, I.N.</creator><creator>Pochtenny, A.E.</creator><creator>Dolgiy, V.K.</creator><creator>Mousdis, G.A.</creator><creator>Psaroudakis, N.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20101101</creationdate><title>Optical and electrophysical properties of sulfur containing metal free phthalocyanine</title><author>Kukhta, A.V. ; Kolesnik, E.E. ; Kukhta, I.N. ; Pochtenny, A.E. ; Dolgiy, V.K. ; Mousdis, G.A. ; Psaroudakis, N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c441t-a01bf76277d25266537cb3fe93e83564bf6629df8f347dba729513e5880d9ccf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Conductivity</topic><topic>DFT</topic><topic>Dipole moment</topic><topic>Energy levels</topic><topic>Evaporation</topic><topic>Exact sciences and technology</topic><topic>Lustre</topic><topic>Optical properties</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Optical properties of specific thin films</topic><topic>Phthalocyanine</topic><topic>Physics</topic><topic>Polymers; organic compounds</topic><topic>Stools</topic><topic>Sulfur</topic><topic>Thin film</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kukhta, A.V.</creatorcontrib><creatorcontrib>Kolesnik, E.E.</creatorcontrib><creatorcontrib>Kukhta, I.N.</creatorcontrib><creatorcontrib>Pochtenny, A.E.</creatorcontrib><creatorcontrib>Dolgiy, V.K.</creatorcontrib><creatorcontrib>Mousdis, G.A.</creatorcontrib><creatorcontrib>Psaroudakis, N.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Synthetic metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kukhta, A.V.</au><au>Kolesnik, E.E.</au><au>Kukhta, I.N.</au><au>Pochtenny, A.E.</au><au>Dolgiy, V.K.</au><au>Mousdis, G.A.</au><au>Psaroudakis, N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optical and electrophysical properties of sulfur containing metal free phthalocyanine</atitle><jtitle>Synthetic metals</jtitle><date>2010-11-01</date><risdate>2010</risdate><volume>160</volume><issue>21</issue><spage>2361</spage><epage>2365</epage><pages>2361-2365</pages><issn>0379-6779</issn><eissn>1879-3290</eissn><coden>SYMEDZ</coden><abstract>Chemical and energy level structure, thin film formation as well as optical and electrophysical properties for metal free phthalocyanine containing rings with sulfur (2,3,9,10,16,17,23,24-tetra(5,6-dihydro-1,4-dithiin-2,3-dithiole)phthalocyanine) have been studied. Thermal heating of the substance powder results in rather good evaporation. Smooth and glasslike homogeneous thin film with a metallic lustre has been obtained. The absorption spectrum of the film with a maximum at 680
nm is strongly broadened. The additional sulfur containing groups are bended forming a stool like structure. Phthalocyanine skeleton and the nearest not bended sulfur containing ring is involved into longwave transition. HOMO and LUMO are at −5.14 and −3.10
eV correspondingly. Vertical ionization potential of free molecule is 5.99
eV and adiabatic one is 5.90
eV. The dipole moment of this molecule is 4.85
D. The predominance of doped conductivity confirms the amorphism of the vacuum deposited film. The mechanism of conductivity was found to be hopping.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.synthmet.2010.09.012</doi><tpages>5</tpages></addata></record> |
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| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Conductivity DFT Dipole moment Energy levels Evaporation Exact sciences and technology Lustre Optical properties Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of specific thin films Phthalocyanine Physics Polymers organic compounds Stools Sulfur Thin film Thin films |
| title | Optical and electrophysical properties of sulfur containing metal free phthalocyanine |
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