Thermal decomposition behavior and mechanical properties of elastomeric composites based on polyolefinic thermoplastic elastomer and organomontmorillonite
The elastomeric composites based on organomontmorillonite (OMMT) and Santoprene thermoplastic elastomer were prepared by melt processing. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer for the composite system. By adding optimum content of PP-g-MA, the fracture surface...
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| Veröffentlicht in: | Journal of polymer research 2012, Vol.19 (1), p.1-13, Article 9750 |
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| creator | Saikrasun, Sunan Amornsakchai, Taweechai |
| description | The elastomeric composites based on organomontmorillonite (OMMT) and Santoprene thermoplastic elastomer were prepared by melt processing. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer for the composite system. By adding optimum content of PP-g-MA, the fracture surface of the composites observed by SEM was smoothened as a result from compatibilizing effect. From XRD results, the measured
d
-spacing data proved a good dispersion of nanoclay along with compatibilizer. Thermal decomposition behavior of the neat components and its composites obtained from simultaneous TG and DSC profiles indicated that the incorporation of OMMT into the matrix polymer improved the thermal stability in air but not in nitrogen. No significant change in thermal stability of the composites with addition of PP-g-MA. The incorporation of clay significantly enhanced in dynamic mechanical and tensile properties of the composites. The dynamic storage modulus, tensile modulus and yield stress of the composites with the presence of PP-g-MA were remarkably improved. |
| doi_str_mv | 10.1007/s10965-011-9750-z |
| format | Article |
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d
-spacing data proved a good dispersion of nanoclay along with compatibilizer. Thermal decomposition behavior of the neat components and its composites obtained from simultaneous TG and DSC profiles indicated that the incorporation of OMMT into the matrix polymer improved the thermal stability in air but not in nitrogen. No significant change in thermal stability of the composites with addition of PP-g-MA. The incorporation of clay significantly enhanced in dynamic mechanical and tensile properties of the composites. The dynamic storage modulus, tensile modulus and yield stress of the composites with the presence of PP-g-MA were remarkably improved.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-011-9750-z</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Compatibility ; Dynamics ; Elastomers ; Industrial Chemistry/Chemical Engineering ; Nanostructure ; Original Paper ; Polymer matrix composites ; Polymer Sciences ; Thermal decomposition ; Thermal stability ; Thermoplastic elastomers</subject><ispartof>Journal of polymer research, 2012, Vol.19 (1), p.1-13, Article 9750</ispartof><rights>Springer Science+Business Media B.V. 2011</rights><rights>Springer Science+Business Media B.V. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-98ecc50f3b069b261d05dbfa6763f7d0939086c7d101c27eb67d2ca316aa41fc3</citedby><cites>FETCH-LOGICAL-c348t-98ecc50f3b069b261d05dbfa6763f7d0939086c7d101c27eb67d2ca316aa41fc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-011-9750-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-011-9750-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Saikrasun, Sunan</creatorcontrib><creatorcontrib>Amornsakchai, Taweechai</creatorcontrib><title>Thermal decomposition behavior and mechanical properties of elastomeric composites based on polyolefinic thermoplastic elastomer and organomontmorillonite</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>The elastomeric composites based on organomontmorillonite (OMMT) and Santoprene thermoplastic elastomer were prepared by melt processing. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer for the composite system. By adding optimum content of PP-g-MA, the fracture surface of the composites observed by SEM was smoothened as a result from compatibilizing effect. From XRD results, the measured
d
-spacing data proved a good dispersion of nanoclay along with compatibilizer. Thermal decomposition behavior of the neat components and its composites obtained from simultaneous TG and DSC profiles indicated that the incorporation of OMMT into the matrix polymer improved the thermal stability in air but not in nitrogen. No significant change in thermal stability of the composites with addition of PP-g-MA. The incorporation of clay significantly enhanced in dynamic mechanical and tensile properties of the composites. The dynamic storage modulus, tensile modulus and yield stress of the composites with the presence of PP-g-MA were remarkably improved.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Compatibility</subject><subject>Dynamics</subject><subject>Elastomers</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nanostructure</subject><subject>Original Paper</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Thermal decomposition</subject><subject>Thermal stability</subject><subject>Thermoplastic elastomers</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kc1q3TAQhU1JoPl7gOxEV9k4kWRbspYhtEkh0E2yFrI8zlWQNa7kW0gepU-bub1tCoWuJDHnOzOjU1Xngl8KzvVVEdyoruZC1EZ3vH79UB2JTsu6N013QHcuJVUU_1gdl_LMeddp1R9VPx82kGcX2Qge5wVLWAMmNsDG_QiYmUsjm8FvXAqeVEvGBfIaoDCcGERXVpwhB8_-0FQZXIGRkcuC8QUjTIFgtu4a4bJD6PWO_uqA-cklnDGtM-YQIyYyOq0OJxcLnP0-T6rHL58fbu7q-2-3X2-u72vftP1amx687_jUDFyZQSox8m4cJqe0aiY9ctMY3iuvR8GFlxoGpUfpXSOUc62YfHNSXex9abnvWyirnUPxEKNLgNtiiaOvNUo2JP30j_QZtznRdNYIYWTbtj2JxF7kM5aSYbJLDrPLL-Rkd2HZfViWwrK7sOwrMXLPFNKmJ8h_jf8PvQEJHp1O</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>Saikrasun, Sunan</creator><creator>Amornsakchai, Taweechai</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>2012</creationdate><title>Thermal decomposition behavior and mechanical properties of elastomeric composites based on polyolefinic thermoplastic elastomer and organomontmorillonite</title><author>Saikrasun, Sunan ; Amornsakchai, Taweechai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-98ecc50f3b069b261d05dbfa6763f7d0939086c7d101c27eb67d2ca316aa41fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Compatibility</topic><topic>Dynamics</topic><topic>Elastomers</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nanostructure</topic><topic>Original Paper</topic><topic>Polymer matrix composites</topic><topic>Polymer Sciences</topic><topic>Thermal decomposition</topic><topic>Thermal stability</topic><topic>Thermoplastic elastomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saikrasun, Sunan</creatorcontrib><creatorcontrib>Amornsakchai, Taweechai</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saikrasun, Sunan</au><au>Amornsakchai, Taweechai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal decomposition behavior and mechanical properties of elastomeric composites based on polyolefinic thermoplastic elastomer and organomontmorillonite</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2012</date><risdate>2012</risdate><volume>19</volume><issue>1</issue><spage>1</spage><epage>13</epage><pages>1-13</pages><artnum>9750</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>The elastomeric composites based on organomontmorillonite (OMMT) and Santoprene thermoplastic elastomer were prepared by melt processing. Maleic anhydride grafted polypropylene (PP-g-MA) was used as a compatibilizer for the composite system. By adding optimum content of PP-g-MA, the fracture surface of the composites observed by SEM was smoothened as a result from compatibilizing effect. From XRD results, the measured
d
-spacing data proved a good dispersion of nanoclay along with compatibilizer. Thermal decomposition behavior of the neat components and its composites obtained from simultaneous TG and DSC profiles indicated that the incorporation of OMMT into the matrix polymer improved the thermal stability in air but not in nitrogen. No significant change in thermal stability of the composites with addition of PP-g-MA. The incorporation of clay significantly enhanced in dynamic mechanical and tensile properties of the composites. The dynamic storage modulus, tensile modulus and yield stress of the composites with the presence of PP-g-MA were remarkably improved.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-011-9750-z</doi><tpages>13</tpages></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Compatibility Dynamics Elastomers Industrial Chemistry/Chemical Engineering Nanostructure Original Paper Polymer matrix composites Polymer Sciences Thermal decomposition Thermal stability Thermoplastic elastomers |
| title | Thermal decomposition behavior and mechanical properties of elastomeric composites based on polyolefinic thermoplastic elastomer and organomontmorillonite |
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