Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors

Composite electrodes prepared by vertically aligned multi-walled carbon nanotubes (MWCNTs) coated with hydrous ruthenium dioxide (RuO2·nH2O) have previously been used in various supercapacitors. The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can r...

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Veröffentlicht in:Carbon (New York) 2012-04, Vol.50 (5), p.1740-1747
Hauptverfasser: Hsieh, Tung-Feng, Chuang, Chia-Chih, Chen, Wen-Jauh, Huang, Jin-Hua, Chen, Wei-Ting, Shu, Chi-Min
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container_end_page 1747
container_issue 5
container_start_page 1740
container_title Carbon (New York)
container_volume 50
creator Hsieh, Tung-Feng
Chuang, Chia-Chih
Chen, Wen-Jauh
Huang, Jin-Hua
Chen, Wei-Ting
Shu, Chi-Min
description Composite electrodes prepared by vertically aligned multi-walled carbon nanotubes (MWCNTs) coated with hydrous ruthenium dioxide (RuO2·nH2O) have previously been used in various supercapacitors. The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can reach up to 1652F/g at a scan rate of 10mV/s, which is larger than that of RuO2·nH2O/Ti or MWCNT/Ti. In this study, a RuO2·nH2O/MWCNT/Ti composite electrode was examined by X-ray photoelectron spectroscopy, which revealed the existence of hydrous ruthenium dioxide in the Ti current collector. The capacitive behavior of the electrode was analyzed by cyclic voltammetry and the galvanostatic charge–discharge method, and the morphology of the composite electrode was examined by scanning electron microscopy.
doi_str_mv 10.1016/j.carbon.2011.12.017
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subjects Capacitance
Capacitors
Carbon
Cross-disciplinary physics: materials science
rheology
Dioxides
Electrodes
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
Materials science
Physics
Ruthenium
Specific materials
Supercapacitors
Titanium
title Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors
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