Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors
Composite electrodes prepared by vertically aligned multi-walled carbon nanotubes (MWCNTs) coated with hydrous ruthenium dioxide (RuO2·nH2O) have previously been used in various supercapacitors. The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can r...
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Veröffentlicht in: | Carbon (New York) 2012-04, Vol.50 (5), p.1740-1747 |
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creator | Hsieh, Tung-Feng Chuang, Chia-Chih Chen, Wen-Jauh Huang, Jin-Hua Chen, Wei-Ting Shu, Chi-Min |
description | Composite electrodes prepared by vertically aligned multi-walled carbon nanotubes (MWCNTs) coated with hydrous ruthenium dioxide (RuO2·nH2O) have previously been used in various supercapacitors. The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can reach up to 1652F/g at a scan rate of 10mV/s, which is larger than that of RuO2·nH2O/Ti or MWCNT/Ti. In this study, a RuO2·nH2O/MWCNT/Ti composite electrode was examined by X-ray photoelectron spectroscopy, which revealed the existence of hydrous ruthenium dioxide in the Ti current collector. The capacitive behavior of the electrode was analyzed by cyclic voltammetry and the galvanostatic charge–discharge method, and the morphology of the composite electrode was examined by scanning electron microscopy. |
doi_str_mv | 10.1016/j.carbon.2011.12.017 |
format | Article |
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The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can reach up to 1652F/g at a scan rate of 10mV/s, which is larger than that of RuO2·nH2O/Ti or MWCNT/Ti. In this study, a RuO2·nH2O/MWCNT/Ti composite electrode was examined by X-ray photoelectron spectroscopy, which revealed the existence of hydrous ruthenium dioxide in the Ti current collector. The capacitive behavior of the electrode was analyzed by cyclic voltammetry and the galvanostatic charge–discharge method, and the morphology of the composite electrode was examined by scanning electron microscopy.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2011.12.017</identifier><identifier>CODEN: CRBNAH</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Capacitance ; Capacitors ; Carbon ; Cross-disciplinary physics: materials science; rheology ; Dioxides ; Electrodes ; Exact sciences and technology ; Fullerenes and related materials; diamonds, graphite ; Materials science ; Physics ; Ruthenium ; Specific materials ; Supercapacitors ; Titanium</subject><ispartof>Carbon (New York), 2012-04, Vol.50 (5), p.1740-1747</ispartof><rights>2011</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c369t-ac1f15e3462c22c35574d9f92add0dfd64cd9e3a54600f65bf23de58474dffb03</citedby><cites>FETCH-LOGICAL-c369t-ac1f15e3462c22c35574d9f92add0dfd64cd9e3a54600f65bf23de58474dffb03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.carbon.2011.12.017$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25872399$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hsieh, Tung-Feng</creatorcontrib><creatorcontrib>Chuang, Chia-Chih</creatorcontrib><creatorcontrib>Chen, Wen-Jauh</creatorcontrib><creatorcontrib>Huang, Jin-Hua</creatorcontrib><creatorcontrib>Chen, Wei-Ting</creatorcontrib><creatorcontrib>Shu, Chi-Min</creatorcontrib><title>Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors</title><title>Carbon (New York)</title><description>Composite electrodes prepared by vertically aligned multi-walled carbon nanotubes (MWCNTs) coated with hydrous ruthenium dioxide (RuO2·nH2O) have previously been used in various supercapacitors. The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can reach up to 1652F/g at a scan rate of 10mV/s, which is larger than that of RuO2·nH2O/Ti or MWCNT/Ti. In this study, a RuO2·nH2O/MWCNT/Ti composite electrode was examined by X-ray photoelectron spectroscopy, which revealed the existence of hydrous ruthenium dioxide in the Ti current collector. The capacitive behavior of the electrode was analyzed by cyclic voltammetry and the galvanostatic charge–discharge method, and the morphology of the composite electrode was examined by scanning electron microscopy.</description><subject>Capacitance</subject><subject>Capacitors</subject><subject>Carbon</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Dioxides</subject><subject>Electrodes</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>Materials science</subject><subject>Physics</subject><subject>Ruthenium</subject><subject>Specific materials</subject><subject>Supercapacitors</subject><subject>Titanium</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-Aw-9CF7azUebthdBFnUFwYteDWkywSzdZk1Sdf-9Wbt49DQMPDMv74PQJcEFwYQv1oWSvnNDQTEhBaEFJvURmpGmZjlrWnKMZhjjJueUslN0FsI6rWVDyhl6W-20d2PI_BjfYbDjJtPWfVsNi83YR5t_yb4HnU0B-SAHF8cOFtFG-UtDDyp6pyFkxvksjFvwSm6lstH5cI5OjOwDXBzmHL3e370sV_nT88Pj8vYpV4y3MZeKGFIBKzlVlCpWVXWpW9NSqTXWRvNS6RaYrEqOseFVZyjTUDVlwozpMJuj6-nv1ruPEUIUGxsU9L0cILUTSVPLGWe0Tmg5ocq7EDwYsfV2I_0uQXuOi7WY2oq9TkGoSDrT2dUhQQYle-PloGz4u6VVU1PWtom7mThIdT8teBGUhUGBtj6ZEtrZ_4N-AHqNj7s</recordid><startdate>20120401</startdate><enddate>20120401</enddate><creator>Hsieh, Tung-Feng</creator><creator>Chuang, Chia-Chih</creator><creator>Chen, Wen-Jauh</creator><creator>Huang, Jin-Hua</creator><creator>Chen, Wei-Ting</creator><creator>Shu, Chi-Min</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120401</creationdate><title>Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors</title><author>Hsieh, Tung-Feng ; Chuang, Chia-Chih ; Chen, Wen-Jauh ; Huang, Jin-Hua ; Chen, Wei-Ting ; Shu, Chi-Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c369t-ac1f15e3462c22c35574d9f92add0dfd64cd9e3a54600f65bf23de58474dffb03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Capacitance</topic><topic>Capacitors</topic><topic>Carbon</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Dioxides</topic><topic>Electrodes</topic><topic>Exact sciences and technology</topic><topic>Fullerenes and related materials; diamonds, graphite</topic><topic>Materials science</topic><topic>Physics</topic><topic>Ruthenium</topic><topic>Specific materials</topic><topic>Supercapacitors</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hsieh, Tung-Feng</creatorcontrib><creatorcontrib>Chuang, Chia-Chih</creatorcontrib><creatorcontrib>Chen, Wen-Jauh</creatorcontrib><creatorcontrib>Huang, Jin-Hua</creatorcontrib><creatorcontrib>Chen, Wei-Ting</creatorcontrib><creatorcontrib>Shu, Chi-Min</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hsieh, Tung-Feng</au><au>Chuang, Chia-Chih</au><au>Chen, Wen-Jauh</au><au>Huang, Jin-Hua</au><au>Chen, Wei-Ting</au><au>Shu, Chi-Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors</atitle><jtitle>Carbon (New York)</jtitle><date>2012-04-01</date><risdate>2012</risdate><volume>50</volume><issue>5</issue><spage>1740</spage><epage>1747</epage><pages>1740-1747</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>Composite electrodes prepared by vertically aligned multi-walled carbon nanotubes (MWCNTs) coated with hydrous ruthenium dioxide (RuO2·nH2O) have previously been used in various supercapacitors. The specific capacitance when using RuO2·nH2O/MWCNT/Ti as electrodes in 1.0M H2SO4 aqueous solution can reach up to 1652F/g at a scan rate of 10mV/s, which is larger than that of RuO2·nH2O/Ti or MWCNT/Ti. In this study, a RuO2·nH2O/MWCNT/Ti composite electrode was examined by X-ray photoelectron spectroscopy, which revealed the existence of hydrous ruthenium dioxide in the Ti current collector. The capacitive behavior of the electrode was analyzed by cyclic voltammetry and the galvanostatic charge–discharge method, and the morphology of the composite electrode was examined by scanning electron microscopy.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2011.12.017</doi><tpages>8</tpages></addata></record> |
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subjects | Capacitance Capacitors Carbon Cross-disciplinary physics: materials science rheology Dioxides Electrodes Exact sciences and technology Fullerenes and related materials diamonds, graphite Materials science Physics Ruthenium Specific materials Supercapacitors Titanium |
title | Hydrous ruthenium dioxide/multi-walled carbon-nanotube/titanium electrodes for supercapacitors |
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