Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts

Herein, the development of visible light-mediated atom transfer radical addition (ATRA) of haloalkanes onto alkenes and alkynes using the reductive and oxidative quenching of [Ir{dF(CF3)ppy}2(dtbbpy)]PF6 and [Ru(bpy)3]Cl2 is presented. Initial investigations indicated that the oxidative quenching of...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-05, Vol.134 (21), p.8875-8884
Hauptverfasser:	Wallentin, Carl-Johan, Nguyen, John D, Finkbeiner, Peter, Stephenson, Corey R. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Alkylation Alkynes - chemistry Catalysis Free Radicals - chemistry Halogenation Light Oxidation-Reduction Photochemical Processes Solvents - chemistry
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