Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state

A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substitue...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (50), p.6241-6243
Hauptverfasser: Blas-Ferrando, Vicente M, Ortiz, Javier, Bouissane, Latifa, Ohkubo, Kei, Fukuzumi, Shunichi, Fernández-Lázaro, Fernando, Sastre-Santos, Angela
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container_issue 50
container_start_page 6241
container_title Chemical communications (Cambridge, England)
container_volume 48
creator Blas-Ferrando, Vicente M
Ortiz, Javier
Bouissane, Latifa
Ohkubo, Kei
Fukuzumi, Shunichi
Fernández-Lázaro, Fernando
Sastre-Santos, Angela
description A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.
doi_str_mv 10.1039/c2cc31087b
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Imides - chemistry
Indoles - chemistry
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Perylene - analogs & derivatives
Perylene - chemistry
Zinc - chemistry
title Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state
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