Temperature Dependence of Surface Nanobubbles

The temperature dependence of nanobubbles was investigated experimentally using atomic force microscopy. By scanning the same area of the surface at temperatures from 51 °C to 25 °C it was possible to track geometrical changes of individual nanobubbles as the temperature was decreased. Interestingly...

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Veröffentlicht in:Chemphyschem 2012-06, Vol.13 (8), p.2213-2217
Hauptverfasser: Berkelaar, Robin P., Seddon, James R. T., Zandvliet, Harold J. W., Lohse, Detlef
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container_issue 8
container_start_page 2213
container_title Chemphyschem
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creator Berkelaar, Robin P.
Seddon, James R. T.
Zandvliet, Harold J. W.
Lohse, Detlef
description The temperature dependence of nanobubbles was investigated experimentally using atomic force microscopy. By scanning the same area of the surface at temperatures from 51 °C to 25 °C it was possible to track geometrical changes of individual nanobubbles as the temperature was decreased. Interestingly, nanobubbles of the same size react differently to this temperature change; some grow whilst others shrink. This effect cannot be attributed to Ostwald ripening, since the growth and shrinkage of nanobubbles appears to occur in distinct patches on the substrate. The total nanobubble volume per unit area shows a maximum around 33 °C, which is comparable with literature where experiments were carried out with increasing temperature. This underlines the stability of surface nanobubbles. Some like it hot: The temperature dependence of nanobubbles is investigated experimentally using atomic force microscopy. By scanning the same area of the surface at different temperatures, it is possible to track geometrical changes of individual nanobubbles as the temperature is decreased (see picture for the distribution at 45 °C). This underlines the stability of surface nanobubbles.
doi_str_mv 10.1002/cphc.201100808
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subjects atomic force microscopy
nanobubbles
nanostructures
surface analysis
temperature dependence
title Temperature Dependence of Surface Nanobubbles
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