Simple Ligand Effects Switch a Hydrogenase Mimic between H2 and O2 Activation

Herein, we report a [NiRu] biomimetic system for O2‐tolerant [NiFe]hydrogenases and demonstrate that electron donation to the [NiRu] center can switch the system between the activation of H2 and O2 through simple ligand effects by using hexamethylbenzene and pentamethylcyclopentadienyl ligands, resp...

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