Sterically Congested Adamantylnaphthalene Quinone Methides

Five new (2-adamantyl)naphthol derivatives (5–9, quinone methide precursors, QMP) were synthesized and their photochemical reactivity was investigated by preparative photolyses, fluorescence spectroscopy, and laser flash photolysis (LFP). Excitation of QMP 5 to S1 leads to efficient excited state in...

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Veröffentlicht in:	Journal of organic chemistry 2012-05, Vol.77 (10), p.4596-4610
Hauptverfasser:	Veljković, Jelena, Uzelac, Lidija, Molčanov, Krešimir, Mlinarić-Majerski, Kata, Kralj, Marijeta, Wan, Peter, Basarić, Nikola
Format:	Artikel
Sprache:	eng
Schlagworte:	Adamantane - analogs & derivatives Adamantane - chemistry Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Antineoplastic Agents - chemical synthesis Antineoplastic Agents - chemistry Antineoplastic Agents - pharmacology Cell Line, Tumor Cell Proliferation - drug effects Chemical reactivity Chemistry Condensed benzenic and aromatic compounds Crystallography, X-Ray Exact sciences and technology General and physical chemistry Humans Indolequinones - chemical synthesis Indolequinones - chemistry Molecular Structure Naphthols - chemistry Organic chemistry Photochemistry Photolysis Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Preparations and properties Prodrugs - chemical synthesis Prodrugs - chemistry Reactivity and mechanisms Spectrometry, Fluorescence Stereoisomerism
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