cis-Bis[(4-nitro-phen-yl)cyanamido-κN(1)]bis-(1,10-phenanthroline-κ(2)N,N')nickel(II) methanol monosolvate

cis-Bis[(4-nitro-phen-yl)cyanamido-κN(1)]bis-(1,10-phenanthroline-κ(2)N,N')nickel(II) methanol monosolvate

In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa-hedral geometry and is chelated by two phenanthroline ligands and two phenyl-cyanamide groups which occupy cis positions. The (4-nitro-phen-yl)cyanamide anions act...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-04, Vol.68 (Pt 4), p.m417-m418
Hauptverfasser: Chiniforoshan, Hossein, Jazestani, Mehdi, Notash, Behrouz
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container_issue Pt 4
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container_title Acta crystallographica. Section E, Structure reports online
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creator Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
description In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa-hedral geometry and is chelated by two phenanthroline ligands and two phenyl-cyanamide groups which occupy cis positions. The (4-nitro-phen-yl)cyanamide anions act as monodentate ligands. There is one classical inter-molecular O-H⋯N hydrogen bond and several C-H⋯O hydrogen bonds are also observed.
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title cis-Bis[(4-nitro-phen-yl)cyanamido-κN(1)]bis-(1,10-phenanthroline-κ(2)N,N')nickel(II) methanol monosolvate
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