A comparative study of structural, thermal and electrical properties of undoped and doped with dodecylbenzenesulphonic acid polypyrrole
Polypyrrole was synthesized and doped with dodecylbenzenesulphonic acid; the latter was confirmed by means of FTIR spectroscopy. The percentage of crystallinity of synthesized polymers was estimated from X-rays diffraction studies. The formation of flaky structure in doped polypyrrole was observed b...
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| Veröffentlicht in: | Polymer science. Series B 2011-10, Vol.53 (9-10), p.540-545 |
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| container_end_page | 545 |
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| container_issue | 9-10 |
| container_start_page | 540 |
| container_title | Polymer science. Series B |
| container_volume | 53 |
| creator | Shakoor, Abdul Rizvi, Tasneem Zahra Farooq, Hafiz Umer Hassan, Najmul Majid, Abdul Saeed, Muhammad |
| description | Polypyrrole was synthesized and doped with dodecylbenzenesulphonic acid; the latter was confirmed by means of FTIR spectroscopy. The percentage of crystallinity of synthesized polymers was estimated from X-rays diffraction studies. The formation of flaky structure in doped polypyrrole was observed by means of SEM. DC conductivity was found to be influenced by dopant dodecylbenzenesulphonic acid. Temperature dependant DC shows three dimensional variable ranges hopping (3D VRH). Activation energy, density of states and hopping length were calculated and found to be influenced by adding dopant to polypyrrole. The doped polypyrrole was found to be more thermally stable as compared to that of pristine polypyrrole. |
| doi_str_mv | 10.1134/S1560090411100010 |
| format | Article |
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The percentage of crystallinity of synthesized polymers was estimated from X-rays diffraction studies. The formation of flaky structure in doped polypyrrole was observed by means of SEM. DC conductivity was found to be influenced by dopant dodecylbenzenesulphonic acid. Temperature dependant DC shows three dimensional variable ranges hopping (3D VRH). Activation energy, density of states and hopping length were calculated and found to be influenced by adding dopant to polypyrrole. The doped polypyrrole was found to be more thermally stable as compared to that of pristine polypyrrole.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090411100010</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Applied sciences ; Chemistry ; Chemistry and Materials Science ; Crystallinity ; Direct current ; Dopants ; Electrical properties ; Electrical, magnetic and optical properties ; Exact sciences and technology ; Functional Polymers ; Hopping (conductivity) ; Mathematical analysis ; Organic polymers ; Physicochemistry of polymers ; Polymer Sciences ; Polypyrroles ; Properties and characterization ; Three dimensional</subject><ispartof>Polymer science. 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Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shakoor, Abdul</au><au>Rizvi, Tasneem Zahra</au><au>Farooq, Hafiz Umer</au><au>Hassan, Najmul</au><au>Majid, Abdul</au><au>Saeed, Muhammad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A comparative study of structural, thermal and electrical properties of undoped and doped with dodecylbenzenesulphonic acid polypyrrole</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2011-10-01</date><risdate>2011</risdate><volume>53</volume><issue>9-10</issue><spage>540</spage><epage>545</epage><pages>540-545</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>Polypyrrole was synthesized and doped with dodecylbenzenesulphonic acid; the latter was confirmed by means of FTIR spectroscopy. The percentage of crystallinity of synthesized polymers was estimated from X-rays diffraction studies. The formation of flaky structure in doped polypyrrole was observed by means of SEM. DC conductivity was found to be influenced by dopant dodecylbenzenesulphonic acid. Temperature dependant DC shows three dimensional variable ranges hopping (3D VRH). Activation energy, density of states and hopping length were calculated and found to be influenced by adding dopant to polypyrrole. The doped polypyrrole was found to be more thermally stable as compared to that of pristine polypyrrole.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1560090411100010</doi><tpages>6</tpages></addata></record> |
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| ispartof | Polymer science. Series B, 2011-10, Vol.53 (9-10), p.540-545 |
| issn | 1560-0904 1555-6123 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Applied sciences Chemistry Chemistry and Materials Science Crystallinity Direct current Dopants Electrical properties Electrical, magnetic and optical properties Exact sciences and technology Functional Polymers Hopping (conductivity) Mathematical analysis Organic polymers Physicochemistry of polymers Polymer Sciences Polypyrroles Properties and characterization Three dimensional |
| title | A comparative study of structural, thermal and electrical properties of undoped and doped with dodecylbenzenesulphonic acid polypyrrole |
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