Superelectrophilic sp super(3 C-H carbonylation of n-octyl acetate as a way to new bifunctional neo-octanes)

Carbonylation of n-octyl acetate in the presence of CBr sub(4 times 2AlBr) sub(3) followed by treatment with nucleophiles such as alcohols, amines or (het)arenes affords 7-acetoxy-2,2-dimethylheptanoyl-containing products.

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Veröffentlicht in:Mendeleev communications 2011-12, Vol.21 (6), p.323-325
Hauptverfasser: Akhrem, Irena S, Avetisyan, Dzhul'etta V, Afanas'eva, Lyudmila V, Orlinkov, Alexander V, Kagramanov, Nikolai D, Petrovskii, Pavel V
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container_end_page 325
container_issue 6
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container_title Mendeleev communications
container_volume 21
creator Akhrem, Irena S
Avetisyan, Dzhul'etta V
Afanas'eva, Lyudmila V
Orlinkov, Alexander V
Kagramanov, Nikolai D
Petrovskii, Pavel V
description Carbonylation of n-octyl acetate in the presence of CBr sub(4 times 2AlBr) sub(3) followed by treatment with nucleophiles such as alcohols, amines or (het)arenes affords 7-acetoxy-2,2-dimethylheptanoyl-containing products.
doi_str_mv 10.1016/j.mencom.2011.11.010
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source Elsevier ScienceDirect Journals
subjects Acetates
Alcohols
Amines
Carbonyls
Nucleophiles
title Superelectrophilic sp super(3 C-H carbonylation of n-octyl acetate as a way to new bifunctional neo-octanes)
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