O2 Insertion into a Cadmium-Carbon Bond: Structural Characterization of Organocadmium Peroxides
Cadmium burning: The violent reaction of CdMe2 with O2 has been controlled by the use of a cadmium aminoalkoxide supporting ligand. The first examples of cadmium organoperoxides, arising from O2 insertion into the CdC bond, are thus formed (see picture; Cd green, C gray, N blue, O red).
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-04, Vol.51 (17), p.4108-4111 |
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| container_end_page | 4111 |
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| container_issue | 17 |
| container_start_page | 4108 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 51 |
| creator | Johnson, Andrew L. Hollingsworth, Nathan Kociok-Köhn, Gabriele Molloy, Kieran C. |
| description | Cadmium burning: The violent reaction of CdMe2 with O2 has been controlled by the use of a cadmium aminoalkoxide supporting ligand. The first examples of cadmium organoperoxides, arising from O2 insertion into the CdC bond, are thus formed (see picture; Cd green, C gray, N blue, O red). |
| doi_str_mv | 10.1002/anie.201200448 |
| format | Article |
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| ispartof | Angewandte Chemie International Edition, 2012-04, Vol.51 (17), p.4108-4111 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | cadmium cubanes organometallic compounds peroxides X-ray diffraction |
| title | O2 Insertion into a Cadmium-Carbon Bond: Structural Characterization of Organocadmium Peroxides |
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