O2 Insertion into a Cadmium-Carbon Bond: Structural Characterization of Organocadmium Peroxides

O2 Insertion into a Cadmium-Carbon Bond: Structural Characterization of Organocadmium Peroxides

Cadmium burning: The violent reaction of CdMe2 with O2 has been controlled by the use of a cadmium aminoalkoxide supporting ligand. The first examples of cadmium organoperoxides, arising from O2 insertion into the CdC bond, are thus formed (see picture; Cd green, C gray, N blue, O red).

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Veröffentlicht in:Angewandte Chemie International Edition 2012-04, Vol.51 (17), p.4108-4111
Hauptverfasser: Johnson, Andrew L., Hollingsworth, Nathan, Kociok-Köhn, Gabriele, Molloy, Kieran C.
Format: Artikel
Sprache:eng
Schlagworte:
cadmium
cubanes
organometallic compounds
peroxides
X-ray diffraction
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Zusammenfassung:Cadmium burning: The violent reaction of CdMe2 with O2 has been controlled by the use of a cadmium aminoalkoxide supporting ligand. The first examples of cadmium organoperoxides, arising from O2 insertion into the CdC bond, are thus formed (see picture; Cd green, C gray, N blue, O red).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201200448