Regioselective synthesis of dimeric (gemini) and trimeric sugar‐based surfactants
A simple and flexible chemoenzymatic route for the preparation of a wide range of dimeric (gemini) and trimeric mono‐ and disaccharide‐based surfactants was developed. The synthesis relies on the use of enzymes for regioselective introduction of fatty acids into carbohydrate moieties. Several struct...
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| Veröffentlicht in: | Journal of surfactants and detergents 1999-07, Vol.2 (3), p.293-302 |
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| container_title | Journal of surfactants and detergents |
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| creator | Gao, Chunli Millqvist‐Fureby, Anna Whitcombe, Michael J. Vulfson, Evgeny N. |
| description | A simple and flexible chemoenzymatic route for the preparation of a wide range of dimeric (gemini) and trimeric mono‐ and disaccharide‐based surfactants was developed. The synthesis relies on the use of enzymes for regioselective introduction of fatty acids into carbohydrate moieties. Several structures were prepared containing xylose, glucose, galactose, and lactose, connected via different hydroxyl groups in the sugar molecules or, alternatively, via the OH group of 2‐hydroxytet‐radecanoic acid used as a hydrophobic moiety for the surfactant. |
| doi_str_mv | 10.1007/s11743-999-0080-9 |
| format | Article |
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| identifier | ISSN: 1097-3958 |
| ispartof | Journal of surfactants and detergents, 1999-07, Vol.2 (3), p.293-302 |
| issn | 1097-3958 1558-9293 |
| language | eng |
| recordid | cdi_proquest_journals_923387651 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Enzyme gemini lipase regioselectivity Sugar sugar ester surfactant Surfactants synthesis |
| title | Regioselective synthesis of dimeric (gemini) and trimeric sugar‐based surfactants |
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