The Existence of Oscillatory Solutions in the Field-Noyes Model for the Belousov-Zhabotinskii Reaction

The cerium ion catalyzed oxidation of malonic acid by bromate in a sulphuric acid solution is essentially the Belousov-Zhabotinskii reaction. Belousov [1] observed temporal oscillations in the concentrations of the cerium ions Ce(III) and Ce(IV) when the reagent was stirred. The quantitative model f...

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Veröffentlicht in:SIAM journal on applied mathematics 1975-05, Vol.28 (3), p.678-688
Hauptverfasser: Hastings, S. P., Murray, J. D.
Format: Artikel
Sprache:eng
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Zusammenfassung:The cerium ion catalyzed oxidation of malonic acid by bromate in a sulphuric acid solution is essentially the Belousov-Zhabotinskii reaction. Belousov [1] observed temporal oscillations in the concentrations of the cerium ions Ce(III) and Ce(IV) when the reagent was stirred. The quantitative model for the chemical mechanism suggested by Field and Noyes [3] is examined here and it is shown that the solutions of the model equations are oscillatory, of finite amplitude and must possess at least one periodic solution.
ISSN:0036-1399
1095-712X
DOI:10.1137/0128057