The Existence of Oscillatory Solutions in the Field-Noyes Model for the Belousov-Zhabotinskii Reaction
The cerium ion catalyzed oxidation of malonic acid by bromate in a sulphuric acid solution is essentially the Belousov-Zhabotinskii reaction. Belousov [1] observed temporal oscillations in the concentrations of the cerium ions Ce(III) and Ce(IV) when the reagent was stirred. The quantitative model f...
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Veröffentlicht in: | SIAM journal on applied mathematics 1975-05, Vol.28 (3), p.678-688 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The cerium ion catalyzed oxidation of malonic acid by bromate in a sulphuric acid solution is essentially the Belousov-Zhabotinskii reaction. Belousov [1] observed temporal oscillations in the concentrations of the cerium ions Ce(III) and Ce(IV) when the reagent was stirred. The quantitative model for the chemical mechanism suggested by Field and Noyes [3] is examined here and it is shown that the solutions of the model equations are oscillatory, of finite amplitude and must possess at least one periodic solution. |
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ISSN: | 0036-1399 1095-712X |
DOI: | 10.1137/0128057 |