Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers
Two new cobalt(II) coordination polymers, namely [Co 1.5 (PhCOO) 3 (bbbm) 1.5 (H 2 O)] n ( 1 ) and [Co(chdc)(bbbm)] n ( 2 ) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H 2 chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray di...
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| Veröffentlicht in: | Transition metal chemistry (Weinheim) 2012-02, Vol.37 (1), p.17-23 |
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| creator | Jiao, Cui-huan He, Cui-hong Geng, Jian-chen Cui, Guang-hua |
| description | Two new cobalt(II) coordination polymers, namely [Co
1.5
(PhCOO)
3
(bbbm)
1.5
(H
2
O)]
n
(
1
) and [Co(chdc)(bbbm)]
n
(
2
) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H
2
chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray diffraction. The cobalt(II) centers display different environments, with trigonal–bipyramidal and octahedral geometries in
1
and a tetrahedral geometry in
2
. The 1D linear chains of complex
1
and ladder-like chains of complex
2
are bridged by bbbm in bis-monodentate coordination mode; the variation of the carboxylate co-ligand effectively tunes the resulting framework architecture. The degradation of methyl orange in a photochemical Fenton-like process using complexes
1
and
2
as catalysts was investigated. |
| doi_str_mv | 10.1007/s11243-011-9550-7 |
| format | Article |
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1.5
(PhCOO)
3
(bbbm)
1.5
(H
2
O)]
n
(
1
) and [Co(chdc)(bbbm)]
n
(
2
) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H
2
chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray diffraction. The cobalt(II) centers display different environments, with trigonal–bipyramidal and octahedral geometries in
1
and a tetrahedral geometry in
2
. The 1D linear chains of complex
1
and ladder-like chains of complex
2
are bridged by bbbm in bis-monodentate coordination mode; the variation of the carboxylate co-ligand effectively tunes the resulting framework architecture. The degradation of methyl orange in a photochemical Fenton-like process using complexes
1
and
2
as catalysts was investigated.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-011-9550-7</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Catalysis ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Organometallic Chemistry ; Physical Chemistry</subject><ispartof>Transition metal chemistry (Weinheim), 2012-02, Vol.37 (1), p.17-23</ispartof><rights>Springer Science+Business Media B.V. 2011</rights><rights>Springer Science+Business Media B.V. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c315t-2f58b54aba333c6f43e087467017cc12c1ae2eeeba0eb7331de06cb64e636a103</citedby><cites>FETCH-LOGICAL-c315t-2f58b54aba333c6f43e087467017cc12c1ae2eeeba0eb7331de06cb64e636a103</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11243-011-9550-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11243-011-9550-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Jiao, Cui-huan</creatorcontrib><creatorcontrib>He, Cui-hong</creatorcontrib><creatorcontrib>Geng, Jian-chen</creatorcontrib><creatorcontrib>Cui, Guang-hua</creatorcontrib><title>Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transition Met Chem</addtitle><description>Two new cobalt(II) coordination polymers, namely [Co
1.5
(PhCOO)
3
(bbbm)
1.5
(H
2
O)]
n
(
1
) and [Co(chdc)(bbbm)]
n
(
2
) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H
2
chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray diffraction. The cobalt(II) centers display different environments, with trigonal–bipyramidal and octahedral geometries in
1
and a tetrahedral geometry in
2
. The 1D linear chains of complex
1
and ladder-like chains of complex
2
are bridged by bbbm in bis-monodentate coordination mode; the variation of the carboxylate co-ligand effectively tunes the resulting framework architecture. The degradation of methyl orange in a photochemical Fenton-like process using complexes
1
and
2
as catalysts was investigated.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wFvwpODqTD427VH8LBQ8qOAtZNOsbtlu1iSL7L83pYInYWCGmfedGR5CThGuEEBdR0QmeAGIxVxKKNQemaBUrJgDvu-TCXABhWAzeUiOYlwDgGRKTIh5Gbv06WITL6kNY0ympTGFwaYhuEhNt6LW5OaYGkv74HsXUpMHvqbp21O8o9ZXpk3ni8VFLn1YNZ1Jje9o79tx40I8Jge1aaM7-c1T8vZw_3r7VCyfHxe3N8vCcpSpYLWcVVKYynDObVkL7mCmRKkAlbXILBrHnHOVAVcpznHloLRVKVzJS4PAp-Rstzd_-TW4mPTaD6HLJ_UcS56j5FmEO5ENPsbgat2HZmPCqBH0FqTegdQZpN6C1Cp72M4Ts7b7cOFv8f-mHy-FdvI</recordid><startdate>20120201</startdate><enddate>20120201</enddate><creator>Jiao, Cui-huan</creator><creator>He, Cui-hong</creator><creator>Geng, Jian-chen</creator><creator>Cui, Guang-hua</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120201</creationdate><title>Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers</title><author>Jiao, Cui-huan ; He, Cui-hong ; Geng, Jian-chen ; Cui, Guang-hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c315t-2f58b54aba333c6f43e087467017cc12c1ae2eeeba0eb7331de06cb64e636a103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiao, Cui-huan</creatorcontrib><creatorcontrib>He, Cui-hong</creatorcontrib><creatorcontrib>Geng, Jian-chen</creatorcontrib><creatorcontrib>Cui, Guang-hua</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiao, Cui-huan</au><au>He, Cui-hong</au><au>Geng, Jian-chen</au><au>Cui, Guang-hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transition Met Chem</stitle><date>2012-02-01</date><risdate>2012</risdate><volume>37</volume><issue>1</issue><spage>17</spage><epage>23</epage><pages>17-23</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Two new cobalt(II) coordination polymers, namely [Co
1.5
(PhCOO)
3
(bbbm)
1.5
(H
2
O)]
n
(
1
) and [Co(chdc)(bbbm)]
n
(
2
) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H
2
chdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized by single crystal X-ray diffraction. The cobalt(II) centers display different environments, with trigonal–bipyramidal and octahedral geometries in
1
and a tetrahedral geometry in
2
. The 1D linear chains of complex
1
and ladder-like chains of complex
2
are bridged by bbbm in bis-monodentate coordination mode; the variation of the carboxylate co-ligand effectively tunes the resulting framework architecture. The degradation of methyl orange in a photochemical Fenton-like process using complexes
1
and
2
as catalysts was investigated.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11243-011-9550-7</doi><tpages>7</tpages></addata></record> |
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| issn | 0340-4285 1572-901X |
| language | eng |
| recordid | cdi_proquest_journals_916316363 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Catalysis Chemistry Chemistry and Materials Science Inorganic Chemistry Organometallic Chemistry Physical Chemistry |
| title | Synthesis, crystal structures and catalytic properties of two 1D cobalt(II) coordination polymers |
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