Arsenic removal from water using calcined Mg–Al layered double hydroxide

Arsenic (As) in drinking water and its related toxicology are serious concerns nowadays. Development of better techniques related to removal of As from drinking water is an urgent need. Layered double hydroxide (LDH) or hydrotalcite-like compound with the general formula [M 1− x 2+ M x 3+ (OH) 2 ] x...

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Veröffentlicht in:Clean technologies and environmental policy 2012-02, Vol.14 (1), p.21-27
Hauptverfasser: Chetia, Mridul, Goswamee, Rajib L., Banerjee, Saumen, Chatterjee, Soumya, Singh, Lokendra, Srivastava, Ravi B., Sarma, Hari P.
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container_issue 1
container_start_page 21
container_title Clean technologies and environmental policy
container_volume 14
creator Chetia, Mridul
Goswamee, Rajib L.
Banerjee, Saumen
Chatterjee, Soumya
Singh, Lokendra
Srivastava, Ravi B.
Sarma, Hari P.
description Arsenic (As) in drinking water and its related toxicology are serious concerns nowadays. Development of better techniques related to removal of As from drinking water is an urgent need. Layered double hydroxide (LDH) or hydrotalcite-like compound with the general formula [M 1− x 2+ M x 3+ (OH) 2 ] x + A x − · n H 2 O can be considered as a good adsorbent for the removal of toxic As from water. Due to large surface area and high anion exchange capacity of LDH, the compound may be a good adsorbent for the removal of As from contaminated water. In this study, the removal of As in aqueous solution by adsorption method based on the calcination–rehydration reaction was investigated in batch experiment at (30 ± 1)°C. Results showed the removal of 99.99% As from a solution of 0.1 ppm of As; the adsorbent required at saturation was 0.10 g/20 ml As solution with 90 min of exposure at (30 ± 1)°C. Factors like pH, adsorbent dose and shaking time influenced the rate of As removal. Experiment showed that the adsorption process follows the Freundlich-type adsorption isotherm. The explanation of adsorption phenomenon is supported by X-ray diffraction pattern.
doi_str_mv 10.1007/s10098-011-0365-1
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Development of better techniques related to removal of As from drinking water is an urgent need. Layered double hydroxide (LDH) or hydrotalcite-like compound with the general formula [M 1− x 2+ M x 3+ (OH) 2 ] x + A x − · n H 2 O can be considered as a good adsorbent for the removal of toxic As from water. Due to large surface area and high anion exchange capacity of LDH, the compound may be a good adsorbent for the removal of As from contaminated water. In this study, the removal of As in aqueous solution by adsorption method based on the calcination–rehydration reaction was investigated in batch experiment at (30 ± 1)°C. Results showed the removal of 99.99% As from a solution of 0.1 ppm of As; the adsorbent required at saturation was 0.10 g/20 ml As solution with 90 min of exposure at (30 ± 1)°C. Factors like pH, adsorbent dose and shaking time influenced the rate of As removal. Experiment showed that the adsorption process follows the Freundlich-type adsorption isotherm. 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subjects Adsorbents
Adsorption
Anion exchange
Aqueous solutions
Arsenic
Arsenic removal
Defense research
Drinking water
Earth and Environmental Science
Environment
Environmental Economics
Environmental Engineering/Biotechnology
Environmental policy
Experiments
Industrial and Production Engineering
Industrial Chemistry/Chemical Engineering
Original Paper
Pollutant removal
R&D
Research & development
Sustainable Development
Toxicology
Water pollution
X-ray diffraction
title Arsenic removal from water using calcined Mg–Al layered double hydroxide
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