Comparison of curing agents for epoxidized vegetable oils applied to composites

Comparison of curing agents for epoxidized vegetable oils applied to composites

Interest in polymers from renewable sources, as alternatives to petroleum‐based polymers, remains strong; however, their performance must be acceptable. To improve performance of epoxidized vegetable oils (EVO) in composite matrix applications, five amine curing agents were evaluated and compared wi...

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Veröffentlicht in:Polymer composites 2011-11, Vol.32 (11), p.1806-1816
Hauptverfasser: Espinoza-Perez, Judith D., Nerenz, Brent A., Haagenson, Darrin M., Chen, Zhigang, Ulven, Chad A., Wiesenborn, Dennis P.
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Applied sciences
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Polymer industry, paints, wood
Technology of polymers
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container_end_page 1816
container_issue 11
container_start_page 1806
container_title Polymer composites
container_volume 32
creator Espinoza-Perez, Judith D.
Nerenz, Brent A.
Haagenson, Darrin M.
Chen, Zhigang
Ulven, Chad A.
Wiesenborn, Dennis P.
description Interest in polymers from renewable sources, as alternatives to petroleum‐based polymers, remains strong; however, their performance must be acceptable. To improve performance of epoxidized vegetable oils (EVO) in composite matrix applications, five amine curing agents were evaluated and compared with an anhydride agent used previously. Curing agents were tested in matrices for composites containing a petroleum‐based epoxy resin plus 0% or 30% epoxidized oil from canola (ECO) and soybean (ESO). The two amines with the highest glass transition temperature, determined by differential scanning calorimetry, were selected for characterization by dynamic mechanical analysis; bis (p‐aminocyclohexyl) methane (PACM) showed the highest performance. Amine: epoxy ratios 0.6 to 1.6 were then evaluated; ratios of 0.8 and 1.0 showed superior performance. E‐glass fiber reinforced composites with PACM/EVO showed thermal and mechanical performance slightly lower than the composites with 0% EVO and comparable with those of the anhydride curing agent. Therefore, ECO or ESO blended with petroleum‐based epoxy resins cured with PACM are recommended for its application in E‐glass reinforced composites. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers
doi_str_mv 10.1002/pc.21213
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To improve performance of epoxidized vegetable oils (EVO) in composite matrix applications, five amine curing agents were evaluated and compared with an anhydride agent used previously. Curing agents were tested in matrices for composites containing a petroleum‐based epoxy resin plus 0% or 30% epoxidized oil from canola (ECO) and soybean (ESO). The two amines with the highest glass transition temperature, determined by differential scanning calorimetry, were selected for characterization by dynamic mechanical analysis; bis (p‐aminocyclohexyl) methane (PACM) showed the highest performance. Amine: epoxy ratios 0.6 to 1.6 were then evaluated; ratios of 0.8 and 1.0 showed superior performance. E‐glass fiber reinforced composites with PACM/EVO showed thermal and mechanical performance slightly lower than the composites with 0% EVO and comparable with those of the anhydride curing agent. 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subjects Applied sciences
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Polymer industry, paints, wood
Technology of polymers
title Comparison of curing agents for epoxidized vegetable oils applied to composites
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