Monomeric cis-isothiocyanato complexes. Crystal and molecular structure of [Mn(mep)2(NCS)2] (mep=4-methoxy-2-(5-methoxy- 3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine)

Monomeric cis-isothiocyanato complexes. Crystal and molecular structure of [Mn(mep)2(NCS)2] (mep=4-methoxy-2-(5-methoxy- 3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine)

The crystal and molecular structures of [Mn(mep)2- (NCS)2] ({ {mep}}=4-methoxy-2-(5-methoxy-3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine) have been determined by X-ray crystallography. The crystal structure of the title compound is built up of isolated [Mn(mep)2(NCS)2] molecules with the stereochemi...

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Veröffentlicht in:Transition metal chemistry (Weinheim) 1997-04, Vol.22 (2), p.161
Hauptverfasser: Garci´a-lozano, Julia, Server-carrio´, Juan, Molla, M Carmen, Escriva`, Emilio
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container_title Transition metal chemistry (Weinheim)
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creator Garci´a-lozano, Julia
Server-carrio´, Juan
Molla, M Carmen
Escriva`, Emilio
description The crystal and molecular structures of [Mn(mep)2- (NCS)2] ({ {mep}}=4-methoxy-2-(5-methoxy-3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine) have been determined by X-ray crystallography. The crystal structure of the title compound is built up of isolated [Mn(mep)2(NCS)2] molecules with the stereochemistry of a distorted octahedron for the MnN6 chromophore. The e.p.r. (Q-band) data are in agreement with the structural data.[PUBLICATION ABSTRACT]
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title Monomeric cis-isothiocyanato complexes. Crystal and molecular structure of [Mn(mep)2(NCS)2] (mep=4-methoxy-2-(5-methoxy- 3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine)
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