Dielectric relaxations of high-k poly(butylene succinate) based all-organic nanocomposite films for capacitor application

High-dielectric constant all-organic composite films consisting of polyaniline (PANI) filler and poly(butylene succinate) host were synthesized by simple blending process. The chemical structures and morphology of the composite films were characterized by Fourier transform infrared spectroscopy and...

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Veröffentlicht in:Journal of materials research 2011-10, Vol.26 (19), p.2493
Hauptverfasser: Yu, Li, Ke, Shanming, Zhang, Yihe, Shen, Bo, Zhang, Anzhen, Huang, Haitao
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container_issue 19
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creator Yu, Li
Ke, Shanming
Zhang, Yihe
Shen, Bo
Zhang, Anzhen
Huang, Haitao
description High-dielectric constant all-organic composite films consisting of polyaniline (PANI) filler and poly(butylene succinate) host were synthesized by simple blending process. The chemical structures and morphology of the composite films were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy, respectively. The dielectric properties of the composite films with different filler concentrations were studied in the frequency range of 100-106 Hz. A percolation phenomenon was observed in the composite films with a percolation threshold vc = 19.7% and the dielectric constant was 10 times that of the pure host material. The enhancement in the dielectric constant can be ascribed to Maxwell-Wagner-Sillars polarization and the low-dielectric loss to good dispersion of PANI filler in the host. As the host polymer is biodegradable, it may be applied as a green dielectric material. [PUBLICATION ABSTRACT]
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subjects Composite materials
Dependence
Dielectric properties
Ferroelectrics
Fourier transforms
Materials research
Materials science
Nanocomposites
Polymers
Studies
Temperature
Thin films
title Dielectric relaxations of high-k poly(butylene succinate) based all-organic nanocomposite films for capacitor application
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