Low-temperature annealing effect on plasma sprayed MnZn ferrite for planar transformers of high-frequency applications

MnZn ferrite coatings fabricated by plasma spray have the advantage of a columnar structure with average grain size between 200-300 nm, somewhat analogous to that of conventional laminated cores used to minimize the eddy current loss at high frequency. The resistivity of these ferrite coatings incre...

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Veröffentlicht in:IEEE transactions on magnetics 2003-09, Vol.39 (5), p.3106-3108
Hauptverfasser: Yan, Q.Y., Gambino, R.J., Sampath, S.
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container_title IEEE transactions on magnetics
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creator Yan, Q.Y.
Gambino, R.J.
Sampath, S.
description MnZn ferrite coatings fabricated by plasma spray have the advantage of a columnar structure with average grain size between 200-300 nm, somewhat analogous to that of conventional laminated cores used to minimize the eddy current loss at high frequency. The resistivity of these ferrite coatings increases by four orders of magnitude after a simple annealing process at 500/spl deg/C in air. Our studies reveal that this change is due to oxygen diffusion through the grain boundaries, which results in the oxidation of Fe/sup 2+/ to Fe/sup 3+/ and inhibits the "hopping" conductivity effect between Fe/sup 2+/ and Fe/sup 3+/. The initial permeability at 100 kHz increases from around 500 to above 1000. This change is believed to be due to the local- and long-range redistribution of Mn and Zn, which improves the soft magnetic properties of the ferrite coatings.
doi_str_mv 10.1109/TMAG.2003.816020
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The resistivity of these ferrite coatings increases by four orders of magnitude after a simple annealing process at 500/spl deg/C in air. Our studies reveal that this change is due to oxygen diffusion through the grain boundaries, which results in the oxidation of Fe/sup 2+/ to Fe/sup 3+/ and inhibits the "hopping" conductivity effect between Fe/sup 2+/ and Fe/sup 3+/. The initial permeability at 100 kHz increases from around 500 to above 1000. This change is believed to be due to the local- and long-range redistribution of Mn and Zn, which improves the soft magnetic properties of the ferrite coatings.</abstract><cop>New York, NY</cop><pub>IEEE</pub><doi>10.1109/TMAG.2003.816020</doi><tpages>3</tpages></addata></record>
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subjects Annealing
Coatings
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity
Eddy currents
Exact sciences and technology
Ferrites
Grain size
Iron
Magnetic properties and materials
Magnetic properties of monolayers and thin films
Magnetic properties of surface, thin films and multilayers
Magnetism
Physics
Plasma applications
Thermal spraying
Transformer cores
title Low-temperature annealing effect on plasma sprayed MnZn ferrite for planar transformers of high-frequency applications
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