Copper(II) complexes of pyrrolidine dithiocarbamate

Copper(II) complexes of pyrrolidine dithiocarbamate

Copper(II)-pyrrolidine dithiocarbamate (PDTC) complexes having the general formula, [Cu(PDTC)^sub 2^], [Cu(PDTC)X^sub 2^]^sup -^ (where X = Cl^sup -^, I^sup -^, CN^sup -^, SCN^sup -^) and [Cu(PDTC)(en)]^sup +^ (en = ethylenediamine) have been prepared and characterized by IR spectroscopy and by ther...

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Veröffentlicht in:Transition metal chemistry (Weinheim) 2007-03, Vol.32 (2), p.199-203
Hauptverfasser: Sarwar, Masood, Ahmad, Saeed, Ahmad, Sajjad, Ali, Saqib, Awan, Shafique Ahmed
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Thermogravimetric analysis
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container_issue 2
container_start_page 199
container_title Transition metal chemistry (Weinheim)
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creator Sarwar, Masood
Ahmad, Saeed
Ahmad, Sajjad
Ali, Saqib
Awan, Shafique Ahmed
description Copper(II)-pyrrolidine dithiocarbamate (PDTC) complexes having the general formula, [Cu(PDTC)^sub 2^], [Cu(PDTC)X^sub 2^]^sup -^ (where X = Cl^sup -^, I^sup -^, CN^sup -^, SCN^sup -^) and [Cu(PDTC)(en)]^sup +^ (en = ethylenediamine) have been prepared and characterized by IR spectroscopy and by thermogravimetric analysis (TGA and DTA). The IR data suggests that coordination of pyrrolidine dithiocarbamate (PDTC) takes place through the two sulphur atoms in a symmetrical bidentate fashion. The results of thermal analysis are consistent with the proposed composition of the complexes.[PUBLICATION ABSTRACT]
doi_str_mv 10.1007/s11243-006-0148-4
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title Copper(II) complexes of pyrrolidine dithiocarbamate
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