Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex
The synthesis and characterization of the first unique binuclear manganese(I) salicylate complex is described. The structure of the complex is unequivocally established with the help of an X-ray crystallographic study. The structure consists of two [MnO^sub 6^] units, containing octahedral Mn^sup I^...
Gespeichert in:
| Veröffentlicht in: | Transition metal chemistry (Weinheim) 2006-05, Vol.31 (4), p.423-428 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 428 |
|---|---|
| container_issue | 4 |
| container_start_page | 423 |
| container_title | Transition metal chemistry (Weinheim) |
| container_volume | 31 |
| creator | Lal, Ram A. Lemtur, Aka Choudhury, Sanjesh Chakrabarty, Mithun Basumatary, Debjani Singh, Mahesh K. Bhaumik, Samhita De, Arjun K. Kumar, Arvind |
| description | The synthesis and characterization of the first unique binuclear manganese(I) salicylate complex is described. The structure of the complex is unequivocally established with the help of an X-ray crystallographic study. The structure consists of two [MnO^sub 6^] units, containing octahedral Mn^sup I^ ions, linked together by a bridging salicylato (Hsal^sup -^) ligand and each Mn^sup I^ is chelated with a (H^sub 2^sal) ligand. The complex possesses a metal oxidation state of +1 and is a rare example of a noncarbonyl or cyanide complex of a binuclear Mn^sup I^ species. The effective magnetic moment per binuclear molecule (µ^sub eff.^ at 27 °C is 8.07 µ^sub b^, that also describes the manganese (+1) oxidation state.[PUBLICATION ABSTRACT] |
| doi_str_mv | 10.1007/s11243-005-6293-3 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_883986640</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2427723431</sourcerecordid><originalsourceid>FETCH-LOGICAL-c272t-871d891ca4ac0c5d4af3f873cf9075a211bbf8da281d543251900f27ce4fdf3c3</originalsourceid><addsrcrecordid>eNpFkN9KwzAYR4MoOKcP4F3warvIzL-u6aWOzQ0cA6cgiIRvaaIdXTuTVtYX8Xnt3MCr30XOdwIHoWtGB4zS-DYwxqUglEZkyBNBxAnqsCjmJKHs9RR1qJCUSK6ic3QRwpq2II9lB_0sm6L6tCELGIoUj3wTKsjxsvK1qWpvcenw27zgvSkPkPfbPQ5f9OX7AE8yHyo83sFmm__BrQw_2bS9zr4t_re3T4Dvs6I2uQWP51B8QGGD7c36eAl5ZpocKotH5V60u0RnDvJgr47bRS-T8fNoSh4XD7PR3SMxPOYVUTFLVcIMSDDURKkEJ5yKhXEJjSPgjK1WTqXAFUsjKXjEEkodj42VLnXCiC66OXi3vvyqbaj0uqx90X6plRKJGg4lbSF2gIwvQ_DW6a3PNuAbzaje19eH-rqNqvf1tRC_FcV3cQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>883986640</pqid></control><display><type>article</type><title>Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex</title><source>Springer Nature - Complete Springer Journals</source><creator>Lal, Ram A. ; Lemtur, Aka ; Choudhury, Sanjesh ; Chakrabarty, Mithun ; Basumatary, Debjani ; Singh, Mahesh K. ; Bhaumik, Samhita ; De, Arjun K. ; Kumar, Arvind</creator><creatorcontrib>Lal, Ram A. ; Lemtur, Aka ; Choudhury, Sanjesh ; Chakrabarty, Mithun ; Basumatary, Debjani ; Singh, Mahesh K. ; Bhaumik, Samhita ; De, Arjun K. ; Kumar, Arvind</creatorcontrib><description>The synthesis and characterization of the first unique binuclear manganese(I) salicylate complex is described. The structure of the complex is unequivocally established with the help of an X-ray crystallographic study. The structure consists of two [MnO^sub 6^] units, containing octahedral Mn^sup I^ ions, linked together by a bridging salicylato (Hsal^sup -^) ligand and each Mn^sup I^ is chelated with a (H^sub 2^sal) ligand. The complex possesses a metal oxidation state of +1 and is a rare example of a noncarbonyl or cyanide complex of a binuclear Mn^sup I^ species. The effective magnetic moment per binuclear molecule (µ^sub eff.^ at 27 °C is 8.07 µ^sub b^, that also describes the manganese (+1) oxidation state.[PUBLICATION ABSTRACT]</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-005-6293-3</identifier><language>eng</language><publisher>Dordrecht: Springer Nature B.V</publisher><subject>Crystal structure</subject><ispartof>Transition metal chemistry (Weinheim), 2006-05, Vol.31 (4), p.423-428</ispartof><rights>Springer 2006</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c272t-871d891ca4ac0c5d4af3f873cf9075a211bbf8da281d543251900f27ce4fdf3c3</citedby><cites>FETCH-LOGICAL-c272t-871d891ca4ac0c5d4af3f873cf9075a211bbf8da281d543251900f27ce4fdf3c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27911,27912</link.rule.ids></links><search><creatorcontrib>Lal, Ram A.</creatorcontrib><creatorcontrib>Lemtur, Aka</creatorcontrib><creatorcontrib>Choudhury, Sanjesh</creatorcontrib><creatorcontrib>Chakrabarty, Mithun</creatorcontrib><creatorcontrib>Basumatary, Debjani</creatorcontrib><creatorcontrib>Singh, Mahesh K.</creatorcontrib><creatorcontrib>Bhaumik, Samhita</creatorcontrib><creatorcontrib>De, Arjun K.</creatorcontrib><creatorcontrib>Kumar, Arvind</creatorcontrib><title>Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex</title><title>Transition metal chemistry (Weinheim)</title><description>The synthesis and characterization of the first unique binuclear manganese(I) salicylate complex is described. The structure of the complex is unequivocally established with the help of an X-ray crystallographic study. The structure consists of two [MnO^sub 6^] units, containing octahedral Mn^sup I^ ions, linked together by a bridging salicylato (Hsal^sup -^) ligand and each Mn^sup I^ is chelated with a (H^sub 2^sal) ligand. The complex possesses a metal oxidation state of +1 and is a rare example of a noncarbonyl or cyanide complex of a binuclear Mn^sup I^ species. The effective magnetic moment per binuclear molecule (µ^sub eff.^ at 27 °C is 8.07 µ^sub b^, that also describes the manganese (+1) oxidation state.[PUBLICATION ABSTRACT]</description><subject>Crystal structure</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNpFkN9KwzAYR4MoOKcP4F3warvIzL-u6aWOzQ0cA6cgiIRvaaIdXTuTVtYX8Xnt3MCr30XOdwIHoWtGB4zS-DYwxqUglEZkyBNBxAnqsCjmJKHs9RR1qJCUSK6ic3QRwpq2II9lB_0sm6L6tCELGIoUj3wTKsjxsvK1qWpvcenw27zgvSkPkPfbPQ5f9OX7AE8yHyo83sFmm__BrQw_2bS9zr4t_re3T4Dvs6I2uQWP51B8QGGD7c36eAl5ZpocKotH5V60u0RnDvJgr47bRS-T8fNoSh4XD7PR3SMxPOYVUTFLVcIMSDDURKkEJ5yKhXEJjSPgjK1WTqXAFUsjKXjEEkodj42VLnXCiC66OXi3vvyqbaj0uqx90X6plRKJGg4lbSF2gIwvQ_DW6a3PNuAbzaje19eH-rqNqvf1tRC_FcV3cQ</recordid><startdate>200605</startdate><enddate>200605</enddate><creator>Lal, Ram A.</creator><creator>Lemtur, Aka</creator><creator>Choudhury, Sanjesh</creator><creator>Chakrabarty, Mithun</creator><creator>Basumatary, Debjani</creator><creator>Singh, Mahesh K.</creator><creator>Bhaumik, Samhita</creator><creator>De, Arjun K.</creator><creator>Kumar, Arvind</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200605</creationdate><title>Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex</title><author>Lal, Ram A. ; Lemtur, Aka ; Choudhury, Sanjesh ; Chakrabarty, Mithun ; Basumatary, Debjani ; Singh, Mahesh K. ; Bhaumik, Samhita ; De, Arjun K. ; Kumar, Arvind</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c272t-871d891ca4ac0c5d4af3f873cf9075a211bbf8da281d543251900f27ce4fdf3c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Crystal structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lal, Ram A.</creatorcontrib><creatorcontrib>Lemtur, Aka</creatorcontrib><creatorcontrib>Choudhury, Sanjesh</creatorcontrib><creatorcontrib>Chakrabarty, Mithun</creatorcontrib><creatorcontrib>Basumatary, Debjani</creatorcontrib><creatorcontrib>Singh, Mahesh K.</creatorcontrib><creatorcontrib>Bhaumik, Samhita</creatorcontrib><creatorcontrib>De, Arjun K.</creatorcontrib><creatorcontrib>Kumar, Arvind</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lal, Ram A.</au><au>Lemtur, Aka</au><au>Choudhury, Sanjesh</au><au>Chakrabarty, Mithun</au><au>Basumatary, Debjani</au><au>Singh, Mahesh K.</au><au>Bhaumik, Samhita</au><au>De, Arjun K.</au><au>Kumar, Arvind</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><date>2006-05</date><risdate>2006</risdate><volume>31</volume><issue>4</issue><spage>423</spage><epage>428</epage><pages>423-428</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>The synthesis and characterization of the first unique binuclear manganese(I) salicylate complex is described. The structure of the complex is unequivocally established with the help of an X-ray crystallographic study. The structure consists of two [MnO^sub 6^] units, containing octahedral Mn^sup I^ ions, linked together by a bridging salicylato (Hsal^sup -^) ligand and each Mn^sup I^ is chelated with a (H^sub 2^sal) ligand. The complex possesses a metal oxidation state of +1 and is a rare example of a noncarbonyl or cyanide complex of a binuclear Mn^sup I^ species. The effective magnetic moment per binuclear molecule (µ^sub eff.^ at 27 °C is 8.07 µ^sub b^, that also describes the manganese (+1) oxidation state.[PUBLICATION ABSTRACT]</abstract><cop>Dordrecht</cop><pub>Springer Nature B.V</pub><doi>10.1007/s11243-005-6293-3</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0340-4285 |
| ispartof | Transition metal chemistry (Weinheim), 2006-05, Vol.31 (4), p.423-428 |
| issn | 0340-4285 1572-901X |
| language | eng |
| recordid | cdi_proquest_journals_883986640 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Crystal structure |
| title | Synthesis and Crystal Structure of [Mn2(H2sal)2(Hsal)2(H2O)4]. First Example of the Reductive Synthesis of a Binuclear Manganese(I) Salicylate Complex |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T00%3A09%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Crystal%20Structure%20of%20%5BMn2(H2sal)2(Hsal)2(H2O)4%5D.%20First%20Example%20of%20the%20Reductive%20Synthesis%20of%20a%20Binuclear%20Manganese(I)%20Salicylate%20Complex&rft.jtitle=Transition%20metal%20chemistry%20(Weinheim)&rft.au=Lal,%20Ram%20A.&rft.date=2006-05&rft.volume=31&rft.issue=4&rft.spage=423&rft.epage=428&rft.pages=423-428&rft.issn=0340-4285&rft.eissn=1572-901X&rft_id=info:doi/10.1007/s11243-005-6293-3&rft_dat=%3Cproquest_cross%3E2427723431%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=883986640&rft_id=info:pmid/&rfr_iscdi=true |