Heterobimetallic compounds [Ru([eta]5-Cp)(dppf)X] (X = Cl, Br, I and N3): synthesis, electrochemical analysis, and the crystal structure of [Ru([eta]5-Cp)(dppf)I] [dppf = 1,1'-bis(diphenylphosphino)ferrocene]
A series of new ruthenium-iron based derivatives [Ru(η^sup 5^-Cp)(dppf)Cl] (1), [Ru(η^sup 5^-Cp)(dppf)Br] (2), [Ru(η^sup 5^-Cp)(dppf)I] (3) and [Ru(η^sup 5^-Cp)(dppf)N^sub 3^] (4) were obtained by reactions of [Ru(η^sup 5^-Cp)(PPh^sub 3^)^sub 2^Cl] with 1,1'-bis(diphenylphosphino) ferrocene (dp...
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| Veröffentlicht in: | Transition metal chemistry (Weinheim) 2009-11, Vol.34 (8), p.949 |
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| creator | Paim, Lilian A Batista, Alzir A Dias, Fabrícia M Golfeto, Camilla C Ellena, Javier Siebald, Helmuth G L Ardisson, J D |
| description | A series of new ruthenium-iron based derivatives [Ru(η^sup 5^-Cp)(dppf)Cl] (1), [Ru(η^sup 5^-Cp)(dppf)Br] (2), [Ru(η^sup 5^-Cp)(dppf)I] (3) and [Ru(η^sup 5^-Cp)(dppf)N^sub 3^] (4) were obtained by reactions of [Ru(η^sup 5^-Cp)(PPh^sub 3^)^sub 2^Cl] with 1,1'-bis(diphenylphosphino) ferrocene (dppf) and characterized by IR, NMR (^sup 1^H, ^sup 13^C and ^sup 31^P), ^sup 57^Fe Mössbauer spectroscopy and cyclic voltammetry. Additionally, the compound (3) was structurally characterized by X-ray crystallography, and the results were as follows: orthorhombic, Pbca, a = 18.2458(10), b = 20.9192(11), c = 34.4138(19) , α = β = γ = 90°, V = 13135.3(12) ^sup 3^ and Z = 16.[PUBLICATION ABSTRACT] |
| doi_str_mv | 10.1007/s11243-009-9286-9 |
| format | Article |
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Additionally, the compound (3) was structurally characterized by X-ray crystallography, and the results were as follows: orthorhombic, Pbca, a = 18.2458(10), b = 20.9192(11), c = 34.4138(19) , α = β = γ = 90°, V = 13135.3(12) ^sup 3^ and Z = 16.[PUBLICATION ABSTRACT]</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-009-9286-9</identifier><language>eng</language><publisher>Dordrecht: Springer Nature B.V</publisher><subject>Analytical chemistry ; Crystal structure</subject><ispartof>Transition metal chemistry (Weinheim), 2009-11, Vol.34 (8), p.949</ispartof><rights>Springer Science+Business Media B.V. 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Paim, Lilian A</creatorcontrib><creatorcontrib>Batista, Alzir A</creatorcontrib><creatorcontrib>Dias, Fabrícia M</creatorcontrib><creatorcontrib>Golfeto, Camilla C</creatorcontrib><creatorcontrib>Ellena, Javier</creatorcontrib><creatorcontrib>Siebald, Helmuth G; L</creatorcontrib><creatorcontrib>Ardisson, J D</creatorcontrib><title>Heterobimetallic compounds [Ru([eta]5-Cp)(dppf)X] (X = Cl, Br, I and N3): synthesis, electrochemical analysis, and the crystal structure of [Ru([eta]5-Cp)(dppf)I] [dppf = 1,1'-bis(diphenylphosphino)ferrocene]</title><title>Transition metal chemistry (Weinheim)</title><description>A series of new ruthenium-iron based derivatives [Ru(η^sup 5^-Cp)(dppf)Cl] (1), [Ru(η^sup 5^-Cp)(dppf)Br] (2), [Ru(η^sup 5^-Cp)(dppf)I] (3) and [Ru(η^sup 5^-Cp)(dppf)N^sub 3^] (4) were obtained by reactions of [Ru(η^sup 5^-Cp)(PPh^sub 3^)^sub 2^Cl] with 1,1'-bis(diphenylphosphino) ferrocene (dppf) and characterized by IR, NMR (^sup 1^H, ^sup 13^C and ^sup 31^P), ^sup 57^Fe Mössbauer spectroscopy and cyclic voltammetry. 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Additionally, the compound (3) was structurally characterized by X-ray crystallography, and the results were as follows: orthorhombic, Pbca, a = 18.2458(10), b = 20.9192(11), c = 34.4138(19) , α = β = γ = 90°, V = 13135.3(12) ^sup 3^ and Z = 16.[PUBLICATION ABSTRACT]</abstract><cop>Dordrecht</cop><pub>Springer Nature B.V</pub><doi>10.1007/s11243-009-9286-9</doi></addata></record> |
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| subjects | Analytical chemistry Crystal structure |
| title | Heterobimetallic compounds [Ru([eta]5-Cp)(dppf)X] (X = Cl, Br, I and N3): synthesis, electrochemical analysis, and the crystal structure of [Ru([eta]5-Cp)(dppf)I] [dppf = 1,1'-bis(diphenylphosphino)ferrocene] |
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