Intermediate and ion-pair formation in the outer-sphere reactions between azido-pentacyanocobaltate(III) and iron(II) polypyridyl complexes in aqueous medium

The kinetics of the reactions between azido-pentacyanocobaltate(III), Co(CN) 5 N 3 3− , and iron(II) polypyridyl complexes, Fe(LL) 3 2+ (LL = bipy, phen), have been studied in both neutral and acidic aqueous solutions at I  = 0.1 mol dm −3 NaCl. The reactions were carried out under pseudo-first-orde...

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Veröffentlicht in:	Transition metal chemistry (Weinheim) 2009-08, Vol.34 (5), p.483-491
Hauptverfasser:	Ogunlusi, Grace O., Ige, Jide, Oyetunji, Olayinka A., Ojo, Jonathan F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Aqueous solutions Catalysis Chemistry Chemistry and Materials Science Inorganic Chemistry Organometallic Chemistry Physical Chemistry
Online-Zugang:	Volltext
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