Tellurium clusters in channels of the porous silica ZSM-11
The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not rando...
Gespeichert in:
| Veröffentlicht in: | Glass physics and chemistry 2008-04, Vol.34 (2), p.182-186 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 186 |
|---|---|
| container_issue | 2 |
| container_start_page | 182 |
| container_title | Glass physics and chemistry |
| container_volume | 34 |
| creator | Lapshin, A. E. Shepelev, Yu. F. Smolin, Yu. I. Vasil’eva, E. A. |
| description | The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) Å. The clusters Te
4
are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) Å. |
| doi_str_mv | 10.1134/S1087659608020119 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_881095500</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2664884771</sourcerecordid><originalsourceid>FETCH-LOGICAL-c343t-1041a9fb262782ed05e53e95d4f7fb52187005c8d95828e384a7ba10f952ddf53</originalsourceid><addsrcrecordid>eNp1kE9LAzEQxYMoWKsfwFvQ8-pM_mwSb1KsChUPrSBelnQ3sVu2uzXZPfjtTangQXqaGd7vvYFHyCXCDSIXt3MErXJpctDAANEckRGmI-PI34_TnuRsp5-SsxjXAGCUEiNyt3BNM4R62NCyGWLvQqR1S8uVbVvXRNp52q8c3XahGyKNdVOXln7MXzLEc3LibRPdxe8ck7fpw2LylM1eH58n97Os5IL3GYJAa_yS5Uxp5iqQTnJnZCW88kvJUCsAWerKSM2041pYtbQI3khWVV7yMbna525D9zW42BfrbghtellojWCkBEjQ9SGI5bnQWiiFicI9VYYuxuB8sQ31xobvAqHY9Vj86zF52N4TE9t-uvCXfNj0A6htcVU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2664884771</pqid></control><display><type>article</type><title>Tellurium clusters in channels of the porous silica ZSM-11</title><source>Springer Nature - Complete Springer Journals</source><creator>Lapshin, A. E. ; Shepelev, Yu. F. ; Smolin, Yu. I. ; Vasil’eva, E. A.</creator><creatorcontrib>Lapshin, A. E. ; Shepelev, Yu. F. ; Smolin, Yu. I. ; Vasil’eva, E. A.</creatorcontrib><description>The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) Å. The clusters Te
4
are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) Å.</description><identifier>ISSN: 1087-6596</identifier><identifier>EISSN: 1608-313X</identifier><identifier>DOI: 10.1134/S1087659608020119</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Ceramics ; Channels ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Clusters ; Composites ; Crystal structure ; Glass ; Materials Science ; Maximum entropy method ; Nanoclusters ; Natural Materials ; Physical Chemistry ; Silicon dioxide ; Tellurium ; Tetrahedra</subject><ispartof>Glass physics and chemistry, 2008-04, Vol.34 (2), p.182-186</ispartof><rights>MAIK Nauka 2008</rights><rights>MAIK Nauka 2008.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c343t-1041a9fb262782ed05e53e95d4f7fb52187005c8d95828e384a7ba10f952ddf53</citedby><cites>FETCH-LOGICAL-c343t-1041a9fb262782ed05e53e95d4f7fb52187005c8d95828e384a7ba10f952ddf53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1087659608020119$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1087659608020119$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lapshin, A. E.</creatorcontrib><creatorcontrib>Shepelev, Yu. F.</creatorcontrib><creatorcontrib>Smolin, Yu. I.</creatorcontrib><creatorcontrib>Vasil’eva, E. A.</creatorcontrib><title>Tellurium clusters in channels of the porous silica ZSM-11</title><title>Glass physics and chemistry</title><addtitle>Glass Phys Chem</addtitle><description>The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) Å. The clusters Te
4
are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) Å.</description><subject>Ceramics</subject><subject>Channels</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Clusters</subject><subject>Composites</subject><subject>Crystal structure</subject><subject>Glass</subject><subject>Materials Science</subject><subject>Maximum entropy method</subject><subject>Nanoclusters</subject><subject>Natural Materials</subject><subject>Physical Chemistry</subject><subject>Silicon dioxide</subject><subject>Tellurium</subject><subject>Tetrahedra</subject><issn>1087-6596</issn><issn>1608-313X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvQ8-pM_mwSb1KsChUPrSBelnQ3sVu2uzXZPfjtTangQXqaGd7vvYFHyCXCDSIXt3MErXJpctDAANEckRGmI-PI34_TnuRsp5-SsxjXAGCUEiNyt3BNM4R62NCyGWLvQqR1S8uVbVvXRNp52q8c3XahGyKNdVOXln7MXzLEc3LibRPdxe8ck7fpw2LylM1eH58n97Os5IL3GYJAa_yS5Uxp5iqQTnJnZCW88kvJUCsAWerKSM2041pYtbQI3khWVV7yMbna525D9zW42BfrbghtellojWCkBEjQ9SGI5bnQWiiFicI9VYYuxuB8sQ31xobvAqHY9Vj86zF52N4TE9t-uvCXfNj0A6htcVU</recordid><startdate>20080401</startdate><enddate>20080401</enddate><creator>Lapshin, A. E.</creator><creator>Shepelev, Yu. F.</creator><creator>Smolin, Yu. I.</creator><creator>Vasil’eva, E. A.</creator><general>SP MAIK Nauka/Interperiodica</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080401</creationdate><title>Tellurium clusters in channels of the porous silica ZSM-11</title><author>Lapshin, A. E. ; Shepelev, Yu. F. ; Smolin, Yu. I. ; Vasil’eva, E. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c343t-1041a9fb262782ed05e53e95d4f7fb52187005c8d95828e384a7ba10f952ddf53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Ceramics</topic><topic>Channels</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Clusters</topic><topic>Composites</topic><topic>Crystal structure</topic><topic>Glass</topic><topic>Materials Science</topic><topic>Maximum entropy method</topic><topic>Nanoclusters</topic><topic>Natural Materials</topic><topic>Physical Chemistry</topic><topic>Silicon dioxide</topic><topic>Tellurium</topic><topic>Tetrahedra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lapshin, A. E.</creatorcontrib><creatorcontrib>Shepelev, Yu. F.</creatorcontrib><creatorcontrib>Smolin, Yu. I.</creatorcontrib><creatorcontrib>Vasil’eva, E. A.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Glass physics and chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lapshin, A. E.</au><au>Shepelev, Yu. F.</au><au>Smolin, Yu. I.</au><au>Vasil’eva, E. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tellurium clusters in channels of the porous silica ZSM-11</atitle><jtitle>Glass physics and chemistry</jtitle><stitle>Glass Phys Chem</stitle><date>2008-04-01</date><risdate>2008</risdate><volume>34</volume><issue>2</issue><spage>182</spage><epage>186</epage><pages>182-186</pages><issn>1087-6596</issn><eissn>1608-313X</eissn><abstract>The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) Å. The clusters Te
4
are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) Å.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1087659608020119</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1087-6596 |
| ispartof | Glass physics and chemistry, 2008-04, Vol.34 (2), p.182-186 |
| issn | 1087-6596 1608-313X |
| language | eng |
| recordid | cdi_proquest_journals_881095500 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Ceramics Channels Characterization and Evaluation of Materials Chemistry and Materials Science Clusters Composites Crystal structure Glass Materials Science Maximum entropy method Nanoclusters Natural Materials Physical Chemistry Silicon dioxide Tellurium Tetrahedra |
| title | Tellurium clusters in channels of the porous silica ZSM-11 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T16%3A21%3A19IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tellurium%20clusters%20in%20channels%20of%20the%20porous%20silica%20ZSM-11&rft.jtitle=Glass%20physics%20and%20chemistry&rft.au=Lapshin,%20A.%20E.&rft.date=2008-04-01&rft.volume=34&rft.issue=2&rft.spage=182&rft.epage=186&rft.pages=182-186&rft.issn=1087-6596&rft.eissn=1608-313X&rft_id=info:doi/10.1134/S1087659608020119&rft_dat=%3Cproquest_cross%3E2664884771%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2664884771&rft_id=info:pmid/&rfr_iscdi=true |