Synthesis and crystal structure of a new modification of sodium tetrahydroxyborate NaB(OH)4
A new polymorphic modification of sodium tetrahydroxyborate NaB(OH) 4 is synthesized and its crystal structure is determined. The compound crystallizes in symmetry space group P 2 1 2 1 2 1 with the unit cell parameters a = 5.323(5) Å, b = 9.496(5) Å, and c = 6.596(5) Å. The discrepancy factor for 5...
Gespeichert in:
| Veröffentlicht in: | Glass physics and chemistry 2009-06, Vol.35 (3), p.308-312 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 312 |
|---|---|
| container_issue | 3 |
| container_start_page | 308 |
| container_title | Glass physics and chemistry |
| container_volume | 35 |
| creator | Lapshin, A. E. Medvedev, E. F. Polyakova, I. G. Shepelev, Yu. F. |
| description | A new polymorphic modification of sodium tetrahydroxyborate NaB(OH)
4
is synthesized and its crystal structure is determined. The compound crystallizes in symmetry space group
P
2
1
2
1
2
1
with the unit cell parameters
a
= 5.323(5) Å,
b
= 9.496(5) Å, and
c
= 6.596(5) Å. The discrepancy factor for 511 symmetrically nonequivalent reflections is
R
= 0.0188. Layers that are formed by boron tetrahedra, aligned parallel to the (010) planes, and alternate with layers of sodium cations can be distinguished in the structure. |
| doi_str_mv | 10.1134/S1087659609030110 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_881094646</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2417031991</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2300-915ac2889fab3d1b43ad806adb206d8a896335340a7492d9c648899ae9b844133</originalsourceid><addsrcrecordid>eNp1kE9LAzEQxYMoWKsfwFvwpIfVySZNk6OKWqHYQxUED8vsJmu3tJuaZNH99qZU8CCe5s_7vTcwhJwyuGSMi6s5AzWWIy1BAwfGYI8MmASVccZf91Of5GyrH5KjEJYAoMdjMSBv876NCxuaQLE1tPJ9iLiiIfquip231NUUaWs_6dqZpm4qjI1rt9uQ5m5No40eF73x7qsvncdo6RPenM8mF-KYHNS4Cvbkpw7Jy_3d8-0km84eHm-vp1mVc4BMsxFWuVK6xpIbVgqORoFEU-YgjUKlJecjLgDHQudGV1IkWKPVpRKCcT4kZ7vcjXcfnQ2xWLrOt-lkoRQDLaSQCWI7qPIuBG_rYuObNfq-YFBsX1j8eWHy5DtPSGz7bv1v8P-mb8MVchI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>881094646</pqid></control><display><type>article</type><title>Synthesis and crystal structure of a new modification of sodium tetrahydroxyborate NaB(OH)4</title><source>Springer Nature - Complete Springer Journals</source><creator>Lapshin, A. E. ; Medvedev, E. F. ; Polyakova, I. G. ; Shepelev, Yu. F.</creator><creatorcontrib>Lapshin, A. E. ; Medvedev, E. F. ; Polyakova, I. G. ; Shepelev, Yu. F.</creatorcontrib><description>A new polymorphic modification of sodium tetrahydroxyborate NaB(OH)
4
is synthesized and its crystal structure is determined. The compound crystallizes in symmetry space group
P
2
1
2
1
2
1
with the unit cell parameters
a
= 5.323(5) Å,
b
= 9.496(5) Å, and
c
= 6.596(5) Å. The discrepancy factor for 511 symmetrically nonequivalent reflections is
R
= 0.0188. Layers that are formed by boron tetrahedra, aligned parallel to the (010) planes, and alternate with layers of sodium cations can be distinguished in the structure.</description><identifier>ISSN: 1087-6596</identifier><identifier>EISSN: 1608-313X</identifier><identifier>DOI: 10.1134/S1087659609030110</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Crystal structure ; Glass ; Materials Science ; Minerals ; Natural Materials ; Physical Chemistry</subject><ispartof>Glass physics and chemistry, 2009-06, Vol.35 (3), p.308-312</ispartof><rights>Pleiades Publishing, Ltd. 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2300-915ac2889fab3d1b43ad806adb206d8a896335340a7492d9c648899ae9b844133</citedby><cites>FETCH-LOGICAL-c2300-915ac2889fab3d1b43ad806adb206d8a896335340a7492d9c648899ae9b844133</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1087659609030110$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1087659609030110$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lapshin, A. E.</creatorcontrib><creatorcontrib>Medvedev, E. F.</creatorcontrib><creatorcontrib>Polyakova, I. G.</creatorcontrib><creatorcontrib>Shepelev, Yu. F.</creatorcontrib><title>Synthesis and crystal structure of a new modification of sodium tetrahydroxyborate NaB(OH)4</title><title>Glass physics and chemistry</title><addtitle>Glass Phys Chem</addtitle><description>A new polymorphic modification of sodium tetrahydroxyborate NaB(OH)
4
is synthesized and its crystal structure is determined. The compound crystallizes in symmetry space group
P
2
1
2
1
2
1
with the unit cell parameters
a
= 5.323(5) Å,
b
= 9.496(5) Å, and
c
= 6.596(5) Å. The discrepancy factor for 511 symmetrically nonequivalent reflections is
R
= 0.0188. Layers that are formed by boron tetrahedra, aligned parallel to the (010) planes, and alternate with layers of sodium cations can be distinguished in the structure.</description><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Crystal structure</subject><subject>Glass</subject><subject>Materials Science</subject><subject>Minerals</subject><subject>Natural Materials</subject><subject>Physical Chemistry</subject><issn>1087-6596</issn><issn>1608-313X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvwpIfVySZNk6OKWqHYQxUED8vsJmu3tJuaZNH99qZU8CCe5s_7vTcwhJwyuGSMi6s5AzWWIy1BAwfGYI8MmASVccZf91Of5GyrH5KjEJYAoMdjMSBv876NCxuaQLE1tPJ9iLiiIfquip231NUUaWs_6dqZpm4qjI1rt9uQ5m5No40eF73x7qsvncdo6RPenM8mF-KYHNS4Cvbkpw7Jy_3d8-0km84eHm-vp1mVc4BMsxFWuVK6xpIbVgqORoFEU-YgjUKlJecjLgDHQudGV1IkWKPVpRKCcT4kZ7vcjXcfnQ2xWLrOt-lkoRQDLaSQCWI7qPIuBG_rYuObNfq-YFBsX1j8eWHy5DtPSGz7bv1v8P-mb8MVchI</recordid><startdate>200906</startdate><enddate>200906</enddate><creator>Lapshin, A. E.</creator><creator>Medvedev, E. F.</creator><creator>Polyakova, I. G.</creator><creator>Shepelev, Yu. F.</creator><general>SP MAIK Nauka/Interperiodica</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200906</creationdate><title>Synthesis and crystal structure of a new modification of sodium tetrahydroxyborate NaB(OH)4</title><author>Lapshin, A. E. ; Medvedev, E. F. ; Polyakova, I. G. ; Shepelev, Yu. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2300-915ac2889fab3d1b43ad806adb206d8a896335340a7492d9c648899ae9b844133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Crystal structure</topic><topic>Glass</topic><topic>Materials Science</topic><topic>Minerals</topic><topic>Natural Materials</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lapshin, A. E.</creatorcontrib><creatorcontrib>Medvedev, E. F.</creatorcontrib><creatorcontrib>Polyakova, I. G.</creatorcontrib><creatorcontrib>Shepelev, Yu. F.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Glass physics and chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lapshin, A. E.</au><au>Medvedev, E. F.</au><au>Polyakova, I. G.</au><au>Shepelev, Yu. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and crystal structure of a new modification of sodium tetrahydroxyborate NaB(OH)4</atitle><jtitle>Glass physics and chemistry</jtitle><stitle>Glass Phys Chem</stitle><date>2009-06</date><risdate>2009</risdate><volume>35</volume><issue>3</issue><spage>308</spage><epage>312</epage><pages>308-312</pages><issn>1087-6596</issn><eissn>1608-313X</eissn><abstract>A new polymorphic modification of sodium tetrahydroxyborate NaB(OH)
4
is synthesized and its crystal structure is determined. The compound crystallizes in symmetry space group
P
2
1
2
1
2
1
with the unit cell parameters
a
= 5.323(5) Å,
b
= 9.496(5) Å, and
c
= 6.596(5) Å. The discrepancy factor for 511 symmetrically nonequivalent reflections is
R
= 0.0188. Layers that are formed by boron tetrahedra, aligned parallel to the (010) planes, and alternate with layers of sodium cations can be distinguished in the structure.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1087659609030110</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1087-6596 |
| ispartof | Glass physics and chemistry, 2009-06, Vol.35 (3), p.308-312 |
| issn | 1087-6596 1608-313X |
| language | eng |
| recordid | cdi_proquest_journals_881094646 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Crystal structure Glass Materials Science Minerals Natural Materials Physical Chemistry |
| title | Synthesis and crystal structure of a new modification of sodium tetrahydroxyborate NaB(OH)4 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T16%3A13%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20crystal%20structure%20of%20a%20new%20modification%20of%20sodium%20tetrahydroxyborate%20NaB(OH)4&rft.jtitle=Glass%20physics%20and%20chemistry&rft.au=Lapshin,%20A.%20E.&rft.date=2009-06&rft.volume=35&rft.issue=3&rft.spage=308&rft.epage=312&rft.pages=308-312&rft.issn=1087-6596&rft.eissn=1608-313X&rft_id=info:doi/10.1134/S1087659609030110&rft_dat=%3Cproquest_cross%3E2417031991%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=881094646&rft_id=info:pmid/&rfr_iscdi=true |