Thermal Behavior of Alkali Zinc Phosphates
Alkali zinc phosphates Na2ZnP2O7, K2ZnP2O7, LiNaZnP2O7, LiKZnP2O7, NaKZnP2O7, and Li12Zn4(P2O7)5, which can be prepared both by the solid-phase synthesis and through crystallization from a glass, are studied using high-temperature X-ray powder diffraction. The unit cell parameters as functions of th...
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| Veröffentlicht in: | Glass physics and chemistry 2005-09, Vol.31 (5), p.684-689 |
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| creator | Lapshin, A E Petrova, M A Osipova, Yu N Novikova, A S Shepelev, Yu F |
| description | Alkali zinc phosphates Na2ZnP2O7, K2ZnP2O7, LiNaZnP2O7, LiKZnP2O7, NaKZnP2O7, and Li12Zn4(P2O7)5, which can be prepared both by the solid-phase synthesis and through crystallization from a glass, are studied using high-temperature X-ray powder diffraction. The unit cell parameters as functions of the temperature in the range 20–700°C are analyzed, and the linear anisotropic thermal expansion coefficients are determined. The majority of these compounds are characterized by strong anisotropy of thermal expansion. It is found that the LiKZnP2O7 compound exists in two polymorphic modifications, namely, the low-temperature monoclinic modification and the high-temperature orthorhombic modification. |
| doi_str_mv | 10.1007/s10720-005-0114-9 |
| format | Article |
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The unit cell parameters as functions of the temperature in the range 20–700°C are analyzed, and the linear anisotropic thermal expansion coefficients are determined. The majority of these compounds are characterized by strong anisotropy of thermal expansion. It is found that the LiKZnP2O7 compound exists in two polymorphic modifications, namely, the low-temperature monoclinic modification and the high-temperature orthorhombic modification.</description><identifier>ISSN: 1087-6596</identifier><identifier>EISSN: 1608-313X</identifier><identifier>DOI: 10.1007/s10720-005-0114-9</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Anisotropy ; Crystallization ; Diffraction ; High temperature ; Low temperature ; Mineralogy ; Solid phase synthesis ; Thermal expansion ; Thermodynamic properties ; Unit cell ; X ray powder diffraction ; Zinc phosphate</subject><ispartof>Glass physics and chemistry, 2005-09, Vol.31 (5), p.684-689</ispartof><rights>MAIK "Nauka/Interperiodica" 2005.</rights><rights>MAIK "Nauka/Interperiodica" 2005</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c300t-8eb227acd50361606d30009dd49f9a768b11b4e37f682b08d01fe3579995b2b23</citedby><cites>FETCH-LOGICAL-c300t-8eb227acd50361606d30009dd49f9a768b11b4e37f682b08d01fe3579995b2b23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Lapshin, A E</creatorcontrib><creatorcontrib>Petrova, M A</creatorcontrib><creatorcontrib>Osipova, Yu N</creatorcontrib><creatorcontrib>Novikova, A S</creatorcontrib><creatorcontrib>Shepelev, Yu F</creatorcontrib><title>Thermal Behavior of Alkali Zinc Phosphates</title><title>Glass physics and chemistry</title><description>Alkali zinc phosphates Na2ZnP2O7, K2ZnP2O7, LiNaZnP2O7, LiKZnP2O7, NaKZnP2O7, and Li12Zn4(P2O7)5, which can be prepared both by the solid-phase synthesis and through crystallization from a glass, are studied using high-temperature X-ray powder diffraction. The unit cell parameters as functions of the temperature in the range 20–700°C are analyzed, and the linear anisotropic thermal expansion coefficients are determined. The majority of these compounds are characterized by strong anisotropy of thermal expansion. It is found that the LiKZnP2O7 compound exists in two polymorphic modifications, namely, the low-temperature monoclinic modification and the high-temperature orthorhombic modification.</description><subject>Anisotropy</subject><subject>Crystallization</subject><subject>Diffraction</subject><subject>High temperature</subject><subject>Low temperature</subject><subject>Mineralogy</subject><subject>Solid phase synthesis</subject><subject>Thermal expansion</subject><subject>Thermodynamic properties</subject><subject>Unit cell</subject><subject>X ray powder diffraction</subject><subject>Zinc phosphate</subject><issn>1087-6596</issn><issn>1608-313X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG9Fb0J0JmnzcVyX9QMW9LCCeAlpm9Ku3W1NuoL_3pR69TRzeJh33oeQS4RbBJB3AUEyoAAZBcSU6iMyQwGKcuTvx3EHJanItDglZyFsAUBLmc7IzaZ2fmfb5N7V9rvpfNJVyaL9tG2TfDT7Inmtu9DXdnDhnJxUtg3u4m_OydvDarN8ouuXx-flYk0LDjBQ5XLGpC3KDLiIL4iSj2llmepKWylUjpinjstKKJaDKgErxzOptc5yljM-J1fT3d53XwcXBrPtDn4fI41SsQfnPI3Q9X8QEyIFgSo2nxOcqMJ3IXhXmd43O-t_DIIZvZnJm4nezOjNaP4LQrhcug</recordid><startdate>20050901</startdate><enddate>20050901</enddate><creator>Lapshin, A E</creator><creator>Petrova, M A</creator><creator>Osipova, Yu N</creator><creator>Novikova, A S</creator><creator>Shepelev, Yu F</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20050901</creationdate><title>Thermal Behavior of Alkali Zinc Phosphates</title><author>Lapshin, A E ; Petrova, M A ; Osipova, Yu N ; Novikova, A S ; Shepelev, Yu F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c300t-8eb227acd50361606d30009dd49f9a768b11b4e37f682b08d01fe3579995b2b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Anisotropy</topic><topic>Crystallization</topic><topic>Diffraction</topic><topic>High temperature</topic><topic>Low temperature</topic><topic>Mineralogy</topic><topic>Solid phase synthesis</topic><topic>Thermal expansion</topic><topic>Thermodynamic properties</topic><topic>Unit cell</topic><topic>X ray powder diffraction</topic><topic>Zinc phosphate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lapshin, A E</creatorcontrib><creatorcontrib>Petrova, M A</creatorcontrib><creatorcontrib>Osipova, Yu N</creatorcontrib><creatorcontrib>Novikova, A S</creatorcontrib><creatorcontrib>Shepelev, Yu F</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Glass physics and chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lapshin, A E</au><au>Petrova, M A</au><au>Osipova, Yu N</au><au>Novikova, A S</au><au>Shepelev, Yu F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal Behavior of Alkali Zinc Phosphates</atitle><jtitle>Glass physics and chemistry</jtitle><date>2005-09-01</date><risdate>2005</risdate><volume>31</volume><issue>5</issue><spage>684</spage><epage>689</epage><pages>684-689</pages><issn>1087-6596</issn><eissn>1608-313X</eissn><abstract>Alkali zinc phosphates Na2ZnP2O7, K2ZnP2O7, LiNaZnP2O7, LiKZnP2O7, NaKZnP2O7, and Li12Zn4(P2O7)5, which can be prepared both by the solid-phase synthesis and through crystallization from a glass, are studied using high-temperature X-ray powder diffraction. The unit cell parameters as functions of the temperature in the range 20–700°C are analyzed, and the linear anisotropic thermal expansion coefficients are determined. The majority of these compounds are characterized by strong anisotropy of thermal expansion. It is found that the LiKZnP2O7 compound exists in two polymorphic modifications, namely, the low-temperature monoclinic modification and the high-temperature orthorhombic modification.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s10720-005-0114-9</doi><tpages>6</tpages></addata></record> |
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| subjects | Anisotropy Crystallization Diffraction High temperature Low temperature Mineralogy Solid phase synthesis Thermal expansion Thermodynamic properties Unit cell X ray powder diffraction Zinc phosphate |
| title | Thermal Behavior of Alkali Zinc Phosphates |
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