Identification of Camphor Oxidation and Reduction Products in Pseudomonas putida: New Activity of the Cytochrome P450^sub cam^ System
P450 enzymes are known for catalyzing hydroxylation reactions of non-activated C-H bonds. For example, P450^sub cam^ from Pseudomonas putida oxidizes (1R)-(+)-camphor to 5-exo-hydroxy camphor and further to 5-ketocamphor. This hydroxylation reaction proceeds via a catalytic cycle in which the reduct...
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Veröffentlicht in: | Journal of chemical ecology 2011-06, Vol.37 (6), p.657 |
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Sprache: | eng |
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