Synthesis and performance evaluation of polyurethane silica hybrid resins
Purpose - The aim of this paper is to synthesise polyester silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico-chemical and thermal properties of polyuretha...
Gespeichert in:
Veröffentlicht in: | Pigment & resin technology 2011-01, Vol.40 (1), p.49-57 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 57 |
---|---|
container_issue | 1 |
container_start_page | 49 |
container_title | Pigment & resin technology |
container_volume | 40 |
creator | Athawale, Vilas D Kulkarni, Mona A |
description | Purpose - The aim of this paper is to synthesise polyester silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico-chemical and thermal properties of polyurethane silica (PU Silica) hybrid coatings.Design methodology approach - Silica particle-containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester silica resin was further crosslinked with TMP-TDI adduct to synthesise PU Silica hybrid coatings and studied for thermo-mechanical, physico-chemical properties.Findings - It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.Research limitations implications - In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.Practical implications - The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.Originality value - Hybrid organic-inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi-functional properties. |
doi_str_mv | 10.1108/03699421111095946 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_818545263</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2216264001</sourcerecordid><originalsourceid>FETCH-LOGICAL-c382t-f219aa314301d797f53840254f5cf353802823626b0fecafb2e8ab9f59b8616f3</originalsourceid><addsrcrecordid>eNqNkE1LxDAQhoMouH78AG_Bixer-W5ylMWPhQUP6jmkbcJ2SZuatEL_vVnWk-vBuQzDPM_wMgBcYXSHMZL3iAqlGMG5kOKKiSOwwCWXhVAMH4PFbl9kAJ2Cs5S2CCFCSrUAq7e5Hzc2tQmavoGDjS7EzvS1hfbL-MmMbehhcHAIfp6iHTemtzC1vq0N3MxVbBsYs96nC3DijE_28qefg4-nx_flS7F-fV4tH9ZFTSUZC0ewMoZiRhFuSlU6TiVDhDPHa0fzgIgkVBBRIWdr4ypipamU46qSAgtHz8HN_u4Qw-dk06i7NtXW-xwsTElLzoVUHPNMXv8it2GKfQ6nJZaccSJohvAeqmNIKVqnh9h2Js4aI717rT54bXbQ3rGdjcY3_1Ju_1YOUD00jn4DTLWGpw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>818545263</pqid></control><display><type>article</type><title>Synthesis and performance evaluation of polyurethane silica hybrid resins</title><source>Emerald A-Z Current Journals</source><creator>Athawale, Vilas D ; Kulkarni, Mona A</creator><creatorcontrib>Athawale, Vilas D ; Kulkarni, Mona A</creatorcontrib><description>Purpose - The aim of this paper is to synthesise polyester silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico-chemical and thermal properties of polyurethane silica (PU Silica) hybrid coatings.Design methodology approach - Silica particle-containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester silica resin was further crosslinked with TMP-TDI adduct to synthesise PU Silica hybrid coatings and studied for thermo-mechanical, physico-chemical properties.Findings - It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.Research limitations implications - In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.Practical implications - The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.Originality value - Hybrid organic-inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi-functional properties.</description><identifier>ISSN: 0369-9420</identifier><identifier>EISSN: 1758-6941</identifier><identifier>DOI: 10.1108/03699421111095946</identifier><identifier>CODEN: PGRTBC</identifier><language>eng</language><publisher>Bradford: Emerald Group Publishing Limited</publisher><subject>Acids ; Blending ; Coatings ; Ethanol ; Fluorides ; Fourier transforms ; Nanoparticles ; Performance evaluation ; Polyester resins ; Polyesters ; Polymerization ; Polymers ; Polyurethane ; Polyurethane resins ; Protective coatings ; Resins ; Scanning electron microscopy ; Silica ; Silicon dioxide ; Spectrum analysis ; Studies ; Temperature ; Thermal properties ; Thermogravimetric analysis</subject><ispartof>Pigment & resin technology, 2011-01, Vol.40 (1), p.49-57</ispartof><rights>Emerald Group Publishing Limited</rights><rights>Copyright Emerald Group Publishing Limited 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c382t-f219aa314301d797f53840254f5cf353802823626b0fecafb2e8ab9f59b8616f3</citedby><cites>FETCH-LOGICAL-c382t-f219aa314301d797f53840254f5cf353802823626b0fecafb2e8ab9f59b8616f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.emerald.com/insight/content/doi/10.1108/03699421111095946/full/pdf$$EPDF$$P50$$Gemerald$$H</linktopdf><linktohtml>$$Uhttps://www.emerald.com/insight/content/doi/10.1108/03699421111095946/full/html$$EHTML$$P50$$Gemerald$$H</linktohtml><link.rule.ids>314,780,784,967,11635,27924,27925,52686,52689</link.rule.ids></links><search><creatorcontrib>Athawale, Vilas D</creatorcontrib><creatorcontrib>Kulkarni, Mona A</creatorcontrib><title>Synthesis and performance evaluation of polyurethane silica hybrid resins</title><title>Pigment & resin technology</title><description>Purpose - The aim of this paper is to synthesise polyester silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico-chemical and thermal properties of polyurethane silica (PU Silica) hybrid coatings.Design methodology approach - Silica particle-containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester silica resin was further crosslinked with TMP-TDI adduct to synthesise PU Silica hybrid coatings and studied for thermo-mechanical, physico-chemical properties.Findings - It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.Research limitations implications - In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.Practical implications - The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.Originality value - Hybrid organic-inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi-functional properties.</description><subject>Acids</subject><subject>Blending</subject><subject>Coatings</subject><subject>Ethanol</subject><subject>Fluorides</subject><subject>Fourier transforms</subject><subject>Nanoparticles</subject><subject>Performance evaluation</subject><subject>Polyester resins</subject><subject>Polyesters</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polyurethane</subject><subject>Polyurethane resins</subject><subject>Protective coatings</subject><subject>Resins</subject><subject>Scanning electron microscopy</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Spectrum analysis</subject><subject>Studies</subject><subject>Temperature</subject><subject>Thermal properties</subject><subject>Thermogravimetric analysis</subject><issn>0369-9420</issn><issn>1758-6941</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqNkE1LxDAQhoMouH78AG_Bixer-W5ylMWPhQUP6jmkbcJ2SZuatEL_vVnWk-vBuQzDPM_wMgBcYXSHMZL3iAqlGMG5kOKKiSOwwCWXhVAMH4PFbl9kAJ2Cs5S2CCFCSrUAq7e5Hzc2tQmavoGDjS7EzvS1hfbL-MmMbehhcHAIfp6iHTemtzC1vq0N3MxVbBsYs96nC3DijE_28qefg4-nx_flS7F-fV4tH9ZFTSUZC0ewMoZiRhFuSlU6TiVDhDPHa0fzgIgkVBBRIWdr4ypipamU46qSAgtHz8HN_u4Qw-dk06i7NtXW-xwsTElLzoVUHPNMXv8it2GKfQ6nJZaccSJohvAeqmNIKVqnh9h2Js4aI717rT54bXbQ3rGdjcY3_1Ju_1YOUD00jn4DTLWGpw</recordid><startdate>20110101</startdate><enddate>20110101</enddate><creator>Athawale, Vilas D</creator><creator>Kulkarni, Mona A</creator><general>Emerald Group Publishing Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7WY</scope><scope>7XB</scope><scope>8AF</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>M0F</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20110101</creationdate><title>Synthesis and performance evaluation of polyurethane silica hybrid resins</title><author>Athawale, Vilas D ; Kulkarni, Mona A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c382t-f219aa314301d797f53840254f5cf353802823626b0fecafb2e8ab9f59b8616f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Acids</topic><topic>Blending</topic><topic>Coatings</topic><topic>Ethanol</topic><topic>Fluorides</topic><topic>Fourier transforms</topic><topic>Nanoparticles</topic><topic>Performance evaluation</topic><topic>Polyester resins</topic><topic>Polyesters</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polyurethane</topic><topic>Polyurethane resins</topic><topic>Protective coatings</topic><topic>Resins</topic><topic>Scanning electron microscopy</topic><topic>Silica</topic><topic>Silicon dioxide</topic><topic>Spectrum analysis</topic><topic>Studies</topic><topic>Temperature</topic><topic>Thermal properties</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Athawale, Vilas D</creatorcontrib><creatorcontrib>Kulkarni, Mona A</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Access via ABI/INFORM (ProQuest)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>STEM Database</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Trade & Industry</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Pigment & resin technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Athawale, Vilas D</au><au>Kulkarni, Mona A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and performance evaluation of polyurethane silica hybrid resins</atitle><jtitle>Pigment & resin technology</jtitle><date>2011-01-01</date><risdate>2011</risdate><volume>40</volume><issue>1</issue><spage>49</spage><epage>57</epage><pages>49-57</pages><issn>0369-9420</issn><eissn>1758-6941</eissn><coden>PGRTBC</coden><abstract>Purpose - The aim of this paper is to synthesise polyester silica hybrid resins and their hybrid polyurethanes via in situ (IS) and blending (BL) methods and to evaluate the effect of preparation method, interaction type and silica content on the physico-chemical and thermal properties of polyurethane silica (PU Silica) hybrid coatings.Design methodology approach - Silica particle-containing silica sol was prepared according to Stöber method using tetraethylorthosilicate as the precursor and then introduced into polyester matrix by in situ and direct blending method. The modified polyester silica resin was further crosslinked with TMP-TDI adduct to synthesise PU Silica hybrid coatings and studied for thermo-mechanical, physico-chemical properties.Findings - It was found IS polymerisation caused more polyester segments to chemically bond onto the surface of silica particles than BL process. Results also reveal that due to stronger interaction between silica particles and PU matrix, hybrid resins prepared by IS method confers better properties than BL method and exhibit optimal properties at the critical concentration of 8 wt% silica.Research limitations implications - In the present study, silica particles are used to modify properties of polyurethane resins. Many other countless combinations in terms of inorganic filler or organic matrices can be explored to obtain a wide range of interesting properties and applications.Practical implications - The results obtained in this study will be extremely useful to enhance the understanding of this class of hybrid materials.Originality value - Hybrid organic-inorganic networks offer a new area of material science that has extraordinary implications for developing novel materials that exhibit a diverse range of multi-functional properties.</abstract><cop>Bradford</cop><pub>Emerald Group Publishing Limited</pub><doi>10.1108/03699421111095946</doi><tpages>9</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0369-9420 |
ispartof | Pigment & resin technology, 2011-01, Vol.40 (1), p.49-57 |
issn | 0369-9420 1758-6941 |
language | eng |
recordid | cdi_proquest_journals_818545263 |
source | Emerald A-Z Current Journals |
subjects | Acids Blending Coatings Ethanol Fluorides Fourier transforms Nanoparticles Performance evaluation Polyester resins Polyesters Polymerization Polymers Polyurethane Polyurethane resins Protective coatings Resins Scanning electron microscopy Silica Silicon dioxide Spectrum analysis Studies Temperature Thermal properties Thermogravimetric analysis |
title | Synthesis and performance evaluation of polyurethane silica hybrid resins |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T15%3A48%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20performance%20evaluation%20of%20polyurethane%20silica%20hybrid%20resins&rft.jtitle=Pigment%20&%20resin%20technology&rft.au=Athawale,%20Vilas%20D&rft.date=2011-01-01&rft.volume=40&rft.issue=1&rft.spage=49&rft.epage=57&rft.pages=49-57&rft.issn=0369-9420&rft.eissn=1758-6941&rft.coden=PGRTBC&rft_id=info:doi/10.1108/03699421111095946&rft_dat=%3Cproquest_cross%3E2216264001%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=818545263&rft_id=info:pmid/&rfr_iscdi=true |