Microinclusions in dark gray diamond crystals of octahedral habit from Yakutian kimberlites

Micrometer-sized inclusions in dark gray diamond crystals of octahedral habit from Yakutian kimberlites were studied by analytical scanning electron microscopy and analytical transmission electron microscopy. In addition to peridotite-suite silicate inclusions (enstatie and olivine), which were prev...

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Veröffentlicht in:Geochemistry international 2006-11, Vol.44 (11), p.1121-1128
Hauptverfasser: Titkov, S. V., Gorshkov, A. I., Zudin, N. G., Ryabchikov, I. D., Magazina, L. O., Sivtsov, A. V.
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container_end_page 1128
container_issue 11
container_start_page 1121
container_title Geochemistry international
container_volume 44
creator Titkov, S. V.
Gorshkov, A. I.
Zudin, N. G.
Ryabchikov, I. D.
Magazina, L. O.
Sivtsov, A. V.
description Micrometer-sized inclusions in dark gray diamond crystals of octahedral habit from Yakutian kimberlites were studied by analytical scanning electron microscopy and analytical transmission electron microscopy. In addition to peridotite-suite silicate inclusions (enstatie and olivine), which were previously studied in detail as macroinclusions in perfect diamond crystals, there are abundant inclusions of native metals (Fe-Cr and Fe-Cr-Ti intermetallic compounds and metallic Fe), sulfides (Fe-Ni sulfide, polydymite, and chalcopyrite), and carbonates (calcite). Rare grains of ilmenite, fluorite, apatite, zircon, phlogopite, and some other minerals were also found. The gray and black colors of diamonds were previously attributed to the presence of graphite. Although this phase was identified in the electron diffraction patterns of all the samples, its content was very low. Microinclusions of induced octahedral morphology composed of intimate enstatite-calcite intergrowths were also found. Possible deep processes responsible for the formation of diamonds with such a peculiar inclusion association are discussed in light of new data on experimental synthesis.[PUBLICATION ABSTRACT]
doi_str_mv 10.1134/S0016702906110036
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subjects Calcite
Carbonates
Crystals
Electron microscopes
Mineralogy
Sulfides
title Microinclusions in dark gray diamond crystals of octahedral habit from Yakutian kimberlites
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