Effects of Chemical Treatment on the Luminescence of ZnO

The effects of chemical treatment on the luminescence of ZnO were investigated by cathodoluminescence. For this purpose, ZnO ceramics and O- and Zn-terminated faces of ZnO single crystals were studied. The samples were dipped in KOH and HCl solutions as well as pure H 2 O for 3 min. H 2 O and HCl tr...

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Veröffentlicht in:Journal of electronic materials 2010-06, Vol.39 (6), p.761-765
Hauptverfasser: Dierre, B., Yuan, X. L., Armani, N., Fabbri, F., Salviati, G., Ueda, K., Sekiguchi, T.
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container_end_page 765
container_issue 6
container_start_page 761
container_title Journal of electronic materials
container_volume 39
creator Dierre, B.
Yuan, X. L.
Armani, N.
Fabbri, F.
Salviati, G.
Ueda, K.
Sekiguchi, T.
description The effects of chemical treatment on the luminescence of ZnO were investigated by cathodoluminescence. For this purpose, ZnO ceramics and O- and Zn-terminated faces of ZnO single crystals were studied. The samples were dipped in KOH and HCl solutions as well as pure H 2 O for 3 min. H 2 O and HCl treatments of ZnO ceramics can increase or decrease the initial ultraviolet (UV) intensity depending on the location examined, and induce an increase of the UV intensity under e-beam irradiation. HCl treatment of the Zn-face of ZnO single crystals slightly affects the surface morphology and the luminescence. HCl treatment of the O-face etches the surface to hexagonal pyramidal features. In addition, the initial UV intensity is always lower for the HCl-treated than for the untreated O-face, while the UV intensity increases at the beginning of e-beam irradiation. These results suggest that the UV intensity is influenced by the surface and bulk reactions of H + with ZnO.
doi_str_mv 10.1007/s11664-010-1124-5
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subjects Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Crystals
Electronics and Microelectronics
Etching
Exact sciences and technology
Ii-vi semiconductors
Instrumentation
Luminescence
Materials Science
Optical and Electronic Materials
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Photoluminescence
Physics
Solid State Physics
Zinc oxides
title Effects of Chemical Treatment on the Luminescence of ZnO
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