Calix[4]arene@MIL-101 as host@MOF for cage-in-cage pore space partitioning for enhanced CO2 separation and catalysis

Highly stable para-sulfonated calix[4]arene (SCA), a bowl-shaped macrocycle possessing intrinsic porosity, was incorporated into the spherical voids of the micro–mesoporous MIL-101(Cr) metal–organic framework by adsorptive loading from a solution. The pore-space partitioning in the MOF by polar func...

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Veröffentlicht in:	Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2025-01, Vol.13 (5), p.3894-3902
Hauptverfasser:	Saied Shafiei Navid, Rahman Hosseinzadeh, Oestreich, Robert, Abdpour, Soheil, Thi Hai Yen Beglau, Janiak, Christoph
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorptivity Aqueous solutions Cages Carbon dioxide Carboxylic acids Catalysis Catalytic activity Catalytic converters Chromium Esterification Leaching Metal-organic frameworks Partitioning Porosity Sulfuric acid
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