Effects of Tb(NO3)3 salt on the structural characteristics, optical, and radiation shielding properties of (PVA-PVP- PEG) polymeric composite films
Herein, this study introduces a simple, effective, and potentially successful approach to the preparation of polymeric composite systems using a Polyvinyl alcohol (PVA)-Polyvinyl pyrrolidone (PVP)-Polyethylene glycol (PEG) (PVA-PVP-PEG), (8:1:1) as the host polymeric blend with the inclusion of Tb(N...
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| creator | Mohammed, Mervat I. Zahran, Heba Y. Zyoud, Samer H. Shahwan, Moyad Aydin, Cihat Yahia, Ibrahim S. Abdelhameed, Doaa |
| description | Herein, this study introduces a simple, effective, and potentially successful approach to the preparation of polymeric composite systems using a Polyvinyl alcohol (PVA)-Polyvinyl pyrrolidone (PVP)-Polyethylene glycol (PEG) (PVA-PVP-PEG), (8:1:1) as the host polymeric blend with the inclusion of Tb(NO
3
)
3
-salt filler. The diffraction of X-rays (XRD), infrared spectroscopic (FTIR), Ultraviolet–visible (UV–vis) spectroscopy, and Phy-X/PSD software were utilized to analyze the modified samples’ structures, identify their optical and radiation shielding properties. The XRD patterns show the presence of Tb(NO
3
)
3
phases inside the composite matrix, where adding filler causes modifications in the polymeric network’s structure for filled composite samples. FTIR analysis showed that the Tb(NO
3
)
3
-salt interacted with the blend’s functional groups via H-bond formation. The UV–Vis spectra analysis showed all samples, especially those loaded with 8.0 wt.% Tb(NO
3
)
3
-salt has the highest values for absorbance, dielectric constant, refractive index, extinction coefficient, and optical and electrical conductivity. Tauc’s formula, the ASF model, and "
ε
i
-
h
v
plots were all applied to investigate optically the band gap in great detail. The values of
E
d
and
E
o
and
n
o
have been investigated using a single oscillator model where their values were controlled by Tb(NO
3
)
3
- salt content
.
Using calculated gap energy, various approaches were applied to obtain the conceptual significance of the linear refractive index
(
n
)
. The nonlinear optical parameters
χ
(
1
)
,
χ
(
3
)
, and
n
2
increased noticeably as the Tb(NO
3
)
3
-salt percentage is increased to 8.0 wt%. The suggested largely doped Tb(NO
3
)
3
-salt composites show great promise as a CUT-OFF laser filters and attenuators in addition to being used in laser power-limiting technology. Based on our results, the sample was 8.0 wt.% Tb(NO
3
)
3
-salt has better gamma-ray shielding properties than the others because it has the largest Tb(NO3)3-salt concentration. The study opens a new route to fabricate Tb(NO
3
)
3
/(PVA-PVP-PEG) polymeric composites with superior optical properties. |
| doi_str_mv | 10.1007/s10965-024-04219-6 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3155701017</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3155701017</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-fdcbfd2141e074feb5786d25355d3de02dd38fdc210487e1f3925cd955bb9e7d3</originalsourceid><addsrcrecordid>eNp9kLtOxDAQRSMEEs8foLJEAxKGsR3HSYnQ8pAQbAG0luMHa5SNg-0t9jv4YQyLREc1U9xzZ3Sq6pjABQEQl4lA13AMtMZQU9LhZqvaI1xQ3HaMb5cdKMWdaGC32k_pHYBz0bR71efMOatzQsGh5_708YmdMZTUkFEYUV5YlHJc6byKakB6oaLS2UafstfpHIWpTDWcIzUaFJXxKvuCpYW3g_HjG5pimGzM3v70n85fr_D8dY7RfHZ7hqYwrJelTCMdllNIPlvk_LBMh9WOU0OyR7_zoHq5mT1f3-GHp9v766sHrClAxs7o3hlKamJB1M72XLSNoZxxbpixQI1hbQlRAnUrLHGso1ybjvO-76ww7KA62fSWNz9WNmX5HlZxLCclI8UPECCipOgmpWNIKVonp-iXKq4lAfktX27kyyJf_siXTYHYBkolPL7Z-Ff9D_UFXLiIRw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3155701017</pqid></control><display><type>article</type><title>Effects of Tb(NO3)3 salt on the structural characteristics, optical, and radiation shielding properties of (PVA-PVP- PEG) polymeric composite films</title><source>SpringerLink Journals</source><creator>Mohammed, Mervat I. ; Zahran, Heba Y. ; Zyoud, Samer H. ; Shahwan, Moyad ; Aydin, Cihat ; Yahia, Ibrahim S. ; Abdelhameed, Doaa</creator><creatorcontrib>Mohammed, Mervat I. ; Zahran, Heba Y. ; Zyoud, Samer H. ; Shahwan, Moyad ; Aydin, Cihat ; Yahia, Ibrahim S. ; Abdelhameed, Doaa</creatorcontrib><description>Herein, this study introduces a simple, effective, and potentially successful approach to the preparation of polymeric composite systems using a Polyvinyl alcohol (PVA)-Polyvinyl pyrrolidone (PVP)-Polyethylene glycol (PEG) (PVA-PVP-PEG), (8:1:1) as the host polymeric blend with the inclusion of Tb(NO
3
)
3
-salt filler. The diffraction of X-rays (XRD), infrared spectroscopic (FTIR), Ultraviolet–visible (UV–vis) spectroscopy, and Phy-X/PSD software were utilized to analyze the modified samples’ structures, identify their optical and radiation shielding properties. The XRD patterns show the presence of Tb(NO
3
)
3
phases inside the composite matrix, where adding filler causes modifications in the polymeric network’s structure for filled composite samples. FTIR analysis showed that the Tb(NO
3
)
3
-salt interacted with the blend’s functional groups via H-bond formation. The UV–Vis spectra analysis showed all samples, especially those loaded with 8.0 wt.% Tb(NO
3
)
3
-salt has the highest values for absorbance, dielectric constant, refractive index, extinction coefficient, and optical and electrical conductivity. Tauc’s formula, the ASF model, and "
ε
i
-
h
v
plots were all applied to investigate optically the band gap in great detail. The values of
E
d
and
E
o
and
n
o
have been investigated using a single oscillator model where their values were controlled by Tb(NO
3
)
3
- salt content
.
Using calculated gap energy, various approaches were applied to obtain the conceptual significance of the linear refractive index
(
n
)
. The nonlinear optical parameters
χ
(
1
)
,
χ
(
3
)
, and
n
2
increased noticeably as the Tb(NO
3
)
3
-salt percentage is increased to 8.0 wt%. The suggested largely doped Tb(NO
3
)
3
-salt composites show great promise as a CUT-OFF laser filters and attenuators in addition to being used in laser power-limiting technology. Based on our results, the sample was 8.0 wt.% Tb(NO
3
)
3
-salt has better gamma-ray shielding properties than the others because it has the largest Tb(NO3)3-salt concentration. The study opens a new route to fabricate Tb(NO
3
)
3
/(PVA-PVP-PEG) polymeric composites with superior optical properties.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-024-04219-6</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Electrical resistivity ; Fillers ; Fourier transforms ; Functional groups ; Gamma rays ; Industrial Chemistry/Chemical Engineering ; Infrared analysis ; Infrared spectroscopy ; Nonlinear optics ; Optical properties ; Original Paper ; Polyethylene glycol ; Polymer matrix composites ; Polymer Sciences ; Polyvinyl alcohol ; Radiation ; Radiation shielding ; Refractivity ; Skeletal composites ; Spectrum analysis ; X-ray diffraction</subject><ispartof>Journal of polymer research, 2025, Vol.32 (1), Article 27</ispartof><rights>The Polymer Society, Taipei 2025 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. 2025</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-fdcbfd2141e074feb5786d25355d3de02dd38fdc210487e1f3925cd955bb9e7d3</cites><orcidid>0000-0001-9402-8140</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-024-04219-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-024-04219-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Mohammed, Mervat I.</creatorcontrib><creatorcontrib>Zahran, Heba Y.</creatorcontrib><creatorcontrib>Zyoud, Samer H.</creatorcontrib><creatorcontrib>Shahwan, Moyad</creatorcontrib><creatorcontrib>Aydin, Cihat</creatorcontrib><creatorcontrib>Yahia, Ibrahim S.</creatorcontrib><creatorcontrib>Abdelhameed, Doaa</creatorcontrib><title>Effects of Tb(NO3)3 salt on the structural characteristics, optical, and radiation shielding properties of (PVA-PVP- PEG) polymeric composite films</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>Herein, this study introduces a simple, effective, and potentially successful approach to the preparation of polymeric composite systems using a Polyvinyl alcohol (PVA)-Polyvinyl pyrrolidone (PVP)-Polyethylene glycol (PEG) (PVA-PVP-PEG), (8:1:1) as the host polymeric blend with the inclusion of Tb(NO
3
)
3
-salt filler. The diffraction of X-rays (XRD), infrared spectroscopic (FTIR), Ultraviolet–visible (UV–vis) spectroscopy, and Phy-X/PSD software were utilized to analyze the modified samples’ structures, identify their optical and radiation shielding properties. The XRD patterns show the presence of Tb(NO
3
)
3
phases inside the composite matrix, where adding filler causes modifications in the polymeric network’s structure for filled composite samples. FTIR analysis showed that the Tb(NO
3
)
3
-salt interacted with the blend’s functional groups via H-bond formation. The UV–Vis spectra analysis showed all samples, especially those loaded with 8.0 wt.% Tb(NO
3
)
3
-salt has the highest values for absorbance, dielectric constant, refractive index, extinction coefficient, and optical and electrical conductivity. Tauc’s formula, the ASF model, and "
ε
i
-
h
v
plots were all applied to investigate optically the band gap in great detail. The values of
E
d
and
E
o
and
n
o
have been investigated using a single oscillator model where their values were controlled by Tb(NO
3
)
3
- salt content
.
Using calculated gap energy, various approaches were applied to obtain the conceptual significance of the linear refractive index
(
n
)
. The nonlinear optical parameters
χ
(
1
)
,
χ
(
3
)
, and
n
2
increased noticeably as the Tb(NO
3
)
3
-salt percentage is increased to 8.0 wt%. The suggested largely doped Tb(NO
3
)
3
-salt composites show great promise as a CUT-OFF laser filters and attenuators in addition to being used in laser power-limiting technology. Based on our results, the sample was 8.0 wt.% Tb(NO
3
)
3
-salt has better gamma-ray shielding properties than the others because it has the largest Tb(NO3)3-salt concentration. The study opens a new route to fabricate Tb(NO
3
)
3
/(PVA-PVP-PEG) polymeric composites with superior optical properties.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrical resistivity</subject><subject>Fillers</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Gamma rays</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Nonlinear optics</subject><subject>Optical properties</subject><subject>Original Paper</subject><subject>Polyethylene glycol</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Polyvinyl alcohol</subject><subject>Radiation</subject><subject>Radiation shielding</subject><subject>Refractivity</subject><subject>Skeletal composites</subject><subject>Spectrum analysis</subject><subject>X-ray diffraction</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOxDAQRSMEEs8foLJEAxKGsR3HSYnQ8pAQbAG0luMHa5SNg-0t9jv4YQyLREc1U9xzZ3Sq6pjABQEQl4lA13AMtMZQU9LhZqvaI1xQ3HaMb5cdKMWdaGC32k_pHYBz0bR71efMOatzQsGh5_708YmdMZTUkFEYUV5YlHJc6byKakB6oaLS2UafstfpHIWpTDWcIzUaFJXxKvuCpYW3g_HjG5pimGzM3v70n85fr_D8dY7RfHZ7hqYwrJelTCMdllNIPlvk_LBMh9WOU0OyR7_zoHq5mT1f3-GHp9v766sHrClAxs7o3hlKamJB1M72XLSNoZxxbpixQI1hbQlRAnUrLHGso1ybjvO-76ww7KA62fSWNz9WNmX5HlZxLCclI8UPECCipOgmpWNIKVonp-iXKq4lAfktX27kyyJf_siXTYHYBkolPL7Z-Ff9D_UFXLiIRw</recordid><startdate>2025</startdate><enddate>2025</enddate><creator>Mohammed, Mervat I.</creator><creator>Zahran, Heba Y.</creator><creator>Zyoud, Samer H.</creator><creator>Shahwan, Moyad</creator><creator>Aydin, Cihat</creator><creator>Yahia, Ibrahim S.</creator><creator>Abdelhameed, Doaa</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9402-8140</orcidid></search><sort><creationdate>2025</creationdate><title>Effects of Tb(NO3)3 salt on the structural characteristics, optical, and radiation shielding properties of (PVA-PVP- PEG) polymeric composite films</title><author>Mohammed, Mervat I. ; Zahran, Heba Y. ; Zyoud, Samer H. ; Shahwan, Moyad ; Aydin, Cihat ; Yahia, Ibrahim S. ; Abdelhameed, Doaa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-fdcbfd2141e074feb5786d25355d3de02dd38fdc210487e1f3925cd955bb9e7d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrical resistivity</topic><topic>Fillers</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Gamma rays</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Nonlinear optics</topic><topic>Optical properties</topic><topic>Original Paper</topic><topic>Polyethylene glycol</topic><topic>Polymer matrix composites</topic><topic>Polymer Sciences</topic><topic>Polyvinyl alcohol</topic><topic>Radiation</topic><topic>Radiation shielding</topic><topic>Refractivity</topic><topic>Skeletal composites</topic><topic>Spectrum analysis</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohammed, Mervat I.</creatorcontrib><creatorcontrib>Zahran, Heba Y.</creatorcontrib><creatorcontrib>Zyoud, Samer H.</creatorcontrib><creatorcontrib>Shahwan, Moyad</creatorcontrib><creatorcontrib>Aydin, Cihat</creatorcontrib><creatorcontrib>Yahia, Ibrahim S.</creatorcontrib><creatorcontrib>Abdelhameed, Doaa</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohammed, Mervat I.</au><au>Zahran, Heba Y.</au><au>Zyoud, Samer H.</au><au>Shahwan, Moyad</au><au>Aydin, Cihat</au><au>Yahia, Ibrahim S.</au><au>Abdelhameed, Doaa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of Tb(NO3)3 salt on the structural characteristics, optical, and radiation shielding properties of (PVA-PVP- PEG) polymeric composite films</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2025</date><risdate>2025</risdate><volume>32</volume><issue>1</issue><artnum>27</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>Herein, this study introduces a simple, effective, and potentially successful approach to the preparation of polymeric composite systems using a Polyvinyl alcohol (PVA)-Polyvinyl pyrrolidone (PVP)-Polyethylene glycol (PEG) (PVA-PVP-PEG), (8:1:1) as the host polymeric blend with the inclusion of Tb(NO
3
)
3
-salt filler. The diffraction of X-rays (XRD), infrared spectroscopic (FTIR), Ultraviolet–visible (UV–vis) spectroscopy, and Phy-X/PSD software were utilized to analyze the modified samples’ structures, identify their optical and radiation shielding properties. The XRD patterns show the presence of Tb(NO
3
)
3
phases inside the composite matrix, where adding filler causes modifications in the polymeric network’s structure for filled composite samples. FTIR analysis showed that the Tb(NO
3
)
3
-salt interacted with the blend’s functional groups via H-bond formation. The UV–Vis spectra analysis showed all samples, especially those loaded with 8.0 wt.% Tb(NO
3
)
3
-salt has the highest values for absorbance, dielectric constant, refractive index, extinction coefficient, and optical and electrical conductivity. Tauc’s formula, the ASF model, and "
ε
i
-
h
v
plots were all applied to investigate optically the band gap in great detail. The values of
E
d
and
E
o
and
n
o
have been investigated using a single oscillator model where their values were controlled by Tb(NO
3
)
3
- salt content
.
Using calculated gap energy, various approaches were applied to obtain the conceptual significance of the linear refractive index
(
n
)
. The nonlinear optical parameters
χ
(
1
)
,
χ
(
3
)
, and
n
2
increased noticeably as the Tb(NO
3
)
3
-salt percentage is increased to 8.0 wt%. The suggested largely doped Tb(NO
3
)
3
-salt composites show great promise as a CUT-OFF laser filters and attenuators in addition to being used in laser power-limiting technology. Based on our results, the sample was 8.0 wt.% Tb(NO
3
)
3
-salt has better gamma-ray shielding properties than the others because it has the largest Tb(NO3)3-salt concentration. The study opens a new route to fabricate Tb(NO
3
)
3
/(PVA-PVP-PEG) polymeric composites with superior optical properties.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-024-04219-6</doi><orcidid>https://orcid.org/0000-0001-9402-8140</orcidid></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Electrical resistivity Fillers Fourier transforms Functional groups Gamma rays Industrial Chemistry/Chemical Engineering Infrared analysis Infrared spectroscopy Nonlinear optics Optical properties Original Paper Polyethylene glycol Polymer matrix composites Polymer Sciences Polyvinyl alcohol Radiation Radiation shielding Refractivity Skeletal composites Spectrum analysis X-ray diffraction |
| title | Effects of Tb(NO3)3 salt on the structural characteristics, optical, and radiation shielding properties of (PVA-PVP- PEG) polymeric composite films |
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