Unveiling the zwitterionic nature of an ethyl piperazine-based dithiocarbamate chain transfer agent for achieving high molar mass polyvinyl acetate: experimental and computational insights

Vinyl acetate (VAc) is one of the least active unconjugated monomers among the less activated monomers (LAMs), resulting in highly reactive and unstable propagating radicals. A significant obstacle in achieving well-defined high molar mass polyvinyl acetate (PVAc) is the occurrence of chain transfer...

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Veröffentlicht in:	Polymer chemistry 2025-01, Vol.16 (3), p.356-367
Hauptverfasser:	Haribabu, P. M., Ranjan, Prabodh, Vijayakrishna, Kari
Format:	Artikel
Sprache:	eng
Schlagworte:	Chain transfer Chains (polymeric) Cleavage Electrons Monomers Nitrogen Polymerization Polyvinyl acetates Radicals Vinyl acetate Zwitterions
Online-Zugang:	Volltext
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