Effect of Nanosized Al2O3 Dispersion on the Structural and Electrochemical Properties of PMMA/TEGDME-Based Mg-Ion Conducting Polymer Gel Electrolyte
A poly(methylmethacrylate)-based Mg-ion conducting polymer gel electrolyte immobilizing a liquid electrolyte of magnesium perchlorate in tetraethylene glycol dimethyl ether (TEGDME) solvent is presented. In order to enhance the electrolytic properties of the electrolyte, the impact of aluminum oxide...
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| Veröffentlicht in: | Journal of electronic materials 2025, Vol.54 (1), p.141-150 |
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| creator | Poonam Kuhar, Suman B. Patel, Maitri Maheshwaran, C. Mishra, Kuldeep Kanchan, D. K. Annalakshmi, A. Acharya, Naveen K. Kumar, Deepak |
| description | A poly(methylmethacrylate)-based Mg-ion conducting polymer gel electrolyte immobilizing a liquid electrolyte of magnesium perchlorate in tetraethylene glycol dimethyl ether (TEGDME) solvent is presented. In order to enhance the electrolytic properties of the electrolyte, the impact of aluminum oxide (Al
2
O
3
) nanoparticles on the structural, thermal, and electrochemical properties has been investigated. The optimized composition of the polymer gel electrolyte (PMMA + TEGDME + MgClO
4
+ 2.5 wt% Al
2
O
3
) showed increased ionic conductivity of 4.94 × 10
−5
S cm
−1
with a significantly low activation energy of 0.18 eV. Ion dynamics in the polymer gel electrolyte have been quantitatively analyzed by investigating various frequency-dependent parameters such as the real and imaginary components of dielectric permittivity, loss tangent, and the modulus. The possible conformational changes in the electrolyte system on addition of Al
2
O
3
nanoparticles have been investigated by x-ray diffraction (XRD), Fourier-transform infrared (FTIR) analysis, and differential scanning calorimetry (DSC). These studies have revealed CH
3
-Mg-Al
2
O
3
interaction in the electrolyte with significantly affected crystallinity and sufficient gel phase range with variation in temperature. |
| doi_str_mv | 10.1007/s11664-024-11511-0 |
| format | Article |
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2
O
3
) nanoparticles on the structural, thermal, and electrochemical properties has been investigated. The optimized composition of the polymer gel electrolyte (PMMA + TEGDME + MgClO
4
+ 2.5 wt% Al
2
O
3
) showed increased ionic conductivity of 4.94 × 10
−5
S cm
−1
with a significantly low activation energy of 0.18 eV. Ion dynamics in the polymer gel electrolyte have been quantitatively analyzed by investigating various frequency-dependent parameters such as the real and imaginary components of dielectric permittivity, loss tangent, and the modulus. The possible conformational changes in the electrolyte system on addition of Al
2
O
3
nanoparticles have been investigated by x-ray diffraction (XRD), Fourier-transform infrared (FTIR) analysis, and differential scanning calorimetry (DSC). These studies have revealed CH
3
-Mg-Al
2
O
3
interaction in the electrolyte with significantly affected crystallinity and sufficient gel phase range with variation in temperature.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-024-11511-0</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>28th International Conference on Nuclear Tracks and Radiation Measurements ; Aluminum oxide ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Conducting polymers ; Dimethyl ether ; Electrochemical analysis ; Electrolytes ; Electronics and Microelectronics ; Energy Materials ; Energy Storage ; Fourier transforms ; Infrared analysis ; Instrumentation ; Ion currents ; Ion dynamics ; Magnesium perchlorates ; Materials Science ; Nanoparticles ; Optical and Electronic Materials ; Polymer gels ; Polymers ; Polymethyl methacrylate ; Solid State Physics</subject><ispartof>Journal of electronic materials, 2025, Vol.54 (1), p.141-150</ispartof><rights>The Minerals, Metals & Materials Society 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. Jan 2025</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-61fce6db9b01393a4318878d2227c4556cb03118d0ec304cea80de50881161d33</cites><orcidid>0000-0002-8366-5192</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11664-024-11511-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11664-024-11511-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Poonam</creatorcontrib><creatorcontrib>Kuhar, Suman B.</creatorcontrib><creatorcontrib>Patel, Maitri</creatorcontrib><creatorcontrib>Maheshwaran, C.</creatorcontrib><creatorcontrib>Mishra, Kuldeep</creatorcontrib><creatorcontrib>Kanchan, D. K.</creatorcontrib><creatorcontrib>Annalakshmi, A.</creatorcontrib><creatorcontrib>Acharya, Naveen K.</creatorcontrib><creatorcontrib>Kumar, Deepak</creatorcontrib><title>Effect of Nanosized Al2O3 Dispersion on the Structural and Electrochemical Properties of PMMA/TEGDME-Based Mg-Ion Conducting Polymer Gel Electrolyte</title><title>Journal of electronic materials</title><addtitle>J. Electron. Mater</addtitle><description>A poly(methylmethacrylate)-based Mg-ion conducting polymer gel electrolyte immobilizing a liquid electrolyte of magnesium perchlorate in tetraethylene glycol dimethyl ether (TEGDME) solvent is presented. In order to enhance the electrolytic properties of the electrolyte, the impact of aluminum oxide (Al
2
O
3
) nanoparticles on the structural, thermal, and electrochemical properties has been investigated. The optimized composition of the polymer gel electrolyte (PMMA + TEGDME + MgClO
4
+ 2.5 wt% Al
2
O
3
) showed increased ionic conductivity of 4.94 × 10
−5
S cm
−1
with a significantly low activation energy of 0.18 eV. Ion dynamics in the polymer gel electrolyte have been quantitatively analyzed by investigating various frequency-dependent parameters such as the real and imaginary components of dielectric permittivity, loss tangent, and the modulus. The possible conformational changes in the electrolyte system on addition of Al
2
O
3
nanoparticles have been investigated by x-ray diffraction (XRD), Fourier-transform infrared (FTIR) analysis, and differential scanning calorimetry (DSC). These studies have revealed CH
3
-Mg-Al
2
O
3
interaction in the electrolyte with significantly affected crystallinity and sufficient gel phase range with variation in temperature.</description><subject>28th International Conference on Nuclear Tracks and Radiation Measurements</subject><subject>Aluminum oxide</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Conducting polymers</subject><subject>Dimethyl ether</subject><subject>Electrochemical analysis</subject><subject>Electrolytes</subject><subject>Electronics and Microelectronics</subject><subject>Energy Materials</subject><subject>Energy Storage</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Instrumentation</subject><subject>Ion currents</subject><subject>Ion dynamics</subject><subject>Magnesium perchlorates</subject><subject>Materials Science</subject><subject>Nanoparticles</subject><subject>Optical and Electronic Materials</subject><subject>Polymer gels</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Solid State Physics</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEURoMoWH9ewFXAdfTeZH7istaxClYLKrgL08ydOjKd1GS6qM_hA5taxZ0QCITvnMBh7AThDAHy84CYZYkAmQjEFFHADhtgmiiBOnvZZQNQGYpUqnSfHYTwBhBXGgfss6hrsj13Nb8vOxeaD6r4sJUPil81YUk-NK7j8fSvxB97v7L9ypctL7uKF20kvbOvtGhsfJt6F4G-obDRTSeT4flTMb6aFOKyDFE7mYvbaBq5roqappvzqWvXC_J8TO2vrV33dMT26rINdPxzH7Ln6-JpdCPuHsa3o-GdsBKgFxnWlrJqdjEDVBeqTBRqnetKSpnbJE0zOwOFqCsgqyCxVGqoKAWtYy2slDpkp1vv0rv3FYXevLmV7-KXRmGSS51iDnEltyvrXQiearP0zaL0a4NgNvXNtr6J9c13fbOB1BYKcdzNyf-p_6G-AORXhwE</recordid><startdate>2025</startdate><enddate>2025</enddate><creator>Poonam</creator><creator>Kuhar, Suman B.</creator><creator>Patel, Maitri</creator><creator>Maheshwaran, C.</creator><creator>Mishra, Kuldeep</creator><creator>Kanchan, D. K.</creator><creator>Annalakshmi, A.</creator><creator>Acharya, Naveen K.</creator><creator>Kumar, Deepak</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-8366-5192</orcidid></search><sort><creationdate>2025</creationdate><title>Effect of Nanosized Al2O3 Dispersion on the Structural and Electrochemical Properties of PMMA/TEGDME-Based Mg-Ion Conducting Polymer Gel Electrolyte</title><author>Poonam ; Kuhar, Suman B. ; Patel, Maitri ; Maheshwaran, C. ; Mishra, Kuldeep ; Kanchan, D. K. ; Annalakshmi, A. ; Acharya, Naveen K. ; Kumar, Deepak</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-61fce6db9b01393a4318878d2227c4556cb03118d0ec304cea80de50881161d33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>28th International Conference on Nuclear Tracks and Radiation Measurements</topic><topic>Aluminum oxide</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Conducting polymers</topic><topic>Dimethyl ether</topic><topic>Electrochemical analysis</topic><topic>Electrolytes</topic><topic>Electronics and Microelectronics</topic><topic>Energy Materials</topic><topic>Energy Storage</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Instrumentation</topic><topic>Ion currents</topic><topic>Ion dynamics</topic><topic>Magnesium perchlorates</topic><topic>Materials Science</topic><topic>Nanoparticles</topic><topic>Optical and Electronic Materials</topic><topic>Polymer gels</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Poonam</creatorcontrib><creatorcontrib>Kuhar, Suman B.</creatorcontrib><creatorcontrib>Patel, Maitri</creatorcontrib><creatorcontrib>Maheshwaran, C.</creatorcontrib><creatorcontrib>Mishra, Kuldeep</creatorcontrib><creatorcontrib>Kanchan, D. K.</creatorcontrib><creatorcontrib>Annalakshmi, A.</creatorcontrib><creatorcontrib>Acharya, Naveen K.</creatorcontrib><creatorcontrib>Kumar, Deepak</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Poonam</au><au>Kuhar, Suman B.</au><au>Patel, Maitri</au><au>Maheshwaran, C.</au><au>Mishra, Kuldeep</au><au>Kanchan, D. K.</au><au>Annalakshmi, A.</au><au>Acharya, Naveen K.</au><au>Kumar, Deepak</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Nanosized Al2O3 Dispersion on the Structural and Electrochemical Properties of PMMA/TEGDME-Based Mg-Ion Conducting Polymer Gel Electrolyte</atitle><jtitle>Journal of electronic materials</jtitle><stitle>J. Electron. Mater</stitle><date>2025</date><risdate>2025</risdate><volume>54</volume><issue>1</issue><spage>141</spage><epage>150</epage><pages>141-150</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><abstract>A poly(methylmethacrylate)-based Mg-ion conducting polymer gel electrolyte immobilizing a liquid electrolyte of magnesium perchlorate in tetraethylene glycol dimethyl ether (TEGDME) solvent is presented. In order to enhance the electrolytic properties of the electrolyte, the impact of aluminum oxide (Al
2
O
3
) nanoparticles on the structural, thermal, and electrochemical properties has been investigated. The optimized composition of the polymer gel electrolyte (PMMA + TEGDME + MgClO
4
+ 2.5 wt% Al
2
O
3
) showed increased ionic conductivity of 4.94 × 10
−5
S cm
−1
with a significantly low activation energy of 0.18 eV. Ion dynamics in the polymer gel electrolyte have been quantitatively analyzed by investigating various frequency-dependent parameters such as the real and imaginary components of dielectric permittivity, loss tangent, and the modulus. The possible conformational changes in the electrolyte system on addition of Al
2
O
3
nanoparticles have been investigated by x-ray diffraction (XRD), Fourier-transform infrared (FTIR) analysis, and differential scanning calorimetry (DSC). These studies have revealed CH
3
-Mg-Al
2
O
3
interaction in the electrolyte with significantly affected crystallinity and sufficient gel phase range with variation in temperature.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11664-024-11511-0</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-8366-5192</orcidid></addata></record> |
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| subjects | 28th International Conference on Nuclear Tracks and Radiation Measurements Aluminum oxide Characterization and Evaluation of Materials Chemistry and Materials Science Conducting polymers Dimethyl ether Electrochemical analysis Electrolytes Electronics and Microelectronics Energy Materials Energy Storage Fourier transforms Infrared analysis Instrumentation Ion currents Ion dynamics Magnesium perchlorates Materials Science Nanoparticles Optical and Electronic Materials Polymer gels Polymers Polymethyl methacrylate Solid State Physics |
| title | Effect of Nanosized Al2O3 Dispersion on the Structural and Electrochemical Properties of PMMA/TEGDME-Based Mg-Ion Conducting Polymer Gel Electrolyte |
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