Effect of substrate temperature on the microstructural and optical properties of chemical molecular beam deposited sb2s3 films
In this work, Sb x S y thin films were grown on glass substrates for the first time using the chemical molecular beam deposition method in the atmospheric pressure hydrogen flow. The structural, morphological and optical properties of Sb x S y thin films grown at different substrate temperatures of...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2024-12, Vol.35 (36), p.2295 |
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| creator | Razykov, T. M. Kuchkarov, К. M. Tivanov, M. S. Lyashenko, L. S. Isakov, D. Z. Khurramov, R. R. Makhmudov, Z. Olimov, A. N. Pirimmetov, M. Sivtsova, P. A. Yuldoshov, R. T. Schmidt-Mende, L. Shakhriev, K. F. Utamuradova, Sh. B. Bekmirzoyev, J. G. |
| description | In this work, Sb
x
S
y
thin films were grown on glass substrates for the first time using the chemical molecular beam deposition method in the atmospheric pressure hydrogen flow. The structural, morphological and optical properties of Sb
x
S
y
thin films grown at different substrate temperatures of 300 °C, 350 °C, 400 °C and 450 °C were studied. XRD results showed that the Sb
x
S
y
thin films grown at different substrate temperatures have an orthorhombic crystal structure. Phase analysis indicated a weakening of Sb-S bonds with increasing substrate temperature. Also, the grain sizes of all obtained thin films ranged from 0.5 to 3 µm. The increase in temperature caused the grains to grow and the spaces between them to increase. Optical experiments reveal that as the substrate temperature increases, the optical band gap energy of the films increases from 1.52 eV to 1.73 eV, as well as an increase in the Urbach energy from 0.11 eV to 0.44 eV. The experimental values of the band gap for Sb
2
S
3
films are near the optimum value for photovoltaic conversion. |
| doi_str_mv | 10.1007/s10854-024-13999-y |
| format | Article |
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x
S
y
thin films were grown on glass substrates for the first time using the chemical molecular beam deposition method in the atmospheric pressure hydrogen flow. The structural, morphological and optical properties of Sb
x
S
y
thin films grown at different substrate temperatures of 300 °C, 350 °C, 400 °C and 450 °C were studied. XRD results showed that the Sb
x
S
y
thin films grown at different substrate temperatures have an orthorhombic crystal structure. Phase analysis indicated a weakening of Sb-S bonds with increasing substrate temperature. Also, the grain sizes of all obtained thin films ranged from 0.5 to 3 µm. The increase in temperature caused the grains to grow and the spaces between them to increase. Optical experiments reveal that as the substrate temperature increases, the optical band gap energy of the films increases from 1.52 eV to 1.73 eV, as well as an increase in the Urbach energy from 0.11 eV to 0.44 eV. The experimental values of the band gap for Sb
2
S
3
films are near the optimum value for photovoltaic conversion.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-024-13999-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Crystal growth ; Crystal structure ; Energy gap ; Glass substrates ; Grain size ; Materials Science ; Molecular beams ; Optical and Electronic Materials ; Optical properties ; Photovoltaic conversion ; Pressure effects ; Temperature ; Thin films</subject><ispartof>Journal of materials science. Materials in electronics, 2024-12, Vol.35 (36), p.2295</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. Dec 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-4314-5683</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-024-13999-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-024-13999-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Razykov, T. M.</creatorcontrib><creatorcontrib>Kuchkarov, К. M.</creatorcontrib><creatorcontrib>Tivanov, M. S.</creatorcontrib><creatorcontrib>Lyashenko, L. S.</creatorcontrib><creatorcontrib>Isakov, D. Z.</creatorcontrib><creatorcontrib>Khurramov, R. R.</creatorcontrib><creatorcontrib>Makhmudov, Z.</creatorcontrib><creatorcontrib>Olimov, A. N.</creatorcontrib><creatorcontrib>Pirimmetov, M.</creatorcontrib><creatorcontrib>Sivtsova, P. A.</creatorcontrib><creatorcontrib>Yuldoshov, R. T.</creatorcontrib><creatorcontrib>Schmidt-Mende, L.</creatorcontrib><creatorcontrib>Shakhriev, K. F.</creatorcontrib><creatorcontrib>Utamuradova, Sh. B.</creatorcontrib><creatorcontrib>Bekmirzoyev, J. G.</creatorcontrib><title>Effect of substrate temperature on the microstructural and optical properties of chemical molecular beam deposited sb2s3 films</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>In this work, Sb
x
S
y
thin films were grown on glass substrates for the first time using the chemical molecular beam deposition method in the atmospheric pressure hydrogen flow. The structural, morphological and optical properties of Sb
x
S
y
thin films grown at different substrate temperatures of 300 °C, 350 °C, 400 °C and 450 °C were studied. XRD results showed that the Sb
x
S
y
thin films grown at different substrate temperatures have an orthorhombic crystal structure. Phase analysis indicated a weakening of Sb-S bonds with increasing substrate temperature. Also, the grain sizes of all obtained thin films ranged from 0.5 to 3 µm. The increase in temperature caused the grains to grow and the spaces between them to increase. Optical experiments reveal that as the substrate temperature increases, the optical band gap energy of the films increases from 1.52 eV to 1.73 eV, as well as an increase in the Urbach energy from 0.11 eV to 0.44 eV. The experimental values of the band gap for Sb
2
S
3
films are near the optimum value for photovoltaic conversion.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Crystal growth</subject><subject>Crystal structure</subject><subject>Energy gap</subject><subject>Glass substrates</subject><subject>Grain size</subject><subject>Materials Science</subject><subject>Molecular beams</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Photovoltaic conversion</subject><subject>Pressure effects</subject><subject>Temperature</subject><subject>Thin films</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LxDAQhoMouK7-AU8Bz9HJV5seZVk_YMHLHryVNp26XdqmJulhL_52s7uCEMjLzMPM8BByz-GRA-RPgYPRioFQjMuiKNjhgiy4ziVTRnxekgUUOmdKC3FNbkLYA0CmpFmQn3Xboo3UtTTMdYi-ikgjDhOmNHukbqRxh3TorHepPdtUrXpajQ11U-xsypN3CY8dhuMYu8PhVB5cj3buK09rrAba4ORCF7GhoRZB0rbrh3BLrtqqD3j39y_J9mW9Xb2xzcfr--p5w6ZcHBg3tWxVLSuj6pxjo7NMCWkVpGeMgCYvQDe2MKbOs9ZmKcOR0KCUURzkkjycx6ZTv2cMsdy72Y9pYym50kkYiCxR8kyFyXfjF_p_ikN59FyePZfJc3nyXB7kLwgJcqI</recordid><startdate>20241201</startdate><enddate>20241201</enddate><creator>Razykov, T. 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M. ; Tivanov, M. S. ; Lyashenko, L. S. ; Isakov, D. Z. ; Khurramov, R. R. ; Makhmudov, Z. ; Olimov, A. N. ; Pirimmetov, M. ; Sivtsova, P. A. ; Yuldoshov, R. T. ; Schmidt-Mende, L. ; Shakhriev, K. F. ; Utamuradova, Sh. B. ; Bekmirzoyev, J. 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B.</au><au>Bekmirzoyev, J. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of substrate temperature on the microstructural and optical properties of chemical molecular beam deposited sb2s3 films</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2024-12-01</date><risdate>2024</risdate><volume>35</volume><issue>36</issue><spage>2295</spage><pages>2295-</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>In this work, Sb
x
S
y
thin films were grown on glass substrates for the first time using the chemical molecular beam deposition method in the atmospheric pressure hydrogen flow. The structural, morphological and optical properties of Sb
x
S
y
thin films grown at different substrate temperatures of 300 °C, 350 °C, 400 °C and 450 °C were studied. XRD results showed that the Sb
x
S
y
thin films grown at different substrate temperatures have an orthorhombic crystal structure. Phase analysis indicated a weakening of Sb-S bonds with increasing substrate temperature. Also, the grain sizes of all obtained thin films ranged from 0.5 to 3 µm. The increase in temperature caused the grains to grow and the spaces between them to increase. Optical experiments reveal that as the substrate temperature increases, the optical band gap energy of the films increases from 1.52 eV to 1.73 eV, as well as an increase in the Urbach energy from 0.11 eV to 0.44 eV. The experimental values of the band gap for Sb
2
S
3
films are near the optimum value for photovoltaic conversion.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-024-13999-y</doi><orcidid>https://orcid.org/0000-0003-4314-5683</orcidid></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Crystal growth Crystal structure Energy gap Glass substrates Grain size Materials Science Molecular beams Optical and Electronic Materials Optical properties Photovoltaic conversion Pressure effects Temperature Thin films |
| title | Effect of substrate temperature on the microstructural and optical properties of chemical molecular beam deposited sb2s3 films |
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