Desulfurization of isothiocyanates by a divalent germanium amide
Ge[N(SiMe 3 ) 2 ] 2 reacts with isocyanates but its reactivity with the related heavier congeners has not been explored. Its reaction with tertiary isothiocyanates results in the abstraction of the sulfur atom to yield a germanium( iv ) dimer [((SiMe 3 ) 2 N) 2 GeS] 2 in high yield. The reaction wit...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-12, Vol.54 (1), p.7-73 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 54 |
| creator | Stancil, Thad R Fortney, Vanessa A Murphy, Julia K Gembicky, Milan Rheingold, Arnold L Weinert, Charles S |
| description | Ge[N(SiMe
3
)
2
]
2
reacts with isocyanates but its reactivity with the related heavier congeners has not been explored. Its reaction with tertiary isothiocyanates results in the abstraction of the sulfur atom to yield a germanium(
iv
) dimer [((SiMe
3
)
2
N)
2
GeS]
2
in high yield. The reaction with
tert
-butylisoselenocyanate produced the related dimer [((SiMe
3
)
2
N)
2
GeSe]
2
within 5 minutes as shown using
77
Se NMR spectroscopy.
A germanium(
ii
) amide abstracts a sulfur atom from isothiocyanates. |
| doi_str_mv | 10.1039/d4dt02882a |
| format | Article |
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3
)
2
]
2
reacts with isocyanates but its reactivity with the related heavier congeners has not been explored. Its reaction with tertiary isothiocyanates results in the abstraction of the sulfur atom to yield a germanium(
iv
) dimer [((SiMe
3
)
2
N)
2
GeS]
2
in high yield. The reaction with
tert
-butylisoselenocyanate produced the related dimer [((SiMe
3
)
2
N)
2
GeSe]
2
within 5 minutes as shown using
77
Se NMR spectroscopy.
A germanium(
ii
) amide abstracts a sulfur atom from isothiocyanates.</description><identifier>ISSN: 1477-9226</identifier><identifier>ISSN: 1477-9234</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d4dt02882a</identifier><identifier>PMID: 39607371</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Congeners ; Dimers ; Germanium ; Isocyanates ; NMR spectroscopy</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-12, Vol.54 (1), p.7-73</ispartof><rights>Copyright Royal Society of Chemistry 2025</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c262t-2e659dfb4517df3d12e4f9a8a78a93c1a927db9edbac16f4e8263bbc945d0b893</cites><orcidid>0000-0003-0754-8688</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39607371$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Stancil, Thad R</creatorcontrib><creatorcontrib>Fortney, Vanessa A</creatorcontrib><creatorcontrib>Murphy, Julia K</creatorcontrib><creatorcontrib>Gembicky, Milan</creatorcontrib><creatorcontrib>Rheingold, Arnold L</creatorcontrib><creatorcontrib>Weinert, Charles S</creatorcontrib><title>Desulfurization of isothiocyanates by a divalent germanium amide</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Ge[N(SiMe
3
)
2
]
2
reacts with isocyanates but its reactivity with the related heavier congeners has not been explored. Its reaction with tertiary isothiocyanates results in the abstraction of the sulfur atom to yield a germanium(
iv
) dimer [((SiMe
3
)
2
N)
2
GeS]
2
in high yield. The reaction with
tert
-butylisoselenocyanate produced the related dimer [((SiMe
3
)
2
N)
2
GeSe]
2
within 5 minutes as shown using
77
Se NMR spectroscopy.
A germanium(
ii
) amide abstracts a sulfur atom from isothiocyanates.</description><subject>Congeners</subject><subject>Dimers</subject><subject>Germanium</subject><subject>Isocyanates</subject><subject>NMR spectroscopy</subject><issn>1477-9226</issn><issn>1477-9234</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0UtLw0AQB_BFFKvVi3cl4EWE6r6Szd4srS8oeKnnMPuIbkmydTcR6qc3tbWCpxmYH8PwH4TOCL4hmMlbw02LaZ5T2ENHhAsxkpTx_V1PswE6jnGBMaU4pYdowGSGBRPkCN1NbeyqsgvuC1rnm8SXiYu-fXder6CB1sZErRJIjPuEyjZt8mZDDY3r6gRqZ-wJOiihivZ0W4fo9eF-PnkazV4enyfj2UjTjLYjarNUmlLxlAhTMkOo5aWEHEQOkmkCkgqjpDUKNMlKbnOaMaW05KnBKpdsiK42e5fBf3Q2tkXtorZVBY31XSwYYUywnIk1vfxHF74LTX9dr3jKCcUi69X1RungYwy2LJbB1RBWBcHFOtdiyqfzn1zHPb7YruxUbc2O_gbZg_MNCFHvpn-PYd-51HyP</recordid><startdate>20241217</startdate><enddate>20241217</enddate><creator>Stancil, Thad R</creator><creator>Fortney, Vanessa A</creator><creator>Murphy, Julia K</creator><creator>Gembicky, Milan</creator><creator>Rheingold, Arnold L</creator><creator>Weinert, Charles S</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0754-8688</orcidid></search><sort><creationdate>20241217</creationdate><title>Desulfurization of isothiocyanates by a divalent germanium amide</title><author>Stancil, Thad R ; Fortney, Vanessa A ; Murphy, Julia K ; Gembicky, Milan ; Rheingold, Arnold L ; Weinert, Charles S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c262t-2e659dfb4517df3d12e4f9a8a78a93c1a927db9edbac16f4e8263bbc945d0b893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Congeners</topic><topic>Dimers</topic><topic>Germanium</topic><topic>Isocyanates</topic><topic>NMR spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stancil, Thad R</creatorcontrib><creatorcontrib>Fortney, Vanessa A</creatorcontrib><creatorcontrib>Murphy, Julia K</creatorcontrib><creatorcontrib>Gembicky, Milan</creatorcontrib><creatorcontrib>Rheingold, Arnold L</creatorcontrib><creatorcontrib>Weinert, Charles S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stancil, Thad R</au><au>Fortney, Vanessa A</au><au>Murphy, Julia K</au><au>Gembicky, Milan</au><au>Rheingold, Arnold L</au><au>Weinert, Charles S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Desulfurization of isothiocyanates by a divalent germanium amide</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-12-17</date><risdate>2024</risdate><volume>54</volume><issue>1</issue><spage>7</spage><epage>73</epage><pages>7-73</pages><issn>1477-9226</issn><issn>1477-9234</issn><eissn>1477-9234</eissn><abstract>Ge[N(SiMe
3
)
2
]
2
reacts with isocyanates but its reactivity with the related heavier congeners has not been explored. Its reaction with tertiary isothiocyanates results in the abstraction of the sulfur atom to yield a germanium(
iv
) dimer [((SiMe
3
)
2
N)
2
GeS]
2
in high yield. The reaction with
tert
-butylisoselenocyanate produced the related dimer [((SiMe
3
)
2
N)
2
GeSe]
2
within 5 minutes as shown using
77
Se NMR spectroscopy.
A germanium(
ii
) amide abstracts a sulfur atom from isothiocyanates.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39607371</pmid><doi>10.1039/d4dt02882a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-0754-8688</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-12, Vol.54 (1), p.7-73 |
| issn | 1477-9226 1477-9234 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_3145412076 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Congeners Dimers Germanium Isocyanates NMR spectroscopy |
| title | Desulfurization of isothiocyanates by a divalent germanium amide |
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