Recent Efforts to Improve the Accuracy and Precision of Carbonate Clumped‐Isotope Analysis
ABSTRACT The carbonate clumped‐isotope thermometer, a relatively recent innovation, is based on the strong relationship between 13C‐18O bond abundance in carbonates and their formation temperature. It can measure temperatures solely based on the CO2 extracted from carbonates and has attracted attent...
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| creator | Oikawa, Kazuma Abe, Osamu Iryu, Yasufumi |
| description | ABSTRACT
The carbonate clumped‐isotope thermometer, a relatively recent innovation, is based on the strong relationship between 13C‐18O bond abundance in carbonates and their formation temperature. It can measure temperatures solely based on the CO2 extracted from carbonates and has attracted attention as it accurately reconstructs surface water temperatures on a geological timescale. However, at the time of development, there were many limitations in its application to paleoenvironmental reconstruction such as the large sample size (10 mg), the complicated organic contaminant removal process, and the lack of internationally recognized carbonate standards, and improvements in the measurement method were required. Here, we review the studies conducted since the thermometer development to improve the accuracy and precision of carbonate clumped‐isotope analysis. Finally, we discuss advanced carbonate clumped‐isotope analysis methods, including laser spectroscopy. |
| doi_str_mv | 10.1111/iar.12537 |
| format | Article |
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The carbonate clumped‐isotope thermometer, a relatively recent innovation, is based on the strong relationship between 13C‐18O bond abundance in carbonates and their formation temperature. It can measure temperatures solely based on the CO2 extracted from carbonates and has attracted attention as it accurately reconstructs surface water temperatures on a geological timescale. However, at the time of development, there were many limitations in its application to paleoenvironmental reconstruction such as the large sample size (10 mg), the complicated organic contaminant removal process, and the lack of internationally recognized carbonate standards, and improvements in the measurement method were required. Here, we review the studies conducted since the thermometer development to improve the accuracy and precision of carbonate clumped‐isotope analysis. Finally, we discuss advanced carbonate clumped‐isotope analysis methods, including laser spectroscopy.</description><identifier>ISSN: 1038-4871</identifier><identifier>EISSN: 1440-1738</identifier><identifier>DOI: 10.1111/iar.12537</identifier><language>eng</language><publisher>Melbourne: John Wiley & Sons Australia, Ltd</publisher><subject>Accuracy ; Carbon dioxide ; Carbonates ; clumped isotope ; Contaminants ; dual clumped isotope ; infrared laser absorption spectroscopy ; mass spectrometry ; Measurement methods ; Organic contaminants ; Pollutant removal ; small carbonate samples ; Spectroscopy ; standardization ; Surface temperature ; Surface water ; Temperature measurement ; Temperature requirements ; Thermometers ; Thermometry ; Water temperature</subject><ispartof>The island arc, 2024-01, Vol.33 (1), p.n/a</ispartof><rights>2024 The Author(s). published by John Wiley & Sons Australia, Ltd.</rights><rights>2024. This article is published under http://creativecommons.org/licenses/by-nc/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2227-3c65c6feff188697a1c22a48b12da0b0b78032ba5cd81859c05fb15e7d54e6c93</cites><orcidid>0000-0001-6503-3100 ; 0009-0004-5760-2448 ; 0000-0002-6099-0662</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fiar.12537$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fiar.12537$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Oikawa, Kazuma</creatorcontrib><creatorcontrib>Abe, Osamu</creatorcontrib><creatorcontrib>Iryu, Yasufumi</creatorcontrib><title>Recent Efforts to Improve the Accuracy and Precision of Carbonate Clumped‐Isotope Analysis</title><title>The island arc</title><description>ABSTRACT
The carbonate clumped‐isotope thermometer, a relatively recent innovation, is based on the strong relationship between 13C‐18O bond abundance in carbonates and their formation temperature. It can measure temperatures solely based on the CO2 extracted from carbonates and has attracted attention as it accurately reconstructs surface water temperatures on a geological timescale. However, at the time of development, there were many limitations in its application to paleoenvironmental reconstruction such as the large sample size (10 mg), the complicated organic contaminant removal process, and the lack of internationally recognized carbonate standards, and improvements in the measurement method were required. Here, we review the studies conducted since the thermometer development to improve the accuracy and precision of carbonate clumped‐isotope analysis. 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The carbonate clumped‐isotope thermometer, a relatively recent innovation, is based on the strong relationship between 13C‐18O bond abundance in carbonates and their formation temperature. It can measure temperatures solely based on the CO2 extracted from carbonates and has attracted attention as it accurately reconstructs surface water temperatures on a geological timescale. However, at the time of development, there were many limitations in its application to paleoenvironmental reconstruction such as the large sample size (10 mg), the complicated organic contaminant removal process, and the lack of internationally recognized carbonate standards, and improvements in the measurement method were required. Here, we review the studies conducted since the thermometer development to improve the accuracy and precision of carbonate clumped‐isotope analysis. Finally, we discuss advanced carbonate clumped‐isotope analysis methods, including laser spectroscopy.</abstract><cop>Melbourne</cop><pub>John Wiley & Sons Australia, Ltd</pub><doi>10.1111/iar.12537</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0001-6503-3100</orcidid><orcidid>https://orcid.org/0009-0004-5760-2448</orcidid><orcidid>https://orcid.org/0000-0002-6099-0662</orcidid><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Accuracy Carbon dioxide Carbonates clumped isotope Contaminants dual clumped isotope infrared laser absorption spectroscopy mass spectrometry Measurement methods Organic contaminants Pollutant removal small carbonate samples Spectroscopy standardization Surface temperature Surface water Temperature measurement Temperature requirements Thermometers Thermometry Water temperature |
| title | Recent Efforts to Improve the Accuracy and Precision of Carbonate Clumped‐Isotope Analysis |
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