Electroless Deposition of Ni-Sn Layers Having High Sn Content(> 30 at.%)on Fe Substrates(3): Examination of bath additives to prevent the formation of cracks and pinholes on the Ni-Sn layers

This study investigated plating bath additive effects on the improvement of electroless Ni-Sn plating film resistance against aqueous sodium hypochlorite solutions. Surfaces of conventional electroless Ni-Sn coatings show numerous cracks and pinholes. Through these gaps, a sodium hypochlorite aqueou...

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Veröffentlicht in:Hyōmen gijutsu 2024/11/01, Vol.75(11), pp.530-537
Hauptverfasser: IWAMOTO, Takayuki, MIZUSHINA, Manato, KARIYA, Shiho, KAWAI, Akimasa, FUKUNISHI, Mika, MATSUMOTO, Futoshi
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container_end_page 537
container_issue 11
container_start_page 530
container_title Hyōmen gijutsu
container_volume 75
creator IWAMOTO, Takayuki
MIZUSHINA, Manato
KARIYA, Shiho
KAWAI, Akimasa
FUKUNISHI, Mika
MATSUMOTO, Futoshi
description This study investigated plating bath additive effects on the improvement of electroless Ni-Sn plating film resistance against aqueous sodium hypochlorite solutions. Surfaces of conventional electroless Ni-Sn coatings show numerous cracks and pinholes. Through these gaps, a sodium hypochlorite aqueous solution can corrode the substrate, thereby decreasing the chemical resistance of the plated coating. A plating solution bath to which a combination of thiourea and hydroquinone had been added reduced the internal stress of the plating film, suppressed the rate of crack formation on the film surface, and reduced pinhole formation. Findings also revealed that the resultant film had higher resistance than conventional Ni-Sn films.
doi_str_mv 10.4139/sfj.75.530
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subjects Additives
Aqueous solutions
Corrosion resistance
Crack
Electroless Deposition
Electroless plating
Hole Formation
Hydroquinone
Ni-Sn
Pinholes
Plating baths
Residual stress
Sodium hypochlorite
Substrates
Thiourea
Tin plating
title Electroless Deposition of Ni-Sn Layers Having High Sn Content(> 30 at.%)on Fe Substrates(3): Examination of bath additives to prevent the formation of cracks and pinholes on the Ni-Sn layers
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